CONDUCTIVE SLURRY, CURRENT COLLECTOR, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND ELECTRIC APPARATUS
This application provides a conductive slurry, a current collector, a secondary battery, a battery module, a battery pack, and an electric apparatus. The conductive slurry in this application includes the following raw material components: an aqueous binder including an aqueous polymer having polycarboxyl functionality, a conductive agent, a dispersant, and a curing agent, where the curing agent is used for cross-linking reaction with the aqueous polymer having polycarboxyl functionality. The conductive slurry in embodiments of this application has relatively good conductivity and adhesion performance as well as relatively good water resistance, which can improve stability of the secondary battery during operation and prolong its cycle life.
1 . A conductive slurry, characterized by comprising the following raw material components:
an aqueous binder comprising an aqueous polymer having polycarboxyl functionality;
a conductive agent;
a dispersant; and
a curing agent for cross-linking reaction with the aqueous polymer having polycarboxyl functionality.
2 . The conductive slurry according to claim 1 , characterized in that the conductive slurry comprises, in parts by mass:
100 parts of aqueous binder;
50-150 parts of conductive agent;
800-850 parts of dispersant; and
3-16 parts of curing agent.
3 . The conductive slurry according to claim 1 , characterized in that the aqueous polymer having polycarboxyl functionality comprises at least one of aqueous acrylic resin, an ethylene vinyl acetate copolymer, and an acrylonitrile multi-copolymer having polycarboxyl functionality.
4 . The conductive slurry according to claim 1 , characterized in that the aqueous acrylic resin comprises a copolymer of polyacrylic acid, acrylic acid, acrylate and optionally other ethylenically unsaturated monomers, or a combination thereof; optionally, the aqueous acrylic resin comprises polyacrylic acid having a number average molecular weight of 300,000 to 800,000; and optionally, the acrylic acid is partially neutralized to form salt.
5 . The conductive slurry according to claim 1 , characterized in that the curing agent comprises a compound having more than two carboxylic acid reactive functional groups, optionally, the carboxylic acid reactive functional group being selected from at least one of aziridine, ethylene oxide, amino, and carbodiimide group; and
optionally, the curing agent comprises at least one of aziridine functional compound, polycarbodiimide and salt thereof, epoxy-functionalized silane compound, polymer grafted with epoxy silane, and polyethyleneimine; and optionally, the polycarbodiimide has a number average molecular weight of 10,000 to 40,000.
6 . The conductive slurry according to claim 2 , characterized in that the dispersant comprises an aqueous solvent, and optionally, the aqueous solvent comprises water.
7 . The conductive slurry according to claim 1 , characterized in that the raw material components of the conductive slurry further comprise a thickener, the thickener comprising at least one of xanthan gum, carboxymethyl cellulose and salt thereof, or poly-N-vinylacetamide.
8 . The conductive slurry according to claim 1 , characterized in that the conductive agent comprises at least one of carbon black, graphite, acetylene black, Ketjen black, graphene, and carbon nanotubes.
9 . A method for preparing the conductive slurry according to claim 1 , characterized in that the method comprises:
uniformly mixing a conductive agent, a dispersant, and an aqueous binder to obtain a pre-mixture; and
adding a curing agent to the pre-mixture and uniformly mixing it to obtain a conductive slurry.
10 . The method according to claim 9 , characterized in that a mass ratio of the curing agent to the aqueous binder is 0.03-0.16.
11 . A current collector, characterized by comprising a substrate and a conductive coating applied on the substrate, wherein the conductive coating comprises a conductive agent and an aqueous polymer binder having polycarboxyl functionality, wherein the aqueous polymer is cross-linked to form a three-dimensional network structure.
12 . The current collector according to claim 11 , characterized in that the conductive coating is formed by curing the conductive slurry according to claim 1 .
13 . The current collector according to claim 11 , characterized in that the substrate comprises an aluminum foil or a polymeric material composite containing aluminum.
14 . The current collector according to claim 11 , characterized in that a peeling force between the conductive coating and the substrate is N≥50N/M.
15 . An electrode plate, characterized by comprising:
the current collector according to claim 11 ; and
an active material layer provided on a conductive coating of the current collector.
16 . The electrode plate according to claim 15 , characterized in that the active material layer comprises an olivine-structured lithium-containing phosphate and an aqueous polymer binder.
17 . A secondary battery, characterized by comprising the electrode plate according to claim 15 .
18 . A battery module, characterized by comprising the secondary battery according to claim 17 .
19 . A battery pack, characterized by comprising the battery module according to claim 18 .
20 . An electric apparatus, characterized by comprising at least one of the secondary battery according to claim 17 .