BINDER FOR SECONDARY BATTERIES AND PREPARATION METHOD THEREOF, AS WELL AS SEPARATOR, BATTERY CELL, BATTERY AND ELECTRICAL APPARATUS
The present application relates to the technical field of secondary batteries, and in particular to a binder for secondary batteries and a preparation method thereof, a separator comprising the binder, a battery cell, a battery and an electrical apparatus. The binder for secondary batteries includes an organic polymer. The organic polymer has a first glass transition temperature and a second glass transition temperature, the first glass transition temperature is less than or equal to 25° C., and the second glass transition temperature is greater than 25° C. During coating of a separator, the binder is non-viscous at room temperature to facilitate winding and unwinding of the separator. However, the binder has a better bonding force when a cold pressing process is carried out after the winding with positive and negative electrode plates, so that the positive and negative electrode plates and the separator fit each other closely.
1 . A binder for secondary batteries, comprising an organic polymer, the organic polymer having a first glass transition temperature and a second glass transition temperature, the first glass transition temperature being less than or equal to 25° C., and the second glass transition temperature being greater than 25° C.
2 . The binder for secondary batteries according to claim 1 , wherein the first glass transition temperature ranges from −80° C. to 25° C., preferably from −60° C. to 25° C.
3 . The binder for secondary batteries according to claim 1 , wherein the second glass transition temperature ranges from 26° C. to 100° C., preferably from 26° C. to 90° C.
4 . The binder for secondary batteries according to claim 1 , wherein the organic polymer comprises an acrylate copolymer, and/or, the organic polymer comprises at least one of an ester group, a carboxyl group, an acrylamide group, a carbonyl group, an amide group and a nitrile group.
5 . The binder for secondary batteries according to claim 1 , wherein the shape of the binder comprises a spherical shape.
6 . The binder for secondary batteries according to claim 1 , wherein the binder has a volume-based particle size Dv50 of 1 μm to 15 μm, preferably 5 μm to 10 μm, and/or, the binder has a number-based particle size Dn10 of 1 μm to 5 μm, preferably 1 μm to 3 μm.
7 . The binder for secondary batteries according to claim 1 , wherein the organic polymer comprises a first polymer and a second polymer, the first polymer and the second polymer both comprising an acrylate copolymer.
8 . The binder for secondary batteries according to claim 7 , wherein a mass ratio of the first polymer to the second polymer has a range value of 1:(0.1-10), preferably 1:(0.5-3).
9 . The binder for secondary batteries according to claim 7 , wherein the first polymer and/or the second polymer comprises a first polymeric monomer, the first polymeric monomer having a structure comprising:
wherein R1 comprises a hydrogen atom or an alkyl group with 1-12 carbon atoms, and R2 comprises an alkyl group with 1-12 carbon atoms.
10 . The binder for secondary batteries according to claim 9 , wherein the first polymeric monomer comprises one or more of methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, tert-butyl acrylate, n-propyl acrylate, cyclohexyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, 2-ethylhexyl methacrylate, isobornyl methacrylate, lauryl methacrylate, 2-hydroxyethyl methacrylate, and 2-hydroxypropyl methacrylate.
11 . The binder for secondary batteries according to claim 7 , wherein the first polymer comprises a second polymeric monomer, the second polymeric monomer having a structure comprising:
wherein R3 comprises a hydrogen atom, and a substituted or unsubstituted alkyl group with 1-6 carbon atoms.
12 . The binder for secondary batteries according to claim 11 , wherein the second polymeric monomer comprises one or more of acrylic acid, methacrylic acid, butenoic acid, and heptenoic acid.
13 . The binder for secondary batteries according to claim 7 , wherein the first polymer and/or the second polymer comprises a third polymeric monomer, the third polymeric monomer having a structure comprising:
wherein R4 comprises a hydrogen atom or an alkyl group with 1-6 carbon atoms and R5 comprises a hydrogen atom, an alkyl group with 1-6 carbon atoms substituted with a hydroxyl group or an alkoxy group with 1-6 carbon atoms.
14 . The binder for secondary batteries according to claim 13 , wherein the third polymeric monomer comprises one or more of acrylamide, N-hydroxymethylacrylamide and N-butoxymethylacrylamide.
15 . The binder for secondary batteries according to claim 7 , wherein the second polymer comprises a fourth polymeric monomer, the fourth polymeric monomer having a structure comprising:
wherein R6 comprises a hydrogen atom or an alkyl group with 1-6 carbon atoms.
16 . The binder for secondary batteries according to claim 15 , wherein the fourth polymeric monomer comprises one or more of acrylonitrile and methacrylonitrile.
17 . A preparation method of a binder for secondary batteries according to claim 1 , comprising:
blending and stirring water, an emulsifier, an initiator, and constituent monomers of the first polymer, and heating and reacting to obtain a first polymer emulsion;
blending and stirring water, an emulsifier, an initiator, and constituent monomers of the second polymer, and heating and reacting to obtain a second polymer emulsion; and
mixing and stirring the first polymer emulsion and the second polymer emulsion, and performing spray drying to obtain the binder.
18 . A separator, comprising the binder for secondary batteries according to claim 1 .
19 . A battery cell, comprising the separator according to claim 18 .
20 . A battery, comprising the battery cell according to claim 19 .
21 . An electrical apparatus, comprising the battery cell according to claim 19 .