IP Library Patent Application 18628843
Patent Application
App. No. 18/628,843

SEPARATOR, PREPARATION METHOD THEREFOR, AND RELATED SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND POWER CONSUMING DEVICE THEREOF

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Patent No.
US None
App. No.
18/628,843
Abstract

The present application relates to a separator, comprising: two layers of substrate and a coating formed between the two layers of substrate, wherein the coating contains inorganic particles, and 30 wt % to 70 wt % of the inorganic particles have a surface coated with a coating layer, and 70 wt % to 30 wt % of the inorganic particles have an uncoated surface, based on the total weight of the inorganic particle. The separator may realize a high mechanical strength, a high wettability, and a good interfacial bonding, and may also effectively inhibit the growth of lithium dendrites, and thus improve the cycling performance of a secondary battery.

Claims (33)

1 . A separator, comprising: two layers of substrate and a coating formed between the two layers of substrate, wherein the coating contains inorganic particles, and 30 wt % to 70 wt % of the inorganic particles have a surface coated with a coating layer, and 70 wt % to 30 wt % of the inorganic particles have an uncoated surface, based on a total weight of the inorganic particle.

2 . The separator according to claim 1 , wherein the inorganic particles are selected from at least one of Si, an Si oxide, an Si nitride, an Fe oxide, an Fe nitride, an Fe oxysalt, an Sn oxide, a Ti oxide, a Ti nitride, a Cu oxide, a Cu nitride, an Mn oxide, a Ge oxide, an Ni oxide, ZrO 2 , ZnO and AIN.

3 . The separator according to claim 1 , wherein the inorganic particles have a particle size Dv50 of 0.01 μm to 10 μm.

4 . The separator according to claim 1 , wherein a material forming the coating layer is selected from at least one of polyvinylidene fluoride (PVDF), polydopamine (PDA), polyaniline (PAn), polyimide (PI), and polymethyl methacrylate (PMMA).

5 . The separator according to claim 1 , wherein in the inorganic particles having a surface coated with the coating layer, a mass ratio of the coating layer to a coated inorganic particle is (0.05-2):1.

6 . The separator according to claim 1 , wherein the coating layer has a thickness of 3 nm to 10 nm.

7 . The separator according to claim 1 , wherein the coating has a thickness of 1 μm to 10 μm;

the coating has a coating amount of 5 g/m 2 to 50 g/m 2 ; and/or

the separator has a thickness of 10 μm to 20 μm.

8 . The separator according to claim 1 , wherein the coating contains 80 wt % to 99 wt % of the inorganic particle;

1 wt % to 5 wt % of a binder;

1 wt % to 3 wt % of a dispersant;

0.1 wt % to 1 wt % of a thickener, all based on a total weight of the coating;

the binder is selected from at least one of sodium carboxymethylcellulose (CMC) and styrene butadiene rubber (SBR);

the dispersant is selected from at least one of hydrolytic polymaleic anhydride, an acrylic block polymer, a polyester block polymer, a polyethylene glycol-type polyol, and a polyethyleneimine derivative; and/or

the thickener is selected from at least one of sodium carboxymethylcellulose, methylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, polyacrylate, polyurethane, and polyether.

9 . The separator according to claim 1 , wherein a material forming the substrate is selected from at least one of polypropylene, polyethylene, polyamide, polyester, polytetrafluoroethylene, polyvinylidene fluoride, and polyvinyl chloride;

the substrate has a thickness of 3 um to 30 um;

the substrate is a porous film having a porosity of 30% to 80%; and/or

the material forming the substrate has a number-average molecular weight of 100,000-1,000,000.

10 . A method for preparing a separator, wherein the separator comprises: two layers of substrate and a coating formed between the two layers of substrate, wherein the coating contains inorganic particles, and 30 wt % to 70 wt % of the inorganic particles have a surface coated with a coating layer, and 70 wt % to 30 wt % of the inorganic particles have an uncoated surface, based on a total weight of the inorganic particle;

the method comprises the following:

(1) uniformly dispersing the inorganic particle in an organic solvent to obtain a dispersion of the inorganic particle;

(2) adding a material forming the coating layer to the dispersion obtained in step (1) to obtain the inorganic particle having a surface coated with the coating layer;

(3) adding the inorganic particle having a surface coated with the coating layer obtained in step (2) and the inorganic particle having an uncoated surface to an organic solvent, adding a binder, a dispersant, and a thickener, and then stirring same until uniform to obtain a coating material for coating the substrate; and

(4) uniformly coating one substrate with the coating material obtained in step (3), and then covering a side, coated with the coating material, of the substrate with the other substrate to obtain the separator.

11 . The method according to claim 10 , wherein the method satisfies one or more of the following (a)-(e):

(a) in step (1), a weight ratio of the inorganic particle to the organic solvent is 1:(15-45);

(b) in step (2), a weight ratio of the material forming the coating layer to the inorganic particle is (1-10):1, optionally (2-6):1; and/or, the material forming the coating layer is added to the dispersion obtained in step (1), and stirred until uniform, followed by centrifuging, drying, and grinding;

(c) in step (3), a solid content of the coating material is 30 wt % to 60 wt %;

(d) the organic solvent in steps (1) and (3) may be the same or different, and optionally, the organic solvent is selected from at least one of N,N-dimethylformamide (DMF), N-methylpyrrolidone (NMP), N,N-dimethylacetamide (DMAC), dimethylsulfoxide (DMSO), and tetrahydrofuran (THF); and

(e) in step (4), after the other substrate covers the side, coated with the coating material, of the substrate, hot-pressing and vacuum-drying are performed; and/or, the hot-pressing is performed by means of a hot press at a pressure of 3 MPa to 8 MPa, and/or at a temperature of 100° C. to 150° C., and/or for 1 minute to 10 minutes; and optionally, the drying is performed at a temperature of 80° C. to 120° C.

12 . A secondary battery, comprising a separator according to claim 1 , or a separator obtained by a method according to claim 10 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 6, 2024
From: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
To: CONTEMPORARY AMPEREX TECHNOLOGY (HONG KONG) LIMITED
Reel/Frame 068338/0402 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2024
From: LIU, FENG; FAN, YULEI; ZHONG, WEI; GE, XIAOMING; OUYANG, CHUYING
To: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
Reel/Frame 067029/0102 →