METHOD FOR PREPARING FUEL CELL CATALYST ELECTRODE AND FUEL CELL CATALYST ELECTRODE PREPARED THEREFROM
The present invention relates to a method for preparing a fuel cell catalyst electrode, which includes dispersing and mixing a first catalyst, a binder, and a first solvent to prepare a first catalyst slurry, heat-treating and pulverizing the first catalyst slurry to prepare a first catalyst powder, dispersing and mixing a second catalyst, a binder, and a second solvent to prepare a second catalyst slurry, heat-treating and pulverizing the second catalyst slurry to prepare a second catalyst powder, dispersing the first catalyst powder and the second catalyst powder in a third solvent to prepare a third catalyst slurry, and applying or transferring the third catalyst slurry onto a substrate to prepare an electrode having a catalyst layer formed therein.
1 . A method for preparing a fuel cell catalyst electrode, the method comprising:
dispersing and mixing a first catalyst, a binder, and a first solvent to prepare a first catalyst slurry (S 10 );
heat-treating and pulverizing the first catalyst slurry to prepare a first catalyst powder (S 20 );
dispersing and mixing a second catalyst, a binder, and a second solvent to prepare a second catalyst slurry (S 30 );
heat-treating and pulverizing the second catalyst slurry to prepare a second catalyst powder (S 40 );
dispersing the first catalyst powder and the second catalyst powder in a third solvent to prepare a third catalyst slurry (S 50 ); and
applying or transferring the third catalyst slurry onto a substrate to prepare an electrode having a catalyst layer formed therein (S 60 ),
wherein in the step (S 50 ), the first catalyst powder and the second catalyst powder are dispersed in a weight ratio of 100:5 to 100:60 in the third solvent.
2 . The method of claim 1 , wherein the first catalyst comprises platinum or a platinum-based alloy, and
the platinum-based alloy is an alloy of platinum and at least one selected from gold, silver, copper, palladium, tin, iridium, rhodium, ruthenium, iron, cobalt, nickel, chromium, tungsten, manganese, and vanadium.
3 . The method of claim 1 , wherein the binders of the steps (S 10 ) and (S 30 ) each include an ion conductive polymer.
4 . The method of claim 1 , wherein the second catalyst comprises a supported catalyst in which a catalyst metal is supported on a support element.
5 . The method of claim 4 , wherein the catalyst metal supported on the supported catalyst is at least one selected from the group consisting of platinum, gold, silver, copper, palladium, tin, iridium, rhodium, ruthenium, iron, cobalt, nickel, chromium, tungsten, manganese, and vanadium.
6 . The method of claim 4 , wherein the support element is a crystalline carbon support element, and the crystalline carbon support element has a vertical crystal size of 2.5 to 4.5 nm and a Brunauer-Emmett-Teller (BET) specific surface area of 100 to 600 m 2 /g.
7 . The method of claim 1 , wherein the first catalyst powder and the second catalyst powder are each formed to be coated with a binder.
8 . The method of claim 1 , wherein in the step (S 50 ), the first catalyst powder and the second catalyst powder are dispersed in a weight ratio of 100:10 to 100:45 in the third solvent.
9 . The method of claim 1 , wherein the first catalyst comprises platinum or a platinum-based alloy,
the platinum-based alloy is an alloy of platinum and at least one selected from gold, silver, copper, palladium, tin, iridium, rhodium, ruthenium, iron, cobalt, nickel, chromium, tungsten, manganese, and vanadium,
the second catalyst comprises a supported catalyst in which a catalyst metal is supported on a support element, and
the catalyst metal supported on the supported catalyst is at least one selected from the group consisting of platinum, gold, silver, copper, palladium, tin, iridium, rhodium, ruthenium, iron, cobalt, nickel, chromium, tungsten, manganese, and vanadium.
10 . A fuel cell catalyst electrode comprising:
a substrate; and
a catalyst layer disposed on at least one surface of the substrate,
wherein the catalyst layer comprises a first catalyst powder and a second catalyst powder, and
the first catalyst powder and the second catalyst powder satisfy a weight ratio of 100:5 to 100:60.
11 . The fuel cell catalyst electrode of claim 10 , wherein the first catalyst powder is formed to have a binder applied onto the first catalyst, and the second catalyst powder is formed to have a binder applied onto the second catalyst.
12 . The fuel cell catalyst electrode of claim 10 , wherein the first catalyst powder and the second catalyst powder satisfy a weight ratio of 100:10 to 100:45.