MEDIA LUBRICANTS SYNTHESIS WITH CLICK CHEMISTRY
A lubricant for magnetic media is synthesized using click chemistry. In one aspect the lubricant is according to general formula (I): where Rc is a fluorinated or non-fluorinated divalent linking segment; where each Re 1 and Re 2 is a click linker moiety that can be triazole or sulfone; n is from 2 to 50; where each Rb 1 and Rb 2 is an optionally non-fluorinated divalent linking segment optionally comprising at least one least one first anchoring functional group engageable with a protective overcoat of a magnetic recording medium; and where each of Rv 1 and Rv 2 , when present, independently comprises a moiety having at least one second anchoring functional group engageable with the protective overcoat of the magnetic recording medium. The click linker moiety may also functional as an anchoring functional group.
1 . A lubricant comprising a plurality of segments according to general formula (I):
wherein Rc is a fluorinated or non-fluorinated divalent linking segment optionally comprising at least one least one first anchoring functional group engageable with a protective overcoat of a magnetic recording medium;
wherein each Re 1 and Re 2 is a click linker moiety;
n is from 2 to 50;
wherein each Rb 1 and Rb 2 is an optionally non-fluorinated divalent linking segment optionally comprising at least one least one first anchoring functional group engageable with a protective overcoat of a magnetic recording medium;
wherein each Re 1 and Re 2 is a click linker moiety;
n is from 2 to 50; and
wherein each of Rv 1 and Rv 2 , when present, independently comprises a moiety having at least one second anchoring functional group engageable with the protective overcoat of the magnetic recording medium.
2 . The lubricant of claim 1 , wherein the click linker moiety is:
3 . The lubricant of claim 1 , wherein the click linker moiety is:
4 . The lubricant of claim 1 , wherein the at least one first and second anchoring functional groups each comprises at least one of B, Si, a pnictogen, a chalcogen, a halogen, —OR*, —NR* 2 , —NR*—CO—R*, —O—CO—R*, —CO—O—R*, —SeR*, —TeR*, —PR* 2 ,—PO—(OR*) 2 , —O—PO—(OR*) 2 , —N═P(NR* 2 ) 3 , —AsR* 2 , —SR*, —SO 2 —(OR*) 2 , —BR* 2 , —SiR* 3 , —(CH 2 ) q —SiR* 3 , —(CF 2 ) q —SiR* 3 , or a combination thereof, wherein q is 1 to 10 and each R* is, independently, a hydrogen, B, Si, a pnictogen, a chalcogen, a halogen, a saturated C 1 -C 50 radical, an unsaturated C 2 -C 50 radical, an aromatic C 4 -C 50 radical, a polycyclic aromatic C 5 -C 50 radical, a heteroaromatic C 5 -C 50 radical, an alicyclic C 3 -C 50 radical, and/or a heterocyclic C 2 -C 50 radical, and wherein two or more R* may join together to form a ring structure.
5 . The lubricant of claim 1 , wherein the at least one first and second anchoring functional groups each comprises a hydroxyl (—OH) moiety.
6 . The lubricant of claim 1 , wherein the at least one first and second anchoring functional groups are not present.
7 . The lubricant of claim 1 , having the formula (V):
where PFPE is a perfluorinated polyether and each R is one of an alkyl ether moiety, a fluoroalkyl ether moiety, a fluoroalkenyl ether moiety, a perfluoroalkyl ether moiety, a perfluoroalkenyl ether moiety, or a combination thereof.
8 . The lubricant of claim 1 , having the formula (IX):
where each R is one of an alkyl ether moiety, a fluoroalkyl ether moiety, a fluoroalkenyl ether moiety, a perfluoroalkyl ether moiety, a perfluoroalkenyl ether moiety, or a combination thereof; D is a perfluoroether group, n is from 2 to 50 and Me is methyl.
9 . The lubricant of claim 1 , having the formula (X):
where each R is one of an alkyl ether moiety, a fluoroalkyl ether moiety, a fluoroalkenyl ether moiety, a perfluoroalkyl ether moiety, a perfluoroalkenyl ether moiety, or a combination thereof, D is a perfluoroether group, n is from 2 to 50 and each EG is an end group comprising an aromatic moiety, a substituted or unsubstituted alkyl moiety, alkenyl moiety, fluoroalkyl ether moiety, fluoroalkenyl ether moiety, perfluoroalkyl ether moiety, perfluoroalkenyl ether moiety, or a combination thereof.
10 . A magnetic recording medium, comprising:
a magnetic recording layer on a substrate;
a protective overcoat on the magnetic recording layer; and
a lubricant layer comprising the lubricant according to claim 1 on the protective overcoat.
11 . A data storage system, comprising:
at least one magnetic head;
a magnetic recording medium including the lubricant of claim 1 ;
a drive mechanism for positioning the at least one magnetic head over the magnetic recording medium; and
a controller electrically coupled to the at least one magnetic head for controlling operation of the at least one magnetic head.
12 . A lubricant having the formula (Ia):
where Rc is a fluorinated or non-fluorinated trivalent, tetravalent, pentavalent, hexavalent, heptavalent, or octavalent linking segment optionally comprising at least one first anchoring functional group engageable with a protective overcoat of a magnetic recording medium;
wherein each Re is a click linker moiety;
each Rb is a perfluorinated polyether optionally having an anchoring functional group engageable with a protective overcoat of a magnetic recording medium;
n is 2; and
Rv, if present, is an anchoring functional group.
13 . The lubricant of claim 12 , wherein Rv is not present.
14 . The lubricant of claim 12 , wherein the click linker moiety is:
15 . The lubricant of claim 12 , wherein the click linker moiety is:
16 . The lubricant of claim 12 , wherein the anchoring functional groups, if present, each comprises at least one of B, Si, a pnictogen, a chalcogen, a halogen, —OR*, —NR* 2 , —NR*—CO—R*, —O—CO—R*, —CO—O—R*, —SeR*, —TeR*, —PR* 2 , —PO—(OR*) 2 , —O—PO—(OR*) 2 , —N═P(NR* 2 ) 3 , —AsR* 2 , —SR*, —SO 2 —(OR*) 2 , —BR* 2 , —SiR* 3 , —(CH 2 ) q —SiR* 3 , —(CF 2 ) q —SiR* 3 , or a combination thereof, wherein q is 1 to 10 and each R* is, independently, a hydrogen, B, Si, a pnictogen, a chalcogen, a halogen, a saturated C 1 -C 50 radical, an unsaturated C 2 -C 50 radical, an aromatic C 4 -C 50 radical, a polycyclic aromatic C 5 -C 50 radical, a heteroaromatic C 5 -C 50 radical, an alicyclic C 3 -C 50 radical, and/or a heterocyclic C 2 -C 50 radical, and wherein two or more R* may join together to form a ring structure.
17 . The lubricant of claim 12 , wherein the anchoring functional groups, if present, each comprises a hydroxyl (—OH) moiety.
18 . The lubricant of claim 12 , wherein the anchoring functional groups are not present.
19 . A magnetic recording medium, comprising:
a magnetic recording layer on a substrate;
a protective overcoat on the magnetic recording layer; and
a lubricant layer comprising the lubricant according to claim 12 on the protective overcoat.
20 . A data storage system, comprising:
at least one magnetic head;
a magnetic recording medium including the lubricant of claim 12 ;
a drive mechanism for positioning the at least one magnetic head over the magnetic recording medium; and
a controller electrically coupled to the at least one magnetic head for controlling operation of the at least one magnetic head.