SEPARATOR AND PREPARATION METHOD THEREFOR, BATTERY, AND ELECTRIC APPARATUS
This application discloses a separator and a preparation method therefor, a battery, and an electric apparatus. The coating is formed on at least part of a surface of the substrate, the coating includes composite particles, first inorganic particles, and a binder, the composite particles form bulges on a surface of the coating, the composite particles include polyacrylate particles and ion-conducting particles, and the ion-conducting particle is present between at least two polyacrylate particles. A mass ratio of the first inorganic particles to the ion-conducting particles is 1:0.007-0.06.
1 . A separator, comprising:
a substrate; and
a coating, wherein the coating is formed on at least part of a surface of the substrate, the coating comprises composite particles, first inorganic particles, and a binder, the composite particles form bulges on a surface of the coating, the composite particles comprise polyacrylate particles and ion-conducting particles, and the ion-conducting particle is present between at least two of the polyacrylate particles;
wherein a mass ratio of the first inorganic particles to the ion-conducting particles is 1:0.007-0.06.
2 . The separator according to claim 1 , wherein based on mass of the coating, a percentage of the first inorganic particles is 50%-70%, preferably 55%-65%.
3 . The separator according to claim 1 , wherein based on the mass of the coating, a percentage of the ion-conducting particles is 0.5%-3%, preferably 0.6%-1.2%.
4 . The separator according to claim 1 , wherein a dielectric constant of the ion-conducting particles is not less than 5, preferably not less than 10.
5 . The separator according to claim 1 , wherein the ion-conducting particles comprise at least one of second inorganic particles and organic-inorganic hybrid composite particles.
6 . The separator according to claim 5 , wherein the second inorganic particles comprise at least one of BaTiO 3 , Pb(Zr,Ti)O 3 (PZT), Pb 1-x La x Zr 1-y Ti y O 3 (PLZT), PB(Mg 3 Nb 2/3 )O 3 —PbTiO 3 (PMN-PT), HfO 2 , SrTiO 3 , SnO 2 , CeO 2 , MgO, NiO, CaO, ZnO, ZrO 2 , Y 2 O 3 , Al 2 O 3 , TiO 2 , SiC, AlO(OH), Al 2 O 3 ·H 2 O, Li 3 PO 4 , Li x Ti y (PO 4 ) 3 , γ-AlOOH, BaSO 4 , Mg(OH) 2 , SiO 2 , SrTiO 3 , BaTiO 3 , and MgF 2 .
7 . The separator according to claim 1 , wherein the composite particles comprise ion-conducting particles of primary particle morphology.
8 . The separator according to claim 1 , wherein a ratio of D v 50 of the first inorganic particles to D v 50 of the ion-conducting particles of the primary particle morphology is 0.5-200:1, preferably 1-4:1.
9 . The separator according to claim 1 , wherein D v 50 of the first inorganic particles is 0.5 μm-2 μm, preferably 1 μm-2 μm.
10 . The separator according to claim 1 , wherein a mass ratio of the composite particles to the first inorganic particles is (5-30):(50-70).
11 . The separator according to claim 1 , wherein D v 50 of the composite particles is greater than D v 50 of the first inorganic particles.
12 . The separator according to claim 1 , wherein D v 50 of the composite particles is ≥2.5 μm, preferably 2.5 μm-10 μm, more preferably 3 μm-8 μm.
13 . The separator according to claim 1 , wherein the composite particles comprise a first agglomerate, and the first agglomerate comprises at least two ion-conducting particles, wherein the first agglomerate is present on a surface of the bulge.
14 . The separator according to claim 13 , wherein 0.01 μm≤D v 50 of the first agglomerate ≤D v 10 of the composite particles.
15 . The separator according to claim 8 , wherein D v 50 of the ion-conducting particles of the primary particle morphology is 0.01 μm-1 μm, preferably 0.5 μm-1 μm.
16 . The separator according to claim 1 , wherein the composite particles comprise a second agglomerate, and the second agglomerate comprises at least two of the polyacrylate particles.
17 . The separator according to claim 16 , wherein D v 50 of the second agglomerate is 0.3 μm-5 μm, preferably 1 μm-2 μm.
18 . The separator according to claim 1 , wherein the polyacrylate particles comprise polyacrylate particles of primary particle morphology and/or polyacrylate particles of secondary particle morphology.
19 . The separator according to claim 18 , wherein D v 50 of the polyacrylate particles of primary particle morphology is 50 nm-400 nm, preferably 100 nm-200 nm.
20 . The separator according to claim 18 , wherein D v 50 of the polyacrylate particles of secondary particle morphology is 2 μm-15 μm, preferably 5 μm-8 μm.
21 . A battery, comprising the separator according to claim 1 .