SOL-GEL COATING FORMULATIONS AND METHODS TO MITIGATE GALVANIC CORROSION
Durable, pigmented and transparent, inorganic-organic hybrid sol, gel coating materials are provided which mitigate galvanic corrosion of metal substrates. The coating materials are generally an acid catalyzed condensation reaction product comprised of an organic polymeric silane (e.g., a polyol functionalized with a silane through a urethane linkage or a polyamine functionalized with a silane through a urea linkage, such as isocyanatopropyltrimethoxysilane or isocyanatopropyltriethoxysilane), an inorganic metal alkoxide (e.g., silicon alkoxides such as tetraethoxysilane or tetramethoxysilane) and metal oxide nano particles such as silica (SiCte) which may optionally include other additives such as color agents and/or corrosion inhibitors.
1 . A coating formulation to inhibit galvanic corrosion which comprises a galvanic corrosion inhibiting amount of acid catalyzable condensation reactants comprised of:
(i) an organic polymeric silane; and
(ii) an inorganic metal alkoxide.
2 . The coating formulation according to claim 1 , wherein the organic polymeric silane and the inorganic metal alkoxide are present in a weight ratio of the organic polymeric silane to the inorganic metal alkoxide of between about 1:9 to about 9:1.
3 . The coating formulation according to claim 2 , wherein the weight ratio of the organic polymeric silane to the inorganic metal alkoxide is about 3:1.
4 . The coating formulation according to claim 1 , wherein the organic polymeric silane is a silane functionalized polyol or polyamine.
5 . The coating formulation according to claim 1 , wherein the organic polymeric silane is a functionalized polycaprolactone polyol having 2 to 4 hydroxyl groups reacted with an isocyanate-terminated silane.
6 . The coating formulation according to claim 5 , wherein the functionalized polycaprolactone polyol has a molecular weight between 50 and 10,000 g/mol.
7 . The coating formulation according to claim 1 , wherein the organic polymeric silane is a polyurea silane.
8 . The coating formulation according to claim 7 , wherein the polyurea silane is a reaction product of an amine having at least 2 primary or secondary amine groups with an isocyanate-terminated silane.
9 . The coating formulation according to claim 8 , wherein the polyurea silane is a reaction product of diethylenetriamine with an isocyanate-terminated silane.
10 . The coating formulation according to claim 9 , wherein metal alkoxide comprises at least one hydrolyzable compound having at least one silane group represented by the formula Si(R 1 ) x (R 2 ) 4-x per molecule, wherein R 1 represents a C 1 -C 8 alkyl group, an epoxide group, a vinyl group, an acrylic group, R 2 represents a hydrolyzable alkoxy group or halide group, and x is 0, 1, 2 or 3.
11 . The coating formulation according to claim 1 , which further comprises between about 1 to about 50 wt. %, based on total weight of the coating formulation, of metal oxide particles having a formula M x O y , wherein M is selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn, and y is an integer.
12 . The coating formulation according to claim 4 , wherein the metal oxide particles are selected from the group consisting of silica, alumina, titania, and zirconia.
13 . The coating formulation according to claim 5 , wherein the metal oxide particles are substantially spherical nanoparticles having an average diameter of 1 to 10 nm.
14 . The coating formulation according to claim 1 , which further comprises 0.1 to 5.0 wt. %, based on total weight of the coating formulation, of a color agent.
15 . The coating formulation according to claim 7 , wherein the color agent is an organic color pigment or an organic dye.
16 . The coating formulation according to claim 1 , further comprising a corrosion inhibitor.
17 . The coating formulation according to claim 9 , wherein the corrosion inhibitor is selected from the group consisting of compounds having one or more thiol moieties, modified and unmodified hydrotalcite compounds, zinc phosphate, zinc oxide, cerium phosphate, cerium nitrate, cerium oxide, aluminum cerium oxide; strontium aluminum polyphosphate and zinc aluminum polyphosphate.
18 . A method of inhibiting galvanic corrosion of a metal component which comprises:
(a) applying onto a metal component the coating formulation according to claim 1 in the presence of an acid catalyst; and
(b) allowing the coating formulation to cure on the metal component to thereby inhibit galvanic corrosion when the metal component is subsequently brought into contact with a second metal component.
19 . An assembly having inhibited galvanic corrosion comprised of first and second metal components in contact with one another, wherein at least one of the first and second metal components includes a cured coating thereon of an acid catalyzed coating formulation according to claim 1 .
20 . The assembly according to claim 19 , wherein the assembly has reduced galvanic corrosion of about 1% to about 100% as compared to an assembly of the first and second metal components without the cured coating thereon.
21 . An assembly comprising:
first and second metal components in contact with one another, wherein
at least one of the first and second metal components includes a cured coating thereon of an acid catalyzed coating formulation according to claim 1 , and wherein
the coated assembly further comprises a secondary coating which overcoats the cured coating.
22 . A method to impart galvanic protection to a metal assembly comprising first and second metal components in contact with one another comprising:
(a) applying a galvanic protective coating of the coating formulation according to claim 1 onto at least one of the first and second metal components;
(b) joining the first and second metal component in contact with one another to form an assembly thereof;
(c) curing the galvanic protective coating either before or after step (b) to form a cured galvanic protective coating; and
(d) applying a secondary coating over the assembly of the first and second metal components.
23 . A coated metal assembly made by the method according to claim 22 .