HYBRID PHOTOCURABLE COMPOSITION
An actinic radiation curable composition includes one or more oxetane functional compounds; b) one or more epoxy functional compounds; c) one or more (meth) acry late functional compounds; and d) one or more photoinitiators. The oxetane functional compounds are present in the composition at from 55% to 90%, preferably from 60% to 90%, more preferably from 70% to 90%, by weight based on the total weight of the oxetane functional compounds and the epoxy functional compounds in the composition.
1 . An actinic radiation curable composition comprising:
a) one or more oxetane functional compounds;
b) one or more epoxy functional compounds;
c) one or more (meth)acrylate functional compounds;
d) at least one photoinitiator;
wherein the composition comprises from 55% to 90%, by weight of the one or more oxetane functional compounds based on the total weight of the one or more oxetane functional compounds and the one or more epoxy functional compounds in the composition and wherein the composition comprises from 15% to 95% by weight of the one or more (meth)acrylate functional compounds based on the total weight of the composition; and
optionally at least one additive.
2 . The actinic radiation curable composition of claim 1 , wherein the composition comprises from 20% to 90% by weight of the one or more (meth)acrylate functional compounds based on the total weight of the composition.
3 . The actinic radiation curable composition of claim 1 , wherein the composition comprises from 75% to 85% by weight of the one or more oxetane functional compounds based on the total weight of the one or more oxetane functional compounds and the one or more epoxy functional compounds in the composition.
4 . The actinic radiation curable composition of claims 1 , wherein the one or more oxetane functional compounds comprise at least one of a monofunctional oxetane compound or a difunctional oxetane compound.
5 . The actinic radiation curable composition of claims 1 , wherein the one or more epoxy functional compounds comprise at least one of a monofunctional epoxy compound or a difunctional epoxy compound.
6 . The actinic radiation curable composition of claims 1 , wherein the one or more oxetane functional compounds comprise at least one of 3-ethyl-3-hydroxymethyl-oxetane, 3-ethyl-3-[(phenylmethoxy)methyl]-oxetane, bis[1-ethyl (3-oxctanyl) |methyl ether, 1,4-bis[(3-ethyl-3-oxetanylmethoxy)methyl]benzene. 4,4-bis(3-ethyl-3-oxetanyl) methoxymethyl |biphenyl, 3-ethyl-3-(methacryloyloxy)methyloxetane, trimethylolpropane tris(3-ethyl-3-oxetanylmethyl)ether, or combinations thereof.
7 . The actinic radiation curable composition of claims 1 , wherein the one or more epoxy functional compounds comprise at least one of epoxidized vegetable oils, mono-epoxides, di-epoxides, poly-epoxides, alicyclic polyglycidyl compounds, cycloaliphatic polyepoxides, epoxy ethers, aromatic epoxies, aliphatic epoxies, aliphatic glycidyl ethers, linear, branched epoxidized polyenes, or combinations thereof.
8 . The actinic radiation curable composition of claims 1 , wherein the one or more epoxy functional compounds comprise at least one of 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate, bis(3,4-epoxy-cyclohexyl) adipate, 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate modified caprolactone, or combinations thereof.
9 . The actinic radiation curable composition of claim 1 , wherein the epoxide compound and/or the oxctane compound comprises one or more (meth)acrylate functional epoxides, one or more (meth)acrylate functional oxetanes, one or more epoxy functional oxetanes, or a combination thereof.
10 . The actinic radiation curable composition of claims 1 further comprising one or more one thermal initiators.
11 . The actinic radiation curable composition of claims 1 , further comprising one or more hydroxyl functional compounds.
12 . The actinic radiation curable composition of any one of claims claim 1 further comprising at least one filler.
13 . The actinic radiation curable composition of claim 1 , wherein the photoinitiator comprises at least one of a cationic photoinitiator or a free radical photoinitiator.
14 . A method of making a cured material, wherein the method comprises actinic radiation curing the actinic radiation curable composition of claim 1 .
15 . A method for the preparation of a 3D-printed article comprising the steps of:
a) providing a first layer of an actinic radiation curable composition of claims 1 onto a surface;
b) curing the first layer, at least partially, to provide a cured first layer;
c) providing an second layer of the actinic radiation curable composition onto the first cured layer;
d) curing the second layer, at least partially, to provide a cured second layer adhered to the cured first layer;
e) repeating steps c) and d) a desired number of times to build up the 3D-printed article.
16 . The method of claim 15 , further comprising a step f) comprising heating the 3D-printed article to a temperature effective to thermally cure the curable composition.