Filter cake removal reactive treatment fluid with chelating agent and viscoelastic surfactant and methods of using same
A fluid comprising: a base fluid; a chelating agent; a carbonate; an oxidizing salt; an organic acid; a viscoelastic surfactant (VES); and a base, where a viscosity of the fluid is 300 cP (mPa·s) or less at a temperature of 300° F. (148.9° C.) or less, and where a density of the fluid from 9 lb/gal (1.08 kg/L) to 20 lb/gal (2.40 kg/L).
1 . A fluid comprising:
a base fluid;
a chelating agent;
a carbonate;
an oxidizing salt;
oxalic acid at a concentration from 1 wt. % to 15 wt. % of the fluid;
a viscoelastic surfactant (VES); and
a base at a concentration from 0.2 wt. % to 5 wt. % of the fluid,
wherein a viscosity of the fluid is 300 cP (mPa s) or less at a temperature of 300° F. (148.9° C.) or less, and
wherein a density of the fluid is from 9 lb/gal (1.08 kg/L) to 20 lb/gal (2.40 kg/L).
2 . The fluid of claim 1 , wherein the base fluid comprises a brine.
3 . The fluid of claim 2 , wherein a total dissolved solids (TDS) of the brine is from 50,000 ppm to 250,000 ppm.
4 . The fluid of claim 1 , wherein the base fluid comprises potassium chloride, sodium chloride, calcium chloride, calcium bromide, potassium formate, or cesium formate.
5 . The fluid of claim 1 , wherein the density is from 10 lb/gal (1.20 kg/L) to 16 lb/gal (1.92 kg/L).
6 . The fluid of claim 1 , wherein the viscosity is 300 cP (mPa·s) or less at a temperature from 200° F. (93.3° C.) to 300° F. (148.9° C.).
7 . The fluid of claim 1 , wherein the viscosity is from 80 cP (mPa's) to 100 cP (mPa s) at a temperature from 200° F. (93.3° C.) to 300° F. (148.9° C.).
8 . The fluid of claim 1 , wherein the chelating agent comprises an aminopolycarboxylic acid or a salt thereof, and wherein the VES comprises erucylamidopropyl betaine.
9 . The fluid of claim 1 , wherein the carbonate is potassium carbonate or cesium carbonate, and wherein the oxidizing salt comprises a chlorate or bromate.
10 . The fluid of claim 1 , wherein the base comprises potassium hydroxide.
11 . The fluid of claim 1 , further comprising an acid-generating material comprising polylactic acid (PLA), polyglycolic acid (PGA), an orthoester, or a polyanhydride.
12 . A fluid for filter cake removal, the fluid comprising:
a brine at a concentration from 50 weight percent (wt. %) to 70 wt. % of the fluid, the brine comprising calcium chloride or calcium bromide;
diethylenetriamine pentaacetic acid (DTPA) at a concentration from 1 wt. % to 15 wt. % of the fluid;
a carbonate at a concentration from 5 wt. % to 30 wt. % of the fluid;
an oxidizing salt at a concentration from 1 wt. % to 20 wt. % of the fluid;
oxalic acid at a concentration from 1 wt. % to 15 wt. % of the fluid;
a viscoelastic surfactant (VES); and
a base at a concentration from 0.2 wt. % to 5 wt. % of the fluid,
wherein a viscosity of the fluid is 300 cP (mPa s) or less at a temperature of 300° F. (148.9° C.) or less, and
wherein a density of the fluid is from 9 lb/gal (1.08 kg/L) to 20 lb/gal (2.40 kg/L).
13 . The fluid of claim 12 , wherein the density is from 12 lb/gal (1.44 kg/L) to 14 lb/gal (1.68 kg/L)).
14 . The fluid of claim 12 , wherein the viscosity is from 80 cP (mPa·s) to 100 cP (mPa·s) at a temperature from 200° F. (93.3° C.) to 300° F. (148.9° C.).
15 . The fluid of claim 12 , wherein a pH of the fluid is from 9 to 12.
16 . A method of treating a wellbore for filter cake removal, the method comprising:
injecting a reactive treatment fluid into a wellbore in a subterranean formation comprising a filter cake on a wall of the wellbore, the filter cake comprising a barite, the reactive treatment fluid comprising:
a base fluid,
a chelating agent,
a carbonate,
an oxidizing salt,
oxalic acid at a concentration from 1 wt. % to 15 wt. % of the reactive treatment fluid,
a viscoelastic surfactant (VES), and
a base at a concentration from 0.2 wt. % to 5 wt. % of the reactive treatment fluid,
wherein the reactive treatment fluid has a density from 9 lb/gal (1.08 kg/L) to 20 lb/gal (2.40 kg/L) and a viscosity of 300 cP (mPa s) or less at a temperature of 300° F. (148.9° C.) or less;
contacting the reactive treatment fluid with the filter cake in the wellbore, the reactive treatment fluid dissolving or exfoliating the barite from the wall into the reactive treatment fluid; and
recovering the reactive treatment fluid comprising the barite removed from the wall.
17 . The method of claim 16 , further comprising, prior to injecting the reactive treatment fluid into the wellbore, forming the wellbore by drilling, wherein the drilling forms the filter cake in the wellbore.
18 . The method of claim 16 , further comprising providing carbon dioxide (CO 2 ) into the wellbore.
19 . The method of claim 16 , further comprising foaming the reactive treatment fluid with CO 2 .