Silicon dominant anodes containing pyrolyzed carbon
Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes containing pyrolyzed carbon may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a water soluble polymer and may comprise one or more additional materials. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
1. A pyrolyzed battery electrode comprising:
a pyrolyzed electrode coating layer on a current collector, the pyrolyzed electrode coating layer formed from an electrode coating layer comprising silicon, a water soluble polymer, a secondary polymer and a conductive additive;
wherein said water soluble polymer and said secondary polymer are at least partially pyrolyzed into carbon during making of the electrode, thus forming said pyrolyzed electrode coating layer; and
wherein the amount of silicon in the pyrolyzed electrode coating layer is about 95-99% by weight.
2. The pyrolyzed battery electrode according to claim 1 , wherein the amount of silicon in the pyrolyzed electrode coating layer is about 96-99% by weight.
3. The pyrolyzed battery electrode according to claim 2 , wherein the amount of silicon in the pyrolyzed electrode coating layer is about 97-99% by weight.
4. The pyrolyzed battery electrode according to claim 1 , wherein said conductive additive is a carbon additive.
5. The pyrolyzed battery electrode according to claim 4 , wherein said carbon additive is single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), carbon nanofibers, or crosslinked carbon nanotubes (CCN).
6. The pyrolyzed battery electrode according to claim 1 , wherein said water soluble polymer is selected from the group consisting of polyimides, polyamideimides, phenolic resins, polysiloxanes, polyurethanes, polyvinyls, acrylics, polysaccharides, and derivatives thereof.
7. The electrode according to claim 1 , wherein said electrode coating layer further comprises a base.
8. The pyrolyzed battery electrode according to claim 1 , which is pyrolyzed at a temperature between about 400-500 degrees Celsius.
9. A lithium ion battery, comprising a pyrolyzed battery electrode according to claim 1 .
10. A method of forming a pyrolyzed battery electrode comprising a pyrolyzed electrode coating layer on a current collector, the method comprising:
creating an electrode slurry comprising silicon, an water soluble polymer, a secondary polymer and a conductive additive;
fabricating a battery electrode by coating the slurry on a current collector to form an electrode coating layer; and
at least partially pyrolyzing said electrode coating layer into carbon, thus forming a pyrolyzed electrode coating layer;
wherein the amount of silicon in the pyrolyzed electrode coating layer is about 95-99% by weight.
11. The method according to claim 10 , wherein the amount of silicon in the pyrolyzed electrode coating layer is about 96-99% by weight.
12. The method according to claim 11 , wherein the amount of silicon in the pyrolyzed electrode coating layer is about 97-99% by weight.
13. The method according to claim 10 , wherein said conductive additive is a carbon additive.
14. The method according to claim 13 , wherein said carbon additive is single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), carbon nanofibers, or crosslinked carbon nanotubes (CCN).
15. The method according to claim 10 , wherein said water soluble polymer is selected from the group consisting of polyimides, polyamideimides, phenolic resins, polysiloxanes, polyurethanes, polyvinyls, acrylics, polysaccharides, and derivatives thereof.
16. The method according to claim 10 , wherein said electrode coating layer further comprises a base.
17. The method according to claim 10 , wherein said at least partially pyrolyzing is carried out at a temperature between about 400-500 degrees Celsius.