Systems and techniques for polymer degassing
A purge system for a polymerization system may include a purge column including a stripping zone and a stripping fluid distributor below the stripping zone for injecting a stripping fluid including one or more light olefins. A first displacement zone is below the distributor. A second displacement zone is below the first displacement zone. A nitrogen distributor introduces nitrogen in the second displacement zone. Another purge system for a polymerization system may include a fluidized bed separator and a purge column. The fluidized bed separator includes a separator inlet, a stripping fluid inlet, a first stripped fluid outlet, and a separator outlet. The purge column includes a flake inlet, a stripping zone, a stripping fluid distributor below the stripping zone, a stripped flake outlet, and a second stripped fluid outlet for a second stripped fluid from the purge column.
1 . A purge system comprising:
a purge column, the purge column comprising:
a flake inlet for introducing a reactor product stream comprising polymer flakes and one or more heavy hydrocarbons;
a stripping zone, the stripping zone comprising a stripping fluid distributor for injecting a stripping fluid comprising one or more light olefins into the stripping zone and adapted to provide stripped polymer flakes;
a stripping fluid outlet for releasing used stripping fluid from the purge column; and
a conical bottom portion below the stripping fluid distributor;
a displacement unit below the purge column and partially overlapping the conical bottom portion of the purge column, the displacement unit configured to receive stripped polymer flakes from the stripping zone, and further configured to displace at least a portion of residual stripping fluid from the stripped polymer flakes by introducing nitrogen, wherein the displacement unit comprises a first displacement outlet disposed at an upper portion of the displacement unit such that the first displacement outlet is higher than a lower edge of the conical bottom portion of the purge column, the first displacement outlet configured to expel displaced fluid from the displacement unit; and
a stripped flake outlet.
2 . The purge system of claim 1 , wherein the conical bottom portion of the purge column is configured as a displacement zone configured to receive stripped polymer flakes from the stripping zone and to displace at least a portion of residual stripping fluid from the stripped polymer flakes.
3 . The purge system of claim 1 , wherein the displacement unit comprises a first displacement zone proximal to the conical portion of the purge column, and a second displacement zone below the first displacement zone.
4 . The purge system of claim 3 , further comprising a second displacement outlet coupled to the second displacement zone for expelling displaced fluid from the first displacement zone and the second displacement zone.
5 . The purge system of claim 4 , wherein:
the first displacement zone has a conical lower portion,
the second displacement zone partially overlaps the conical lower portion of the first displacement zone, and
the second displacement outlet is disposed at a position higher than a lower edge of the conical lower portion of the first displacement zone.
6 . The purge system of claim 1 , further comprising one or more of an olefin sensor, a nitrogen sensor, a flow sensor, or a pressure sensor at one or more predetermined locations of the purge system.
7 . The purge system of claim 1 , wherein the flake inlet is at or adjacent a top of the purge column.
8 . The purge system of claim 1 , wherein the stripping fluid distributor is at or adjacent a bottom of the purge column.
9 . A polymerization system comprising:
a polymerization reactor; and
the purge system of claim 1 coupled to the polymerization reactor.
10 . The polymerization system of claim 9 , wherein the polymerization reactor is a fluidized bed gas phase reactor, a liquid phase reactor, or a loop slurry reactor.
11 . A method of operating a polymerization system comprising a polymerization reactor coupled to the purge system of claim 1 , the method comprising:
contacting one or more olefin monomers and a catalyst in the presence of one or more heavy hydrocarbons in a polymerization reactor to form a reactor product comprising polymer flakes and residual heavy hydrocarbons;
introducing the reactor product in the stripping zone of the purge system;
stripping the one or more heavy hydrocarbons from the polymer flakes of the reactor product in the purge system by distributing a stripping fluid comprising one or more light olefins through the stripping zone to provide stripped polymer flakes; and
displacing residual stripping fluid from the stripped polymer flakes by introducing nitrogen in the displacement unit.
12 . The method of claim 11 , wherein the one or more olefin monomers comprise the one or more light olefins.
13 . The method of claim 12 , wherein the one or more olefin monomers consist of or consist essentially of the one or more light olefins.
14 . The method of claim 11 , further comprising recycling the one or more olefin monomers from the stripping fluid in the stripping zone to the polymerization reactor.
15 . The method of claim 11 , wherein the stripping fluid consists of or consists essentially of ethylene.
16 . The method of claim 15 , wherein the ethylene is not pre-treated for catalyst poisons, and wherein catalyst poisons present in the ethylene are at least partially deactivated by contact with residual catalyst present in the polymer flakes in the purge system.
17 . The method of claim 11 , wherein the one or more heavy hydrocarbons comprise one or more of 1-butene, 1-hexene, 1-octene, 1-decene, butanes, or pentanes.
18 . The method of claim 11 , wherein the stripped polymer flakes in the displacement unit comprise less than 25 ppmw of the heavy hydrocarbons.
19 . The method of claim 11 , wherein the displacement unit comprises a first displacement zone, a second displacement zone below the first displacement zone, and a third displacement zone below the second displacement zone,
wherein the stripped polymer flakes in one or more of the first displacement zone, the second displacement zone, or the third displacement zone comprise less than 5 ppmw of the stripping fluid.
20 . The method of claim 19 , wherein the stripped polymer flakes in the third displacement zone comprise less than 2 ppmw of the stripping fluid.