A DIESEL OXIDATION CATALYST AND A METHOD FOR ITS MANUFACTURE
A method for the manufacture of a diesel oxidation catalyst comprises: (i) providing a carrier substrate; (ii) forming one or more platinum-group-metal-containing washcoat layers each comprising a refractory metal oxide support material on the carrier substrate to provide a first coated substrate; (iii) subjecting the first coated substrate to a first heat treatment to form a heat-treated coated substrate, wherein the first heat treatment comprises heating the first coated substrate to a first maximum temperature and holding the first coated substrate at the first maximum temperature; (iv) depositing a platinum-group-metal-containing composition comprising a refractory metal oxide support material on at least a portion of the heat-treated coated substrate to form a second coated substrate; and (v) subjecting the second coated substrate to a second heat treatment to form the diesel oxidation catalyst, wherein the second heat treatment comprises heating the second coated substrate to a second maximum temperature and holding the second coated substrate at the second maximum temperature; wherein the first maximum temperature is at least 600° C. and wherein the second maximum temperature is at least 25° C. lower than the first maximum temperature.
1 . A method for the manufacture of a diesel oxidation catalyst, the method comprising:
(i) providing a carrier substrate;
(ii) forming one or more platinum-group-metal-containing washcoat layers each comprising a refractory metal oxide support material on the carrier substrate to provide a first coated substrate;
(iii) subjecting the first coated substrate to a first heat treatment to form a heat-treated coated substrate, wherein the first heat treatment comprises heating the first coated substrate to a first maximum temperature and holding the first coated substrate at the first maximum temperature;
(iv) depositing a platinum-group-metal-containing composition comprising a refractory metal oxide support material on at least a portion of the heat-treated coated substrate to form a second coated substrate; and
(v) subjecting the second coated substrate to a second heat treatment to form the diesel oxidation catalyst, wherein the second heat treatment comprises heating the second coated substrate to a second maximum temperature and holding the second coated substrate at the second maximum temperature; wherein the first maximum temperature is at least 600° C. and wherein the second maximum temperature is at least 25° C. lower than the first maximum temperature.
2 . The method according to claim 1 , wherein the first heat treatment is conducted under a moisture-containing atmosphere.
3 . The method according to claim 1 , wherein the first heat treatment is performed:
(a) with the first maximum temperature of from 625 to 750° C., preferably from 650 to 700° C.; and/or
(b) with the first coated substrate held at the first maximum temperature for at least 30 minutes, preferably for from 1 hour to 3 hours; and/or
(c) under conditions of 5 to 15 wt % H 2 O.
4 . The method according to claim 1 , wherein the second heat treatment is performed:
(a) with the second maximum temperature of from 400 to 575° C., preferably from 450 to 550° C.; and/or
(b) with the second coated substrate held at the second maximum temperature for at least 30 minutes, preferably for from 1 hour to 3 hours.
5 . The method according to claim 1 , wherein the carrier substrate is a flow-through substrate.
6 . The method according claim 1 , wherein the one or more platinum-group-metal-containing washcoat layers on the carrier substrate comprise Pt and/or Pd.
7 . The method according to claim 1 , wherein the one or more platinum-group-metal-containing washcoat layers on the carrier substrate further comprises an alkaline earth metal, preferably strontium and/or barium.
8 . The method according to claim 1 , wherein the coated substrate has a continuous platinum-group-metal-containing coating extending from an inlet end to the outlet end of the carrier substrate.
9 . The method according to claim 8 , wherein the continuous platinum-group-metal-containing coating is zoned, wherein an inlet zone comprises Pt and Pd, and whereby an outlet zone comprises Pt and, optionally Pd, and wherein:
(i) the outlet zone has a lesser loading in g/in 3 of Pt than the inlet zone, or
(ii) the outlet zone has a greater loading in g/in 3 of Pt than the inlet zone.
10 . The method according to claim 9 , wherein the continuous platinum-group-metal-containing coating consists of the inlet and outlet zones.
11 . The method according to claim 1 , wherein step (iv) comprises:
(I) applying a platinum-group-metal-containing washcoat to the first coated substrate, preferably forming a washcoat zone extending from an inlet end of the substrate; or
(II) impregnating the first coated substrate with a solution of a platinum-group-metal-containing salt, preferably forming a platinum-group-metal-impregnated zone extending from an inlet end of the substrate.
12 . The method according to claim 1 , wherein the heat-treated coated substrate comprises platinum-group-metal particulates having a mean particulate size (D50) greater than 10 nm, preferably greater than 20 nm, as determined by TEM.
13 . The method according to claim 1 , wherein the diesel oxidation catalyst comprises a layer or zone formed in step (iv) which comprises platinum-group-metal particulates, said particulates having a D90 particulate size less than 15 nm, preferably less than 10 nm as determined by TEM.
14 . A diesel oxidation catalyst article comprising a flow-through carrier substrate having an aged platinum-group-metal-containing washcoat layer thereon, and a fresh platinum-group-metal-containing composition deposited on an inlet end thereof, wherein the aged platinum-group-metal-containing washcoat layer comprises platinum-group-metal particulates having a mean particulate size (D50) greater than 10 nm, as determined by TEM, and wherein the fresh platinum-group-metal-containing composition comprises platinum-group-metal particulates, said particulates having a D90 particulate size less than 10 nm, as determined by TEM.
15 . A diesel oxidation catalyst article comprising a flow-through carrier substrate having an aged platinum-group-metal-containing washcoat layer thereon, and a fresh platinum-group-metal-containing composition deposited on an inlet end thereof, wherein the aged platinum-group-metal-containing washcoat layer comprises platinum-group-metal particulates having a mean particulate size (D50) greater than 10 nm, as determined by TEM, and wherein the fresh platinum-group-metal-containing composition comprises platinum-group-metal particulates, said particulates having a D90 particulate size less than 10 nm, as determined by TEM, obtained by or obtainable by the method according to claim 1 .
16 . An exhaust gas treatment system comprising the diesel oxidation catalyst according to claim 14 arranged upstream of:
(A) a soot filter;
(B) an SCR catalyst article;
(C) an SCRF catalyst article;
(D) a catalysed soot filter;
(E) a soot filter and then an SCR catalyst article; or
(F) a catalysed soot filer and then an SCR catalyst article.
17 . A diesel combustion and exhaust gas treatment system comprising a diesel combustion engine and the exhaust system according to claim 16 .
18 . A method for the manufacture of an exhaust gas treatment system comprising a diesel oxidation catalyst article comprising a flow-through carrier substrate having an aged platinum-group-metal-containing washcoat layer thereon, and a fresh platinum-group-metal-containing composition deposited on an inlet end thereof, wherein the aged platinum-group-metal-containing washcoat layer comprises platinum-group-metal particulates having a mean particulate size (D50) greater than 10 nm, as determined by TEM, and wherein the fresh platinum-group-metal-containing composition comprises platinum-group-metal particulates, said particulates having a D90 particulate size less than 10 nm, as determined by TEM, arranged upstream of:
(A) a soot filter;
(B) an SCR catalyst article;
(C) an SCRF catalyst article;
(D) a catalysed soot filter;
(E) a soot filter and then an SCR catalyst article; or
(F) a catalysed soot filer and then an SCR catalyst article, and
the method comprising, forming a diesel oxidation catalyst according to the method of claim 1 and arranging this upstream of any of (A) to (F).