Solvent Composition and Process for Cleaning Contaminated Industrial Equipment
A method, system and composition for decontaminating a vessel. In an embodiment, a solvent composition for decontamination includes an amine oxide, polydimethylsiloxane, and water.
1 . A system for decontaminating a vessel, comprising:
a steam line,
a solvent composition comprising steam and one or more amine oxides defined according to the formula:
wherein n is from 5 to 22,
wherein the one or more amine oxides have a boiling that matches a boiling point of the steam, and
wherein the solvent composition is substantially vaporized in the steam within the steam line.
2 . The system of claim 1 , further comprising an anti-foaming agent.
3 . The system of claim 2 , wherein the anti-foaming agent comprises polydimethylsiloxane.
4 . The solvent of claim 3 , wherein the polydimethylsiloxane is present in an amount of about 1 ppm to about 100 ppm.
5 . The system of claim 1 , wherein each of the one or more amine oxides comprises N,N dimethyl decylamine; N,N dimethyl dodecylamine; N,N, dimethyl tetradecylamine;
N,N dimethyl hexadecylamine; N,N dimethyl octadecylamine; or a combination thereof
6 . The system of claim 1 , wherein the one or more amine oxides are present in an amount of about 30 ppm to about 2,100 ppm.
7 . The system of claim 1 , further comprising an enzyme blend, wherein the enzyme blend is present in an amount of about 1 ppm to about 100 ppm, and wherein the enzyme blend comprises a lipase, a cellulase, an amylase, a protease, a pectinase, or combinations thereof.
8 . A method of decontaminating a vessel during a refinement process of crude oil and natural gas, comprising:
vaporizing one or more amine oxides within steam in a steam line to form a solvent composition, wherein the one or more amine oxides are defined according to the formula:
wherein n is from 5 to 22,
wherein the one or more amine oxides have a boiling that matches a boiling point of the steam;
injecting the solvent composition into the vessel via the steam line; and
allowing the solvent composition to contact at least a portion of contaminants present in the vessel,
wherein the contaminants comprise a hydrocarbon, hydrogen sulfide, a metal sulfide, or combinations thereof.
9 . The method of claim 8 , further comprising an anti-foaming agent.
10 . The method of claim 9 , wherein the anti-foaming agent comprises polydimethylsiloxane.
11 . The method of claim 10 , wherein the polydimethylsiloxane is present in an amount of about 1 ppm to about 100 ppm.
12 . The method of claim 8 , wherein each of the one or more amine oxides comprises N,N dimethyl decylamine; N,N dimethyl dodecylamine; N,N, dimethyl tetradecylamine; N,N dimethyl hexadecylamine; N,N dimethyl octadecylamine; or a combination thereof
13 . The method of claim 8 , wherein the one or more amine oxides are present in an amount of about 30 ppm to about 2,100 ppm.
14 . The method of claim 8 , further comprising an enzyme blend, wherein the enzyme blend is present in an amount of about 1 ppm to about 100 ppm, and wherein the enzyme blend comprises a lipase, a cellulase, an amylase, a protease, a pectinase, or combinations thereof.
15 . A solvent composition comprising:
steam; and
one or more amine oxides defined according to the formula:
wherein n is from 5 to 22,
wherein the one or more amine oxides have a boiling that matches a boiling point of the steam, and
wherein the solvent composition is substantially vaporized in the steam.
16 . The solvent composition of claim 15 , further comprising an anti-foaming agent.
17 . The solvent composition of claim 16 , wherein the anti-foaming agent comprises polydimethylsiloxane.
18 . The solvent composition of claim 17 , wherein the polydimethylsiloxane is present in an amount of about 1 ppm to about 100 ppm.
19 . The solvent composition of claim 15 , wherein each of the one or more amine oxides comprises N,N dimethyl decylamine; N,N dimethyl dodecylamine; N,N, dimethyl tetradecylamine; N,N dimethyl hexadecylamine; N,N dimethyl octadecylamine; or a combination thereof
20 . The solvent composition of claim 15 , wherein the one or more amine oxides are present in an amount of about 30 ppm to about 2,100 ppm.