Methods and apparatus for extracting metals from materials
The present disclosure relates to an apparatus and method for selectively recovering target metals or minerals from a metal or mineral containing mixture/solution.
1. A method for extracting a target metal from a metal or mineral containing solution, the method comprising:
providing an electrochemical reactor, wherein the electrochemical reactor comprises a flow cell comprising a plurality of electrodes comprising one or more anodes and one or more cathodes, each electrode comprising monolithic silicon having a roughened surface;
feeding the metal or mineral containing solution into the electrochemical reactor causing the metal or mineral containing solution to flow across or through the plurality of electrodes;
applying a voltage between the plurality of electrodes;
transferring the target metal from the metal or mineral containing solution to the plurality of electrodes by electrowinning;
depositing the target metal, a corresponding target metal oxide, or a corresponding target metal hydroxide on the plurality of electrodes; and
recovering the target metal or the corresponding target metal oxide, and/or the corresponding target metal hydroxide by mechanical separation, chemical separation, electrochemical separation, or a combination thereof.
2. The method of claim 1 , wherein the silicon electrodes are non-porous.
3. The method of claim 1 , wherein the silicon electrodes are porous.
4. The method of claim 1 , wherein the voltage applied ranges from about 0 V to about 20 V.
5. The method of claim 1 , wherein the pH of the metal containing solution is from about −1 to less than 10.
6. The method of claim 1 , further comprising maintaining the temperature of the flow cell from about 0° C. to about 120° C.
7. The method of claim 1 , further comprising applying a current density ranging from about 0 to about 2 A cm −2 between the plurality of electrodes.
8. The method of claim 1 , further comprising flowing an acidic, water-based, or solvent-based solution through the flow cell to recover the target metal, the corresponding target metal oxide, and/or the corresponding target metal hydroxide without removing the plurality of electrodes by mechanical separation, chemical separation, or electrochemical separation.
9. The method of claim 1 , further comprising disassembling the electrochemical reactor by removing the electrodes to recover the target metal, the corresponding target metal oxide, and/or the corresponding target metal hydroxide.
10. The method of claim 1 , wherein the target metal, the corresponding target metal oxide, and/or the corresponding target metal hydroxide is recovered in situ by placing a counter-electrode in the electrochemical reactor, wherein the recovered target metal migrates selectively from the plurality of electrodes to the counter-electrode, thereby further purifying the target metal and regenerating the silicon for further use.
11. The method of claim 1 , wherein the mechanical separation comprises sonication, mechanical shear or mechanical stripping, air jet, or water jet, the chemical separation comprises acidic dissolution of the recovered metal, and the electrochemical separation comprises electrorefining.
12. The method of claim 1 , wherein flow of the metal or mineral containing solution is orthogonal to the applied voltage.
13. The method of claim 1 , wherein the metal or mineral containing solution is from a lithium-ion battery recycling stream, a mining production stream, a mining waste stream, a refining stream, or a mining-affected water source.
14. The method of claim 1 , wherein the target metal or mineral is selected from the group consisting of lithium, manganese, cobalt, nickel, copper, lead, zinc, silver, cadmium, precious metals (gold, silver), rare earth elements (lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, and yttrium), platinum, palladium, iridium, ruthenium, rhodium, osmium, rhenium, mercury, thallium, selenium, bismuth, lead, uranium, polonium, combinations thereof, and oxides or hydroxides thereof.
15. The method of claim 1 , wherein the one or more anodes and/or the one or more cathodes are coated with a coating material selected from the group consisting of titanium, nickel, cobalt, copper, silver, platinum, palladium, gold, iridium, hafnium, ruthenium, rhodium, lead, antimony, calcium, oxides or silicides thereof, and combinations thereof.
16. The method of claim 15 , wherein the coating has a thickness of about 0.5 nm to about 500 nm.
17. The method of claim 15 , wherein the coating material is deposited by physical vapor deposition (magnetron sputtering, electron beam evaporation, thermal evaporation, pulsed laser deposition), electroplating, ion implantation, thermal spray deposition, or chemical vapor deposition, and further refined by thermal annealing.
18. The method of claim 15 , wherein the roughened surface of at least one of the plurality of electrodes is prepared prior to coating with ion-beam etching or with immersion in hydrofluoric acid at 0.1 wt % to 50 wt % HF in water.
19. The method of claim 1 , wherein the roughened surface of the plurality of electrodes is roughened via mechanical, chemical, thermal, or photon-based methods such as sanding, sand blasting, laser roughening, or ion etching.
20. The method of claim 1 , wherein the plurality of electrodes are in series or parallel flow configurations, wherein the metal or mineral containing solution flows through porous electrodes or around non-porous electrodes.
21. The method of claim 15 , wherein the coating material comprises Pt/N, Pt/Pb/Sb, Pt/Pb/Sb/Ca, Pt/Ir, Pt/Ru, Pt/Bi, Pt/Hf, or Pt/W.
22. The method of claim 21 , wherein the coating material comprises Pt/Ir.
23. The method of claim 15 , wherein the coating material comprises Au/Ni, Au/Pb/Sb, Au/Pb/Sb/Ca, Au/Ir, Au/Ru, Au/W, Au/Hf, Au/Bi, C/Ni, Cu/Pb/Sb, C/Pb/Sb/Ca, C/Ir, C/Ru, C/W, C/Bi, Hf/Pb, Hf/Sb, Hf/Ca, Hf/Ru, Hf/Rh, Ti/Hf, Ni/Hf, Co/Hf, Cu/Hf, Ag/Hf, Pt/Hf, Pd/Hf, Ir/Hf, or combinations thereof.
24. The method of claim 15 , wherein the coating has a thickness of 50 nm to about 100 nm.
25. The method of claim 1 , wherein the metal or mineral containing solution is acidic.
26. The method of claim 25 , wherein the metal or mineral containing solution has a pH less than 3.
27. The method of claim 25 , wherein the metal or mineral containing solution comprises sulfuric acid, hydrochloric acid, nitric acid, or combinations thereof.
28. The method of claim 27 , wherein the metal or mineral containing solution comprises sulfuric acid.
29. A method for extracting a target metal from a metal or mineral containing solution, the method comprising:
providing an electrochemical reactor, wherein the electrochemical reactor comprises a flow cell comprising a plurality of electrodes comprising one or more anodes and one or more cathodes, each electrode comprising monolithic silicon having a roughened surface;
feeding the metal or mineral containing solution into the electrochemical reactor causing the metal or mineral containing solution to flow across or through the plurality of electrodes;
applying a voltage between the plurality of electrodes;
transferring the target metal from the metal or mineral containing solution to the plurality of electrodes by electrowinning;
depositing the target metal, a corresponding target metal oxide, or a corresponding target metal hydroxide on the plurality of electrodes; and
recovering the target metal or the corresponding target metal oxide, and/or the corresponding target metal hydroxide by mechanical separation, chemical separation, electrochemical separation, or a combination thereof,
wherein at least the one or more anodes are coated with a coating material comprising platinum.