SYSTEMS AND METHODS FOR PROCESSING COAL FOR USE IN A DIRECT AIR CAPTURE SYSTEM
Embodiments discloses herein relate to methods of processing coal. A method to process coal includes subjecting raw coal to a liquefaction process effective to form a liquid pitch resin and subjecting the liquid pitch resin to a filtration process. The method further includes subjecting the liquid pitch resin to a low crystallinity spinning process to form a raw fiber. The raw fiber is then further subjected to a stabilization process configured to oxygen cross-link the fiber to form a stabilized fiber and then subjecting the stabilized fiber to a carbonization process to form a low thermal conductivity carbon fiber.
1 . A method of processing coal, the method comprising:
subjecting raw coal to a liquefaction process to form a liquid pitch resin;
subjecting the liquid pitch resin to a filtration process;
subjecting the liquid pitch resin to a low crystallinity spinning process to form a raw fiber;
subjecting the raw fiber to a stabilization process configured to oxygen cross-link the fiber to form a stabilized fiber; and
subjecting the stabilized fiber to a carbonization process to form a low thermal conductivity carbon fiber.
2 . The method of claim 1 , wherein the pitch resin includes a melting point such that subjecting the liquid pitch resin to a low crystallinity spinning process to form raw fiber does not include a plasticizer.
3 . The method of claim 2 , wherein the melting point of the liquid pitch resin includes between about 80° C. to about 343° C.
4 . The method of claim 1 , further comprising adding a blend additive to the pitch resin before or during the low crystallinity spinning process, the blend additive including at least one of isotropic pitch, pitch with a level an anisotropy, or a thermoplastic blend additive.
5 . The method of claim 1 , wherein the low crystallinity spinning process includes physically altering the spinning conditions.
6 . The method of claim 1 , wherein the pitch resin is treated with a blowing agent to promote foaming of the raw fiber, wherein the blowing agent includes hydrocarbons including at least one of pentane, cyclopentane, liquid carbon dioxide, chlorofluorocarbons (CFC's), or hydrochloroflorcarbons (HCFC's).
7 . The method of claim 5 , wherein physically altering the spinning conditions comprises having a turbulent flow spinneret design, having low draw ratios on the green spun fiber, having a melt blown solvated spinning system, using flow inverters or fritted flow redistributors in a spinneret capillary channel, introducing voids in the spun fiber, using specialized spinnerets to form hollow fibers with one or more cross-sectional holes, using specialized spinnerets to promote shearing, or a combination thereof.
8 . A method of manufacturing an electro-swing reactive adsorption (ESA) system, the method comprising:
forming a carbon composite negative electrode;
forming a carbon composite anode electrode; and
positioning one or more separator membranes between the negative electrode and the anode electrode.
9 . The method of claim 8 , wherein the carbon composite negative electrode includes a low thermal conductivity carbon fiber and the carbon composite anode electrode includes the low thermal conductivity carbon fiber.
10 . The method of claim 8 , further comprising forming the low thermal conductivity carbon fiber by:
subjecting raw coal to a liquefaction process to form a liquid pitch resin;
subjecting the liquid pitch resin to a low crystallinity spinning process to form raw fiber;
subjecting the raw fiber to a stabilization process configured to oxygen cross-link the fibers; and
subjecting the stabilized fiber to a carbonization process to form a low-conductivity carbon fiber.
11 . The method of claim 8 , further comprising forming the carbon composite by:
providing an amount of coal;
beneficiating the amount of coal;
processing at least some of the beneficiated amount of coal effective to produce an amount of solid char; and
treating at least some of the solid char effective to produce an amount of the carbon.
12 . The method of claim 11 , wherein the solid char includes a hydrogen to carbon ratio of from about 0.05 to about 0.65.
13 . The method of claim 11 , wherein treating at least some of the solid char includes at least one of a physical activation or a chemical activation.
14 . The method of claim 13 , wherein the physical activation includes heating the char in an inert atmosphere or in an oxidizing atmosphere.
15 . The method of claim 13 , wherein chemical activation includes impregnating the char with one or more chemicals.
16 . An electro-swing reactive adsorption (ESA) system, the system comprising:
a carbon composite negative electrode;
a carbon composite anode electrode; and
one or more separator membranes positioned between the negative electrode and the anode electrode.
17 . The system of claim 16 , wherein the carbon composite negative electrode includes a low thermal conductivity carbon fiber and the carbon composite anode electrode includes the low thermal conductivity carbon fiber.
18 . The system of claim 17 , wherein the low thermal conductivity carbon fiber is a coal-based low conductivity carbon fiber.
19 . The system of claim 16 , wherein the carbon composite is a coal-based activated carbon.
20 . The system of claim 16 , wherein the ESA system is included in a direct air capture (DAC) system.