SECONDARY BATTERY AND BATTERY MODULE CONTAINING SAME, BATTERY PACK, AND ELECTRICAL DEVICE
A secondary battery is disclosed. The secondary battery includes a positive electrode plate, a negative electrode plate, a separator, and an electrolyte solution. The positive electrode plate includes a positive active material. The positive active material includes a core and a coating. A manganese content of the core is greater than or equal to 25% based on a mass of the core. The coating overlays a surface of the core and contains one or more of an oxide, hydroxide, or oxyacid salt of element X. The element X is one or more selected from Al, B, or P. A mass ratio of the coating to the core is 1:(5 to 100), and optionally 1:(16 to 100). The electrolyte solution contains a first solvent. The first solvent is one or more selected from a fluorocarbonate ester, a fluorocarboxylate ester, a fluorosulfone, a fluoroether, or a fluorobenzene.
1 . A secondary battery, comprising a positive electrode plate, a negative electrode plate, a separator, and an electrolyte solution, wherein
the positive electrode plate comprises a positive active material, the positive active material comprises a core and a coating, a manganese content of the core is greater than or equal to 25% based on a mass of the core; the coating overlays a surface of the core and contains one or more of an oxide, hydroxide, or oxyacid salt of element X; the element X is one or more selected from Al, B, or P; and a mass ratio of the coating to the core is 1:(5 to 100), and optionally 1:(16 to 100); and
the electrolyte solution contains a first solvent, and the first solvent is one or more selected from a fluorocarbonate ester, a fluorocarboxylate ester, a fluorosulfone, a fluoroether, or a fluorobenzene.
2 . The secondary battery according to claim 1 , wherein
a manganese ion dissolution coefficient of the positive electrode plate, denoted as k, satisfies: k≤0.035%, optionally k≤0.017%, and further optionally k≤0.01%, wherein the manganese ion dissolution coefficient is a mass percent of manganese ions in the electrolyte solution after the positive electrode plate in a fully charged state is stored together with the electrolyte solution at 60° C. for 48 hours, and an injection coefficient of the electrolyte solution is 5 g/Ah).
3 . The secondary battery according to claim 1 , wherein
a static protection layer stability coefficient of the positive electrode plate is 54%≤e1≤100%, optionally 70%≤e1≤100%, and further optionally 85%≤e1≤100%, wherein the static protection layer stability coefficient is a ratio of a mass percent of the element X that remains in a positive electrode film layer after the positive electrode plate in a fully charged state is stored together with the electrolyte solution at 60° C. for 48 hours to a mass percent of the element X contained in the positive electrode film layer when the positive electrode plate is in a fully charged initial state.
4 . The secondary battery according to claim 1 , wherein
a dynamic protection layer stability coefficient e2 of the positive electrode plate satisfies: 20%≤e2≤100%, optionally 50%≤e2≤100%, and further optionally 70%≤e2≤100%, wherein the dynamic protection layer stability coefficient is a ratio of a mass percent of the element X that remains in a positive electrode film layer after the positive electrode plate in a fully charged state is stored together with the electrolyte solution at 60° C. for 48 hours to a mass percent of the element X contained in the positive electrode film layer before the storage.
5 . The secondary battery according to claim 1 , wherein
a mass percent of the element X in a positive electrode film layer is 0.05% to 5.35%, optionally 0.1% to 1.61%, and further optionally 0.24% to 1.61%, based on a total mass of the positive active material.
6 . The secondary battery according to claim 1 , wherein
the core is one or more selected from LiM p Mn 2-p O 4 , LiN q Mn 1-q PO 4 , or Li 1+t Mn 1-w L w O 2+t , wherein 0≤p≤1, 0≤q≤0.5, 0≤t≤1, 0≤w≤0.5; and M, N, and L each independently represent one or more of Ni, Co, Fe, Cr, V, Ti, Zr, La, Ce, Rb, P, W, Nb, Mo, Sb, B, Al, or Si;
further optionally, the core is one or more of LiM p Mn 2-p O 4 or Li 1+t Mn 1-w L w O 2+t ; and
further optionally, the core is one or more of LiNi 0.5 Mn 1.5 O 4 , LiNi 0.5 MCo 0.2 Mn 0.3 O 2 , Li 2 MnO 3 , or LiMnPO 4 .
7 . The secondary battery according to claim 1 , wherein the coating is one or more selected from aluminum oxide, boron oxide, a borate salt represented by A a+ x [BO 3 ] 3− y , a phosphate salt represented by A a+ [PO 4 ] 3− y , or a aluminate salt represented by A a+ x [AlO 2 ] 1− z , in which A represents one or more of Li, Na, K, Rb, Cs, Mg, Ca, Ba, Ni, Fe, Co, Ti, Al, Cr, V, Nb, or W, each compound is electrically neutral, and, a, x, y, and z each are selected from 1, 2, or 3; and
optionally, the coating is one or more of Al 2 O 3 , B 2 O 3 , Li 3 BO 3 , Li 3 PO 4 , Na 3 PO 4 , or LiAlO 2 .
8 . The secondary battery according to claim 1 , wherein
the first solvent is one or more selected from
wherein R 1 , R 3 , R 5 , and R 13 each are independently selected from C 1 to C 6 fluoroalkanes; R 2 , R 4 , R 6 , R 14 , R 15 , and R 16 each are independently selected from C 1 to C 6 alkanes or C 1 to C 6 fluoroalkanes; R 7 to R 12 each are independently selected from a C 1 to C 6 fluoroalkane, fluorine, or hydrogen; at least one of R 7 to R 12 is selected from fluorine or a fluoroalkane; and at least one of R 15 or R 16 is selected from C 1 to C 6 fluoroalkanes;
optionally, the first solvent is one or more of
9 . The secondary battery according to claim 1 , wherein
the electrolyte solution further comprises a second solvent, and the second solvent is one or more selected from a non-fluorinated carbonate ester, a non-fluorinated carboxylate ester, a non-fluorinated ether, or a non-fluorinated sulfone;
optionally, the second solvent is one or more of
wherein R 1 ′, R 2 ′, R 3 ′, R 13 ′, R 14 ′, and R 16 ′ each are independently selected from C 1 to C 6 alkanes; and R 4 ′ and R 15 ′ each are independently selected from a C 1 to C 6 alkane or hydrogen; and
optionally, the second solvent is one or more of ethyl methyl carbonate, dimethyl carbonate, diethyl carbonate, ethylene carbonate, propylene carbonate, methyl formate, methyl acetate, ethyl acetate, propyl acetate, methyl propionate, ethyl propionate, or propyl propionate.
10 . The secondary battery according to claim 9 , wherein a mass percent y 1 of the first solvent is 10% to 100%, optionally 40% to 100%, and further optionally 80% to 100%, based on a total mass of the first solvent and the second solvent.
11 . The secondary battery according to claim 9 , wherein a mass percent y 2 of the second solvent is 0% to 90%, optionally 0% to 60%, and further optionally 0% to 20%, based on a total mass of the first solvent and the second solvent.
12 . The secondary battery according to claim 11 , wherein the mass percent y 1 of the first solvent and a mass percent y 2 of the second solvent satisfy: y 1 /y 2 ≥0.66, optionally y 1 /y 2 ≥2.33, and further optionally y 1 /y 2 ≥4.
13 . The secondary battery according to claim 1 , wherein
the electrolyte solution further comprises a film-forming additive, and the film-forming additive is one or more selected from a chain or cyclic sulfate ester, a chain or cyclic sulfonate ester, a chain or cyclic carbonate ester, a polycyclic sulfate ester, or a polycyclic sulfonate ester;
optionally, the film-forming additive is one or more of
and
further optionally, the film-forming additive is one or more of
14 . The secondary battery according to claim 13 , wherein a mass percent of the film-forming additive is 0.5% to 20%, optionally 1% to 10%, and further optionally 1% to 5%, based on a total mass of the first solvent and the second solvent.
15 . The secondary battery according to claim 13 , wherein the film-forming additive comprises one or more of 0.5% to 3%
0.5% to 3%, 0.5% to 3%, or 0.5% to 3%, based on a total mass of the first solvent and the second solvent.
16 . The secondary battery according to claim 1 , wherein the core further comprises a doping element, and the doping element is one or more selected from W, Nb, Sb, Ti, Zr, La, Ce, or S, and optionally one or more of W or Nb.
17 . The secondary battery according to claim 16 , wherein a mass percent of the doping element is 0.05% to 5%, and optionally 0.1% to 2%, based on a total mass of the core.
18 . The secondary battery according to claim 1 , wherein particles of the positive active material are monocrystalline or quasi-monocrystalline.
19 . The secondary battery according to claim 1 , wherein a particle diameter of the positive active material is 1 to 20 μm, and optionally 3 to 15 μm.
20 . The secondary battery according to claim 1 , wherein an acidity of the electrolyte solution is less than or equal to 50 ppm, and a purity of each solvent in use is greater than or equal to 99.9%.
21 . A battery module, comprising the secondary battery according to claim 1 .
22 . A battery pack, comprising the battery module according to claim 21 .
23 . An electrical device, comprising at least one of the secondary battery according to claim 1 .