METHODS FOR RECOVERING HYDROGEN FLUORIDE FROM A FLUOROCARBON PRODUCTION PROCESS
A method of recovering hydrogen fluoride (HF) in a fluorocarbon production process, including absorbing hydrogen fluoride (HF) from an organic stream into water and distilling the hydrogen fluoride (HF) and water solution to produce a recovered hydrogen fluoride (HF) product. The recovered hydrogen fluoride (HF) product may then be used in a variety of fluorocarbon manufacturing processes.
1 . A method of recovering hydrogen fluoride (HF) in a fluorocarbon production process, comprising:
absorbing hydrogen fluoride (HF) from an organic stream into water in an absorption column to form a first solution of hydrogen fluoride (HF) and water having greater than about 35 wt. % HF;
conveying at least a portion of the first solution of hydrogen fluoride (HF) and water to a distillation column; and
distilling the first solution of hydrogen fluoride (HF) and water to provide a first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) and a first bottoms stream comprising a second solution of hydrogen fluoride (HF) and water having greater than about 35 wt. % HF.
2 . The method of claim 1 , wherein the organic stream comprises at least 20 wt. % of trans-1,3,3,3-tetrafluoropropene (HFO-1234ze (E)).
3 . The method of claim 1 , further comprising conveying at least a portion of the first bottoms stream comprising a second solution of hydrogen fluoride (HF) and water having greater than about 35 wt. % hydrogen fluoride (HF) back to the absorption column.
4 . The method of claim 1 , further comprising conveying at least a portion of the first solution of hydrogen fluoride (HF) and water back to the absorption column.
5 . The method of claim 4 , further comprising cooling the portion of the first solution of hydrogen fluoride (HF) and water prior to conveying at least a portion of the first solution of hydrogen fluoride (HF) and water back to the absorption column.
6 . The method of claim 1 , further comprising recovering from the absorption column an organic stream having less than about 5 wt. % HF.
7 . The method of claim 1 , further comprising purifying the distillate comprising at least about 95 wt. % hydrogen fluoride (HF) to recover an anhydrous hydrogen fluoride (HF) product including less than about 1000 ppm of water.
8 . The method of claim 7 , further comprising conveying the anhydrous hydrogen fluoride (HF) product as a reactant to an additional fluorocarbon or chlorofluorocarbon production process.
9 . The method of claim 1 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is conveyed to a process for manufacturing 2,3,3,3-tetrafluoropropene (HFO-1234yf).
10 . The method of claim 9 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is combined and reacted with at least one of:
1,1,2,3-tetrachloropropene (HCO-1230xa); and
2-chloro-3,3,3-trifluoropropene (HCFO-1233xf).
11 . The method of claim 1 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is conveyed to a process for manufacturing trans-1-chloro-3,3,3-trifluoropropene (HFO-1233zd (E)).
12 . The method of claim 11 , wherein the process for manufacturing trans-1-chloro-3,3,3-trifluoropropene (HFO-1233zd (E)) comprises reacting the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) with 1,1,1,3,3-pentachloropropene (HCC-240fa).
13 . A method of recovering hydrogen fluoride (HF) in a fluorocarbon production process, comprising:
absorbing hydrogen fluoride (HF) from an organic stream into water in an absorption column to form a first solution of hydrogen fluoride (HF) and water having greater than about 35 wt. % HF;
conveying at least a portion of the first solution of hydrogen fluoride (HF) and water to a distillation column;
distilling the first solution of hydrogen fluoride (HF) and water to provide a first distillate comprising at least about 70 wt. % hydrogen fluoride (HF) and a first bottoms stream comprising a second solution of hydrogen fluoride (HF) and water having greater than about 35 wt. % HF; and
distilling the first distillate to provide a second distillate comprising at least about 95 wt. % hydrogen fluoride (HF) and a second bottoms stream.
14 . The method of claim 13 , wherein the organic stream comprises at least 20 wt. % of HFO-1234ze (E).
15 . The method of claim 13 , further comprising conveying the second bottoms stream to the first distillation step.
16 . The method of claim 14 , further comprising cooling the second bottoms stream prior to conveying the second bottoms stream to the first distillation step.
17 . The method of claim 13 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is conveyed to a process for manufacturing 2,3,3,3-tetrafluoropropene (HFO-1234yf).
18 . The method of claim 17 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is combined and reacted with at least one of:
1,1,2,3-tetrachloropropene (HCO-1230xa); and
2-chloro-3,3,3-trifluoropropene (HCFO-1233xf).
19 . The method of claim 13 , wherein the first distillate comprising at least about 95 wt. % hydrogen fluoride (HF) is conveyed to a process for manufacturing trans-1-chloro-3,3,3-trifluoropropene (HFO-1233zd (E)).
20 . A hydrogen fluoride composition, comprising:
at least 95 wt. % hydrogen fluoride;
from 0.0001 wt. % to 0.8 wt. % 1,1,1,3,3-pentafluoropropane (HFC-245fa);
from 0.0001 wt. % to 0.2 wt. % cis-1,3,3,3-tetrafluoropropene (HFO-1234ze (Z));
from 0.0001 wt. % to 0.1 wt. % trans-1,3,3,3-tetrafluoropropene (HFO-1234ze (E));
from 0.0001 wt. % to 0.01 wt. % trans-1-chloro-3,3,3-trifluoropropene (HFO-1233zd (E)); and
less than 0.06 wt. % other organic products.