ELECTROCHROMIC MULTI-LAYER DEVICES WITH SPATIALLY COORDINATED SWITCHING
A multi-layer device comprising a first substrate and a first electrically conductive layer on a surface thereof, the first electrically conductive layer having a sheet resistance to the flow of electrical current through the first electrically conductive layer that varies as a function of position.
1 . A process for preparing a multi-layer device comprising forming a multi-layer layer structure comprising an electrochromic layer between and in electrical contact with a first and a second electrically conductive layer, the first or the second electrically conductive layer having a spatially varying sheet resistance that varies as a function of position in the first or the second electrically conductive layer, respectively, wherein a contour map of the sheet resistance as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the sheet resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases, and wherein the multi-layer device comprises a non-rectangular shape.
2 . The process for preparing the multi-layer device of claim 1 , wherein the non-rectangular shape is triangular, pentagonal, hexagonal, circular, or ovular.
3 . The process for preparing the multi-layer device of claim 1 , wherein a perimeter of the non-rectangular shape is a quadrilateral.
4 . The process for preparing the multi-layer device of claim 1 , further comprising forming the spatially varying sheet resistance in the first or the second electrically conductive layer using a composition variation in the respective first or the second electrically conductive layer.
5 . The process for preparing the multi-layer device of claim 1 , further comprising forming the spatially varying sheet resistance in the first or the second electrically conductive layer using a thickness variation in the respective first or the second electrically conductive layer.
6 . The process for preparing the multi-layer device of claim 1 , further comprising forming the spatially varying sheet resistance in the first or the second electrically conductive layer by patterning a series of scribes into the respective first or the second electrically conductive layer.
7 . The process for preparing the multi-layer device of claim 1 , wherein the patterning comprises one or more of laser patterning, mechanical scribing, and lithographie patterning.
8 . The process for preparing the multi-layer device of claim 1 , further comprising forming the spatially varying sheet resistance in the first or the second electrically conductive layer by etching the respective first or the second electrically conductive layer.
9 . The process for preparing the multi-layer device of claim 1 , further comprising forming the spatially varying sheet resistance in the first or the second electrically conductive layer using a defect variation in the respective first or the second electrically conductive layer.
10 . The process for preparing the multi-layer device of claim 1 , further comprising depositing the first electrically conductive layer on a substrate and varying the sheet resistance of the first electrically conductive layer as a function of position in the first electrically conductive layer.
11 . The process for preparing the multi-layer device of claim 1 , wherein the first electrically conductive layer is transmissive to electromagnetic radiation having a wavelength in a range of infrared to ultraviolet.