PRELITHIATED HYBRIDIZED ENERGY STORAGE DEVICE
An energy storage device can include a first electrode, a second electrode and a separator between the first electrode and the second electrode wherein the first electrode includes an electrochemically active material and a porous carbon material, and the second electrode includes elemental lithium metal and carbon particles. A method for fabricating an energy storage device can include forming a first electrode and a second electrode, and inserting a separator between the first electrode and the second electrode, where forming the first electrode includes combining an electrochemically active material and a porous carbon material, and forming the second electrode includes combining elemental lithium metal and a plurality of carbon particles.
1 . An assembly comprising:
a first electrode;
a second electrode comprising an electrode film, wherein the electrode film comprises lithium-intercalating carbon particles, elemental lithium metal particles and a fibrillized binder, wherein at least some of the lithium-intercalating carbon particles and the elemental lithium metal particles form a plurality of lithium-carbon composite particles or lithium-intercalating carbon particles coated with elemental lithium metal; and
a separator between the first electrode and the second electrode;
wherein at least one of the first electrode and the second electrode is free of solvent residues; and
wherein the electrode film is homogeneous, and free of holes and metal smearing.
2 . The assembly of claim 1 , wherein the plurality of lithium-carbon composite particles comprise pores, and wherein at least some of the elemental lithium metal particles are situated within the pores.
3 . The assembly of claim 1 , wherein the first electrode comprises first porous carbon particles, and the first porous carbon particles comprise activated carbon.
4 . The assembly of claim 1 , further comprising a solid electrolyte interface (SEI) layer covering exposed portions of the elemental lithium metal particles.
5 . The assembly of claim 1 , wherein the elemental lithium metal particles are untreated lithium metal particles.
6 . The electrode film of claim 1 , wherein the elemental lithium metal particles comprise a pristine surface.
7 . The assembly of claim 1 , wherein at least one of the first electrode and the second electrode comprises an electrode film comprising a structural matrix of binder fibrils such that the electrode film is a free-standing electrode film.
8 . The assembly of claim 1 , wherein the lithium-intercalating carbon particles are selected from a group consisting of graphite particles, porous carbon particles, activated carbon particles, hierarchically structured carbon particles and combinations thereof.
9 . The assembly of claim 1 , wherein the lithium-intercalating carbon particles coated with elemental lithium metal particles form a homogeneous film.
10 . The assembly of claim 1 , wherein the fibrillized binder comprises polytetrafluoroethylene (PTFE).
11 . The assembly of claim 1 , wherein the electrode film further comprises a second binder.
12 . The assembly of claim 1 , wherein the elemental lithium metal particles comprise particle sizes of less than 75 μm.
13 . An energy storage device comprising the assembly of claim 1 , an electrolyte and a housing.
14 . The energy storage device of claim 13 , wherein the energy storage device is a battery.
15 . A method for fabricating an energy storage device, comprising:
forming a first electrode by laminating a first electrode film to a first current collector;
combining elemental lithium metal particles, lithium-intercalating carbon particles and a fibrillizable binder to form a second electrode film mixture;
processing the lithium-intercalating carbon particles and the elemental lithium metal particles such that at least some of the lithium-intercalating carbon particles and the elemental lithium metal particles form a plurality of lithium-carbon composite particles or form lithium-intercalating carbon particles coated with elemental lithium metal;
forming a second electrode film from the second electrode film mixture;
forming a second electrode by laminating the second electrode film to a second current collector;
inserting a separator between the first electrode and the second electrode; and
placing the first electrode, the separator, the second electrode and an electrolyte in a housing to form an energy storage device;
wherein at least one of the first electrode film and second electrode film is free of solvent residues; and
wherein the second electrode film is homogeneous, and free of holes and metal smearing.
16 . The method of claim 15 , wherein the method does not utilize a solvent.
17 . The method of claim 15 , further comprising reducing a size of a bulk elemental lithium metal to form the elemental lithium metal particles.
18 . The method of claim 15 , wherein the elemental lithium metal particles are untreated elemental lithium metal particles.
19 . The method of claim 15 , wherein combining the elemental lithium metal particles and the lithium-intercalating carbon particles comprises combining dry elemental lithium metal particles and dry carbon particles to form a dry electrode film mixture.
20 . The method of claim 15 , wherein processing comprises a step selected from a group consisting of high shear mixing, heating, exposure to carbonate vapor, exposure to carbonate liquid, and combinations thereof.