Conductive Paste And Sintering Methods
A conductive paste is provided. The conductive paste includes a metal particulate material having a first metal powder having a having a D50 ranging from about 500 nm to about 1,500 nm, a second metal powder having a D50 ranging from about 10 nm to about 100 nm, and a third metal powder having a D50 ranging from about 3,000 nm to about 5,500 nm. The metal paste includes a solvent composition. The weight ratio of the third metal powder to the first metal powder is greater than 1. Electronic articles are also provided.
1 . A conductive paste, comprising:
a metal particulate material comprising a first metal powder having a having a D50 ranging from about 500 nm to about 1,500 nm, a second metal powder having a D50 ranging from about 10 nm to about 100 nm, and a third metal powder having a D50 ranging from about 3,000 nm to about 5,500 nm; and
a solvent composition,
wherein the weight ratio of the third metal powder to the first metal powder is greater than 1.
2 . The conductive paste of claim 1 , wherein the conductive paste comprises from about 90 wt. % to about 99 wt. % of the metal particulate material and from about 1 wt. % to about 10 wt. % of the solvent composition.
3 . The conductive paste of claim 1 , wherein the weight ratio of the third metal powder to the first metal powder is from about 1.2:1 to about 5:1.
4 . The conductive paste of claim 1 , wherein the weight ratio of the third metal powder to the second metal powder is from about 3:1 to about 10:1.
5 . The conductive paste of claim 1 , wherein the first metal powder, the second metal powder, and the third metal powder comprise silver.
6 . The conductive paste of claim 1 , wherein the third metal powder comprises at least 45 wt. % to about 75 wt. % of the metal particulate material.
7 . The conductive paste of claim 1 , wherein each of the first metal powder, second metal powder, and third metal powder comprise spherical particles.
8 . The conductive paste of claim 1 , wherein each of the first metal powder, second metal powder, and third metal powder comprise a coating.
9 . The conductive paste of claim 8 , wherein the coating comprises one or more lipids.
10 . The conductive paste of claim 1 , wherein the solvent composition comprises one or more alcohols and a dispersant.
11 . A sintering method for joining at least two components, the method comprising:
disposing a conductive paste on a first component, the conductive paste comprising:
a metal particulate material comprising a first metal powder having a D50 ranging from about 500 nm to about 1,500 nm, a second metal powder having a D50 ranging from about 10 nm to about 100 nm, and a third metal powder having a D50 ranging from about 3,000 nm to about 5,500 nm, wherein the weight ratio of the third metal powder to the first metal powder is greater than 1;
disposing a second component on the conductive paste to form a component arrangement; and
sintering the component arrangement.
12 . The method of claim 11 , comprising a sintering time of about 90 minutes or less.
13 . The method of claim 11 , wherein disposing the conductive paste on the first component comprises printing the conductive paste on the first component.
14 . The method of claim 11 , wherein disposing a second component on the conductive paste comprises disposing the first component having the conductive paste thereon on a bottom of a die, and pressing the first component and second component together at a pressure of about 0.01 MPa to about 1 MPa for a time period of about 0.1 seconds to about 10 seconds.
15 . The method of claim 11 , wherein sintering the component arrangement comprises exposing the component arrangement to an initial sintering temperature of about 25° C. and ramping up the temperature at a rate of about 3° C./min to about 10° C./min to a final sintering temperature of about 200° C. to about 300° C., which is held for about 15 min to about 60 min.
16 . The method of claim 11 , wherein the component arrangement exhibits a shear strength of at least about 10 MPa to about 60 MPa.
17 . The method of claim 11 , wherein the conductive paste comprises from about 90 wt. % to about 99 wt. % of the metal particulate material and from about 1 wt. % to about 10 wt. % of the solvent composition.
18 . The method of claim 11 , wherein the weight ratio of the third metal powder to the first metal powder is from about 1.2:1 to about 5:1.
19 . The method of claim 11 , wherein the weight ratio of the third metal powder to the second metal powder is from about 3:1 to about 10:1.
20 . An electronic article comprising a semiconductor chip sintered to a substrate with a conductive paste comprising the conductive paste of claim 1 .