POLYURETHANE COATING COMPOSITION
Methods of making a two-component composition that can be applied to a substrate and cured to provide a coating that demonstrates minimal solvent pop at the dry film thickness limit of the coating are provided. A cured coating made from the two-component composition demonstrates minimal solvent pop, minimal air entrapment, and optimal dry spray and overspray acceptance. Coated articles made using the methods described herein are also provided
1 . A method, comprising:
providing a first component of a coating composition;
providing a reaction mixture including
a first solvent and a second solvent, wherein the first solvent is ethyl acetoacetate present in an amount of about 1 to 5 wt %, based on the total weight of the composition, and the second solvent is acetone, and wherein the first and second solvents are present in a ratio of 80/20; and
a catalyst;
combining the first component with the reaction mixture, wherein the reaction mixture is 60 to 75% water, based on the total weight of the reaction mixture;
obtaining a two-component composition by mixing the combination of the first component and the reaction mixture with a second component; and
applying the composition to a substrate at a dry film thickness of 4 to 6 mil and drying at temperatures of 25° C. up to about 160° C. to form a cured coating that demonstrates minimal solvent pop.
2 . The method of claim 1 , wherein the first component includes at least one polyol.
3 . The method of claim 1 , wherein the second component includes at least one polyisocyanate.
4 . The method of claim 1 , wherein the catalyst is selected from metal, metal alkoxide, metal salts of aliphatic carboxylic acids, metal salts of alicyclic carboxylic acids, and combinations thereof.
5 . The method of claim 1 , wherein the catalyst is selected from tin salts, zinc salts, lithium salts, and combinations thereof.
6 . The method of claim 1 , wherein the catalyst is a tin compound.
7 . The method of claim 1 , wherein the catalyst is a zinc compound.
8 . A coated article, comprising:
a substrate; and
a cured coating applied thereon, wherein the coating is obtained by the method of claim 1 .
9 . The article of claim 8 , wherein the substrate is a metal substrate.