SEMICONDUCTOR NANOPARTICLE, PRODCUTION METHOD THEREOF, ELECTRONIC DEVICE INCLUDING THE SAME
A semiconductor nanoparticle, a method of producing the semiconductor nanoparticle, and an electronic device including the semiconductor nanoparticle. The semiconductor nanoparticle includes silver, indium, gallium, and sulfur, with a molar ratio of gallium to indium (Ga/In) of greater than or equal to about 0.8:1 and less than or equal to about 20:1. The semiconductor nanoparticle is substantially free of copper and is configured to emit red light. The emission peak wavelength of the red light is greater than or equal to about 600 nm and less than or equal to about 650 nm, with a full width at half maximum (FWHM) of greater than or equal to about 5 nm and less than or equal to about 90 nm.
1 . A semiconductor nanoparticle, comprising:
silver, indium, gallium, and sulfur, wherein the semiconductor nanoparticle is substantially free of copper;
wherein a mole ratio of gallium to indium in the semiconductor nanoparticle is greater than or equal to about 0.8:1 and less than or equal to about 20:1;
wherein the semiconductor nanoparticle is configured to emit a red light having a peak emission wavelength of greater than or equal to about 600 nanometers and less than or equal to about 650 nanometers and having a full width at half maximum of greater than or equal to about 5 nanometers and less than or equal to about 90 nanometers.
2 . The semiconductor nanoparticle of claim 1 , wherein
the red light has the full width at half maximum of greater than or equal to about 10 nanometers and less than or equal to about 50 nanometers.
3 . The semiconductor nanoparticle of claim 1 , comprising:
a first semiconductor nanocrystal comprising silver, indium, sulfur, and optionally selenium; and
a second semiconductor nanocrystal comprising gallium, sulfur, and optionally silver.
4 . The semiconductor nanoparticle of claim 3 , wherein
the semiconductor nanoparticle has a core-shell structure, comprising:
a core comprising the first semiconductor nanocrystal; and
a shell comprising the second semiconductor nanocrystal and optionally further comprising selenium, and being disposed on the core.
5 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle,
a mole ratio of gallium to indium is greater than or equal to about 1:1 and less than or equal to about 10:1, and optionally, a mole ratio of a sum of indium and gallium to sulfur is greater than or equal to about 0.65:1 and less than or equal to about 1.5:1.
6 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle, a mole ratio of gallium to indium is greater than or equal to about 2.1:1 and less than or equal to about 3.5:1, or the mole ratio of silver to indium is greater than or equal to about 0.5:1 and less than or equal to about 2.5:1.
7 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle,
a mole ratio of silver to indium is greater than or equal to about 1:1 and less than or equal to about 2:1, and
optionally wherein a mole ratio of gallium to silver is greater than or equal to about 1.8:1 and less than or equal to about 1.65:1.
8 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle, a mole ratio of gallium to sulfur is greater than or equal to about 0.37:1 and less than or equal to about 1:1.
9 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle, the mole ratio of sulfur to indium is greater than or equal to about 3.2:1 and less than or equal to about 10:1.
10 . The semiconductor nanoparticle of claim 1 , wherein
in the semiconductor nanoparticle, an indium concentration of an inner portion of the semiconductor nanoparticle is greater than that of an outer portion of the semiconductor nanoparticle.
11 . The semiconductor nanoparticle of claim 1 , wherein
the semiconductor nanoparticle exhibits a peak emission wavelength of red light of greater than or equal to about 603 nanometers and less than or equal to about 645 nanometers, and a quantum yield of greater than or equal to about 30%.
12 . The semiconductor nanoparticle of claim 1 , wherein
in ultraviolet-visible absorption spectroscopy,
the semiconductor nanoparticle exhibits an optical density at 450 nanometers per gram that is greater than or equal to about 0.8 milliliters per milligram per centimeter or
a ratio of absorption at 550 nanometers relative to absorption at 350 nanometers that is greater than or equal to about 0.05:1.
13 . The semiconductor nanoparticle of claim 1 , wherein
in ultraviolet-visible absorption spectroscopy,
the semiconductor nanoparticle has an optical density at 450 nanometers per gram that is greater than or equal to about 1 mL*mg −1 *cm −1 or
an absorption ratio at 550 nanometers relative to 350 nanometers that is greater than or equal to about 0.2:1 and less than or equal to about 0.8:1.
14 . A method of preparing the semiconductor nanoparticle of claim 1 , comprising:
contacting a silver precursor, a first sulfur precursor, and an indium precursor in a first reaction medium, comprising a first organic solvent;
heating the first reaction medium to a reaction temperature to prepare a first semiconductor nanocrystal, comprising silver, indium, and sulfur; and
contacting a second sulfur precursor, the first semiconductor nanocrystal, and a gallium precursor in a second reaction medium, comprising a second organic solvent;
wherein an amount of the first sulfur precursor is greater than or equal to about 2.5 moles and less than or equal to about 20 moles per mole of the indium precursor.
15 . The method of claim 14 , wherein an amount of the first sulfur precursor is greater than or equal to about 4 moles and less than or equal to about 10 moles per mole of the indium precursor.
16 . The method of claim 14 , wherein the reaction temperature is greater than about 210° C. and less than or equal to about 300° C.
17 . An ink composition, comprising:
the semiconductor nanoparticle of claim 1 , and a liquid vehicle.
18 . A semiconductor nanoparticle composite, comprising: a matrix, and the semiconductor nanoparticle of claim 1 dispersed in the matrix.
19 . A color conversion structure, comprising:
a color conversion layer, comprising a color conversion region,
wherein the color conversion region comprises a first region, comprising the semiconductor nanoparticle of claim 1 , corresponding to a first pixel; and,
optionally, partition walls defining each region of the color conversion layer.
20 . An electronic device, comprising the semiconductor nanoparticle of claim 1 .