Dental product with reduced extrusion forces
The invention relates to a dental product comprising a packaging device comprising a compartment with a front end and a rear end, an inner surface and an inner diameter, a layer of lubricant composition on the inner surface of the compartment, a dental material located in the compartment between the front end and the rear end, the lubricant composition comprising a monomer ML with an ethylenically unsaturated group, and filler FL in an amount of 0 to 65 wt. % with respect to the weight of the lubricant composition, the dental material being different with respect to its chemical composition from the lubricant composition.
1. A dental product comprising
a packaging device comprising a compartment with a front end and a rear end, an inner surface and an inner diameter,
a layer of lubricant composition on the inner surface of the compartment,
a dental material located in the compartment between the front end and the rear end,
the lubricant composition comprising a monomer ML with an ethylenically unsaturated (meth) acrylate group, and filler FL in an amount of 0 to 65 wt. % with respect to the weight of the lubricant composition,
the dental material being different with respect to its chemical composition from the lubricant composition.
2. The dental product according to the preceding claim , the dental material comprising
a monomer MC with an ethylenically unsaturated group, and
filler FC in an amount of 65 to 85 wt. % with respect to the weight of the dental material.
3. The dental product according to claim 1 , the lubricant composition having a viscosity in the range of 1 to 10,000 Pa*s at a temperature of 25° C. and a shear rate of 10 s −1 .
4. The dental product according to claim 1 , monomer ML having a molecular weight Mw in the range of 130 to 1,200 g/mol.
5. The dental product according to claim 1 , monomer ML being characterized by the following formula:
A n BA m
with A being an ethylenically unsaturated group,
B being selected from (i) linear or branched C 1 to C 12 alkyl, optionally substituted with functional groups selected from Cl, Br, I, OH, (ii) C 6 to C 12 aryl, optionally substituted with functional groups selected from Cl, Br, I, OH, or (iii) organic group having 4 to 20 carbon atoms bonded to one another by one or more ether, thioether, ester, thioester, thiocarbonyl, amide, urethane, carbonyl and/or sulfonyl linkages,
m, n being independently selected from 0, 1, 2, 3, 4, 5 or 6,
with the proviso that n+m is greater 0.
6. The dental product according to claim 1 , monomer MC being different from monomer ML.
7. The dental product according to claim 1 , filler FL and filler FC being same or different and comprising a nano-sized filler.
8. The dental product according to claim 1 , the lubricant composition and the dental material comprising in addition an initiator system.
9. The dental product according to claim 1 , the lubricant composition not comprising the following components alone or in combination:
silicone oil in an amount of more than 0.5 wt. %;
an acidic polymerizable component in an amount of more than 1 wt. %.
10. The dental product according to claim 1 , the packaging device further comprising at least one of the following:
a nozzle at the front end of the compartment;
a moveable piston located within the compartment.
11. The dental product according to claim 1 , the packaging device being characterized by the following features alone or in combination:
the compartment having a volume of 0.1 ml to 100 ml;
the ratio of length to inner diameter of the compartment being in the range of 25/1 to 3/1.
12. A process for producing a dental product, in particular the dental product described in claim 1 , the process comprising the steps of
providing a packaging device comprising a compartment with a front end and a rear end, an inner surface and an inner diameter, a dental material, and a lubricant composition,
applying a layer of a lubricant composition to the inner surface of the compartment,
filling the compartment to which the layer of lubricant composition has been applied with the dental material.
13. A process for dispensing the dental material from the dental product described in claim 1 , the process for dispensing comprising the step of applying force to the dental material located at the rear end of the compartment of the packaging device, the force being in a range of 5 to 60 N.
14. A kit of parts comprising
the dental product according to claim 1 ,
an applier for dispensing the dental material from the packaging device, and
optionally one or more of the following: a dental adhesive; a dental primer; a dental cement; a dental curing light; an instruction for use.
15. Use of a lubricant composition for reducing the extrusion force needed for dispensing a dental material from a packaging device comprising a compartment, the lubricant composition, the dental material and the packaging device being as described in claim 1 .