DECARBONISATION OF A CHEMICAL PLANT
A chemical plant comprising an off-gas treatment unit arranged to accept a hydrocarbon-containing off-gas stream, the off-gas treatment unit comprising sequentially: (i) an autothermal reformer, arranged to accept a hydrocarbon-containing fuel stream comprising hydrocarbons and steam and produce a reformed gas stream; (ii) a water-gas shift section arranged to accept said reformed gas stream and produce a shifted gas stream; and (iii) a CO2 removal unit arranged to accept said shifted gas stream and produce a CO2 rich stream and a decarbonised fuel stream; wherein said hydrocarbon-containing fuel stream is derived from said hydrocarbon-containing off-gas stream, steam and any supplemental fuel; wherein the chemical plant is arranged such that the decarbonised fuel stream is combusted instead of said hydrocarbon-containing off-gas stream.
1 . A method for retrofitting a chemical plant which is initially arranged such that a hydrocarbon-containing off-gas stream is combusted to provide at least some of the heating duty on the chemical plant, the method comprising the step of:
installing an off-gas treatment unit arranged to accept said hydrocarbon-containing off-gas stream, the off-gas treatment unit comprising sequentially:
(i) an autothermal reformer, arranged to accept a hydrocarbon-containing fuel stream comprising hydrocarbons and steam and produce a reformed gas stream;
(ii) a water-gas shift section arranged to accept said reformed gas stream and produce a shifted gas stream; and
(iii) a CO 2 removal unit arranged to accept said shifted gas stream and produce a CO 2 rich stream and a decarbonised fuel stream;
wherein said hydrocarbon-containing fuel stream is derived from said hydrocarbon-containing off-gas stream, steam and any supplemental fuel;
wherein said off-gas treatment unit is arranged such that the decarbonised fuel stream, optionally having first undergone further purification, is combusted instead of the hydrocarbon-containing off-gas stream;
with the proviso that the hydrocarbon-containing off-gas stream is not a purge gas stream from a methanol loop; and
with the proviso that if the hydrocarbon-containing off-gas stream is a tail-gas stream from the purification unit of a hydrocarbon reforming section comprising a fired steam reformer, water-gas shift and purification unit, then the decarbonised fuel stream from the off-gas treatment unit is not sent to the fired steam reformer of the hydrocarbon reforming section as a fuel.
2 . The method according to claim 1 , wherein the off-gas treatment unit is arranged to accept off-gases from two or more different hydrocarbon-containing off-gas streams from the chemical plant.
3 . The method according to claim 1 , wherein the hydrocarbon-containing off-gas stream is a purge stream.
4 . The method according to claim 1 , wherein the hydrocarbon-containing off-gas stream is a hydrocarbon-containing stream from a purification unit.
5 . The method according to claim 4 , wherein the purification unit is part of a steam reforming section.
6 . The method according to claim 1 , wherein the water-gas shift section comprises a high-temperature shift vessel and the off-gas treatment unit is arranged such that the hydrocarbon-containing feed to the autothermal reformer is pre-heated by heat exchange with a shifted gas stream generated by the high-temperature shift vessel.
7 . A chemical plant comprising an off-gas treatment unit arranged to accept a hydrocarbon-containing off-gas stream, the off-gas treatment unit comprising sequentially:
(i) an autothermal reformer, arranged to accept a hydrocarbon-containing fuel stream comprising hydrocarbons and steam and produce a reformed gas stream;
(ii) a water-gas shift section arranged to accept said reformed gas stream and produce a shifted gas stream; and
(iii) a CO 2 removal unit arranged to accept said shifted gas stream and produce a CO 2 rich stream and a decarbonised fuel stream;
wherein said hydrocarbon-containing fuel stream is derived from said hydrocarbon-containing off-gas stream, steam and any supplemental fuel;
wherein the chemical plant is arranged such that the decarbonised fuel stream, optionally having first undergone further purification, is combusted to provide at least some of the heating duty on the chemical plant;
with the proviso that the hydrocarbon-containing off-gas stream is not a purge gas stream from a methanol loop; and
with the proviso that if the hydrocarbon-containing off-gas stream is a tail-gas stream from the purification unit of a hydrocarbon reforming section comprising a fired steam reformer, water-gas shift and purification unit, then the decarbonised fuel stream from the off-gas treatment unit is not sent to the fired steam reformer of the hydrocarbon reforming section as a fuel.
8 . The chemical plant according to claim 7 , wherein the chemical plant is an oil refinery.
9 . The chemical plant according to claim 7 , wherein the off-gas treatment unit is arranged to accept off-gases from two or more different hydrocarbon-containing off-gas streams from the chemical plant.
10 . The chemical plant according to claim 9 , wherein the two or more different hydrocarbon-containing off-gas streams are combined into a single stream prior to entering the autothermal reformer.
11 . The chemical plant according to claim 7 , wherein the hydrocarbon-containing off-gas stream is a purge stream.
12 . The chemical plant according to claim 7 , wherein the hydrocarbon-containing off-gas stream is a hydrocarbon-containing stream from a purification unit.
13 . The chemical plant according to claim 7 , wherein the water-gas shift section comprises a high-temperature shift vessel and the off-gas treatment unit is arranged such that the hydrocarbon-containing feed to the autothermal reformer is pre-heated by heat exchange with a shifted gas stream generated by the high-temperature shift vessel.
14 . A process of treating a hydrocarbon-containing off-gas stream from a chemical plant by converting said hydrocarbon-containing off-gas stream in an off-gas treatment unit to produce a decarbonised fuel stream and combusting said decarbonised fuel stream to provide at least some of the heating duty on said chemical plant, wherein the chemical plant is as defined in claim 7 .
15 . The process according to claim 14 , wherein said decarbonised fuel stream comprises vol % 50-98 vol % H 2 .
16 . The method according to claim 4 , wherein the purification unit is part of a steam reforming section of a hydrogen, methanol or ammonia plant.
17 . The method according to claim 1 , wherein the off-gas treatment unit comprises a pre-reformer upstream of the autothermal reformer.
18 . The chemical plant according to claim 12 , wherein the purification unit is part of a steam reforming section of a hydrogen, methanol or ammonia plant.
19 . The chemical plant according to claim 7 , wherein the off-gas treatment unit comprises a pre-reformer upstream of the autothermal reformer.