2-CHLORO-3,3,3-TRIFLUOROPROPENE (1233XF) COMPOSITIONS AND METHODS FOR MAKING AND USING THE COMPOSITIONS
A composition including 2-chloro-3,3,3-trifluoropropene (1233xf), one or more of 2,3-dichloro-1,1,1-trifluoropropane (243db), 1,2-dichloro-3,3,3-trifluoropropene (1223xd), 2,3-dichloro-3,3-difluoropropene (1232xf), 2,2,3-trichloro-1,1,1-trifluoro-propane (233ab), 2,3,3-trichloro-1,1,1-trifluoro-propane (233da), 3,3,3-trifluoropropyne, 1-chloro-3,3,3-trifluoropropyne, 3,3,3-trifluoro-1-propene (1243zf), 1-chloro-3,3,3-trifluoro- 1-propene (1233zd), 1-chloro-2,3,3,3-tetrafluoro-1-propene (1224yd), or 2-bromo-3,3,3-trifluoropropene and optionally 1233xf oligomers are disclosed.
1 . A 2,3,3,3-tetrafluoropropene (1234yf) composition produced by the steps of:
a. contacting 2-chloro-3,3,3-trifluoropropene (1233xf) with hydrogen fluoride in the presence of a fluorination catalyst at a temperature sufficient to effect formation of 2-chloro-1,1,1,2-tetrafluoropropene (244bb); and
b. thermally dehydrochlorinating the 2-chloro-2,3,3,3-tetrafluoropropane (244bb) to 1234yf, or contacting the 2-chloro-2,3,3,3-tetrafluoropropane (244bb) with a vapor phase dehydrochlorination catalyst to effect dehydrochlorination to form 2,3,3,3-tetrafluoropropene (1234yf), or contacting the 2-chloro-2,3,3,3-tetrafluoropropane (244bb) with a base at a temperature sufficient to effect dehydrochlorination to form 2,3,3,3-tetrafluoropropene (1234yf).
2 . The composition of claim 1 , wherein the 2-chloro-3,3,3-trifluoropropene (1233xf) is contacted with the hydrogen fluoride in the liquid phase.
3 . The composition of claim 1 , wherein the 2-chloro-1,1,1,2-tetrafluoropropene (244bb) is converted to 1234yf in the vapor phase in the presence of a catalyst.
4 . The composition of claim 1 , wherein the 2-chloro-1,1,1,2-tetrafluoropropene (244bb) is converted to 1234yf in the vapor phase in the absence of a catalyst.
5 . The composition of claim 1 , wherein the 2-chloro-1,1,1,2-tetrafluoropropene (244bb) is contacted with the base in the liquid phase.
6 . The composition of claim 1 further comprising at least one oligomer.
7 . The composition of claim 6 wherein the oligomer has a structure of:
wherein n=0 to 9.
8 . The composition of claim 7 further comprising at least one solvent capable of at least partially dissolving the oligomer.
9 . The composition of claim 8 further comprising at least one solvent capable of at least partially dissolving the oligomer.
10 . The composition of claim 8 wherein the solvent comprises at least one member selected from the group consisting of 113a, dichloromethane, acetone, THF, CHCl3, 1233xf, 244bb, CCI4, 114a, 114, 113, 243db, 250fb, 1230xa, 240 db, 1233zd, 1223xd, 1224yd, and 253fb.
11 . The composition of claim 8 wherein the solvent comprises at least one member selected from the group consisting of 113a, dichloromethane, acetone, THF, CHCl3, 1233xf, 244bb, CCl4, 114a, 114, 113, 243db, 250fb, 1230xa, 240 db, 1233zd, 1223xd, 1224yd, and 253fb.
12 . A composition comprising:
a) 2-chloro-3,3,3-trifluoropropene (1233xf) in an amount of at least 94.6 GC area % based on the total amount of the composition,
b) a member selected from 1-chloro-3,3,3-trifluoro-1-propene (1233zd), 1-chloro-2,3,3,3-tetrafluoro-1-propene (1224yd), and at least one compound selected from the group consisting of 2,3-dichloro-1,1,1-trifluoropropane (243db), 1,2-dichloro-3,3,3-trifluoropropene (1223xd), 2,3-dichloro-3,3-difluoropropene (1232xf), 2,2,3-trichloro-1,1,1-trifluoro-propane (233ab), 2,3,3-trichloro-1,1,1-trifluoro-propane (233da), 3,3,3-trifluoropropyne, 1-chloro-3,3,3-trifluoropropyne, 3,3,3-trifluoro-1-propene (1243zf), 2-bromo-3,3,3-trifluoropropene, and combinations thereof, wherein the member is present in an amount of between about 0.01 weight percent to about 5 weight percent based on the total amount of the composition provided the total amount of the composition is 100%.
13 . The composition of claim 12 , wherein b) includes 2,3-dichloro-1,1,1-trifluoropropane (243db).
14 . The composition of claim 12 , wherein b) includes one of 1-chloro-3,3,3-trifluoropropyne or 2-bromo-3,3,3-trifluoropropene (1233xfB).
15 . A 2-chloro-3,3,3-trifluoropropene (1233xf) composition produced by the steps of:
contacting 2,3-dichloro-1,1,1-trifluoropropane (243db), in the liquid phase, with a base under conditions sufficient to effect dehydrochlorination to form 2-chloro-3,3,3-trifluoropropene (1233xf), 1-chloro-3,3,3-trifluoro-1-propene (1233zd), and 1-chloro-2,3,3,3-tetrafluoro-1-propene (1224yd).
16 . The composition of claim 15 , wherein the base includes at least one of sodium carbonate, potassium carbonate, sodium hydroxide, potassium hydroxide, potassium tert-butoxide, calcium oxides, or calcium hydroxide.