HYDROTHERMAL FEEDSTOCK TREATMENT
The disclosure provides a process for a hydrothermal feedstock treatment including direct steam injection and cooling, which may be performed in the absence of a reactor. The process can be used to reduce inorganic and organic contaminants, such as salts, minerals, metals, asphaltenes, polymers, and coke precursors in both renewable and non-renewable feedstocks. The hydrothermal feedstock treatment may also be used in soap acidulation processes.
1 . A process for treating a feedstock comprising:
combining a feedstock stream and a water stream to form a combined feedstock and water stream;
pressurizing the combined feedstock and water stream above 2 MPa;
adding an additive to at least one of the feedstock stream, the water stream, or the combined feedstock and water stream prior to injecting steam;
injecting steam directly into the combined feedstock and water stream, forming a heated feedstock and water stream,
cooling the heated feedstock and water stream; and
producing a cooled product stream.
2 . The process of claim 1 , further comprising:
depressurizing the cooled product stream; and
separating the cooled product stream by supplying the cooled product stream to a separator, thereby producing a treated feedstock and a separated water stream, optionally further purifying the treated feedstock.
3 . The process of claim 1 , further comprising preheating the feedstock before the step of injecting steam.
4 . The process of claim 1 , further comprising pre-treating the feedstock by steam degumming, enzymatic degumming, water degumming, or a combination thereof prior to the steps of pressurizing the feedstock and injecting steam.
5 . The process of claim 2 , wherein the separating step comprises centrifugal separation.
6 . The process of claim 1 , wherein the feedstock comprises a petroleum-based feedstock or a renewable feedstock, and a contaminant.
7 . The process of claim 6 , wherein the renewable feedstock comprises a glyceride-based lipid.
8 . The process of claim 1 , wherein the pretreated feedstock is pressurized from 3 to 10 MPa; and wherein the steam has a pressure of from 3 to 10 MPa.
9 . The process of claim 1 , wherein the steam injection step heats the feedstock to a temperature above 200° C.
10 . The process of claim 1 , wherein the cooling step comprises reducing the temperature of the heated feedstock and water stream to 90° C. or less over a period of 30 seconds to 15 minutes, 30 seconds to 10 minutes, 30 seconds to 5 minutes, or 30 seconds to 1 minute, inclusive.
11 . The process of claim 1 , further comprising supplying the separated water stream to a water reclaiming process, the water reclaiming process comprising:
heating the separated water stream in a first evaporator to a temperature between 120° C. to 160° C., producing a first heated water stream.
12 . The process of claim 11 , further comprising:
heating the first heated water stream in a second evaporator to a temperature between 110° C. to 150° C., to produce a second heated water stream; and
heating the second water stream in a third evaporator to a temperature between 100° C. to 140° C., to produce a third heated water stream, wherein a volume of the third heated water stream is less than the volume of the separated water stream.
13 . The process of claim 12 , wherein each of the first, second, and third evaporators produces steam during heating.
14 . The process of claim 1 , further comprising:
separating the cooled product stream by supplying the cooled product stream to at least one decanter configured to separate a treated feedstock and a product water stream;
recycling the product water stream back into the pretreated feedstock prior to pressurization, wherein the first water stream is at least partially comprising the recycled product water stream.
15 . The process of claim 14 , further comprising maintaining the heated feedstock and water stream at a laminar flow for a time.
16 . The process of claim 1 , wherein the additive is at least one of: an acid; a base; an ionic liquid; an organic solvent; a reducing agent; an oxidizing agent; a sugar; and a catalyst.
17 . The process of claim 1 , wherein the feedstock stream comprises soapstock.
18 . The process of claim 17 , further comprising:
decanting the heated feedstock and water stream such that the heated feedstock and water stream separates into acid oil and an aqueous phase;
providing the aqueous phase to a separator to separate water from precipitates within the aqueous phase.
19 . A process for treating a feedstock comprising:
combining a feedstock stream and a water stream to form a combined feedstock and water stream;
pressurizing the combined feedstock and water stream above 2 MPa;
adding an additive to at least one of the feedstock stream, the water stream, or the combined feedstock and water stream prior to injecting steam;
injecting steam directly into the combined feedstock and water stream, forming a heated feedstock and water stream; and
providing the heated feedstock and water stream to a multi-separation process configured to separate a purified light phase comprising cleaned feedstock from water.
20 . The process of claim 19 , wherein the multi-separation process comprises:
providing the heated feedstock and water stream to a first decanter configured to separate feedstock from a heavy phase within the heated feedstock and water stream, the heavy phase comprising a combination of water and feedstock;
providing the heavy phase to a second decanter configured to separate an intermediate phase from water within the heavy phase, the intermediate phase comprising a combination of water and feedstock; and
cooling the intermediate phase with a cooler;
providing the intermediate phase to a third decanter configured to separate feedstock from water within the intermediate phase.
21 . The process of claim 20 , wherein water from the second decanter may be recycled back into the water stream.
22 . The process of claim 20 , further comprising:
removing feedstock at a rate from 45-70 #/hr from the first decanter;
removing the heavy phase at a rate from 30-55 #/hr from the first decanter; and
removing the intermediate phase at a rate from 5-30 #/hr form the second decanter; and
removing water at a rate from 10-35 #/hr from the second decanter.
23 . A soap acidulation process for processing soapstock, comprising:
combining a soapstock stream and a water stream to form a combined soapstock and water stream;
pressurizing the combined soapstock and water stream above 2 MPa;
injecting steam directly into the pretreated combined feedstock and water stream, forming a heated soapstock and water stream;
decanting the heated soapstock and water stream such that the heated soapstock and water stream separates into acid oil and an aqueous phase;
providing the aqueous phase to a separator to separate water from precipitates within the aqueous phase.
24 . The soap acidulation process of claim 23 , wherein acid oil comprises free fatty acids.
25 . The soap acidulation process of claim 23 , further comprising adding an additive to at least one of the soapstock stream, the water stream, or the combined soapstock and water stream prior to injecting steam.
26 . The soap acidulation process of claim 25 , wherein the additive is at least one of an acid and a sugar.
27 . The soap acidulation process of claim 23 , wherein the water separated out of the aqueous phase is recycled back into the water stream.
28 . The soap acidulation process of claim 23 , further comprising providing the heated soapstock and water stream to a concentrator configured to remove water from the heated soapstock and water stream.
29 . The soap acidulation process of claim 23 , further comprising adding acid to the heated soapstock and water stream.
30 . The soap acidulation process of claim 23 , wherein the aqueous phase comprises less than 10% of unreacted components of the soapstock stream.