FLUX COMPOSITION
A flux composition includes a flux agent including KAlF4 and CsAlF4; a thickening agent having a first carbon content; a binder having a second carbon content; and an organic solvent; wherein a total carbon content of the flux composition is less than about 1 wt %, based on a total weight of the flux composition. The flux composition is applied onto a substrate by jetting the flux composition through a nozzle orifice of an applicator and onto the substrate.
1 . A flux composition comprising:
a flux agent that is a combination of KAlF 4 and CsAlF 4 ;
a thickening agent having a first carbon content;
a binder having a second carbon content; and
an organic solvent;
wherein a total carbon content of the flux composition is less than about 1 wt %, based on a total weight of the flux composition, measured using combustion analysis.
2 . The flux composition of claim 1 wherein CsAlF 4 is present in an amount of from about 1 to about 30 wt %, based on a total weight of the KAlF 4 and CsAlF 4 .
3 . The flux composition of claim 1 wherein the thickening agent is chosen from cellulose ethers, polysaccharides, polyacrylates, and combinations thereof.
4 . The flux composition of claim 1 wherein the thickening agent is present in an amount of from greater than about 0 and up to about 0.4 wt %, based on a total weight of the flux composition.
5 . The flux composition of claim 1 wherein the binder is a polyacrylate.
6 . The flux composition of claim 1 wherein the binder is present in an amount of from greater than about 0 and up to about 5 wt %, based on a total weight of the flux composition.
7 . The flux composition of claim 1 having a solids content of from about 30 to about 70 wt %, based on a total weight of the flux composition.
8 . The flux composition of claim 1 wherein the organic solvent is chosen from propylene carbonate, propylene glycol, hexylene glycol, dioxane, 3-methoxy-3-methyl-1-butanol, texanol, butyl glycol, butyl diglycol, butyl triglycol, and combinations thereof.
9 . The flux composition of claim 1 wherein the organic solvent is present in an amount of from greater than about 0 and up to about 50 wt %, based on a total weight of the flux composition.
10 . The flux composition of claim 1 having a viscosity of from about 1000 to about 4000 mPas, measured at a sheer rate of about 23.5 s −1 and a temperature of about 21° C.
11 . The flux composition of claim 1 wherein the flux agent has an average particle size distribution Dv90 of less than or equal to about 30 microns, as determined by laser diffraction.
12 . The flux composition of claim 1 wherein the flux agent has an average particle size distribution Dv50 of less than or equal to about 30 microns, as determined by laser diffraction.
13 . The flux composition of claim 1 wherein the flux agent has an average particle size distribution Dv10 of less than or equal to about 30 microns, as determined by laser diffraction.
14 . The flux composition of claim 1 further comprising water.
15 . The flux composition of claim 14 wherein water is present in an amount of from about 0 to about 50 wt %, based on a total weight of the flux composition.
16 . The flux composition of claim 14 wherein water is present in an amount of from about 20 to about 50 wt %, based on a total weight of the flux composition.
17 . A method of applying a flux composition onto a substrate, the method comprising:
a) providing the substrate;
b) providing an applicator comprising a nozzle defining a nozzle orifice that has a nozzle diameter of from about 0.1 to about 2 mm;
c) providing the flux composition comprising:
a flux agent comprising KAlF 4 and CsAlF 4 ;
a thickening agent having a first carbon content;
a binder having a second carbon content; and
an organic solvent;
wherein a total carbon content of the flux composition is less than about 1 wt %, based on a total weight of the flux composition, measured according to using combustion analysis; and
d) jetting the flux composition through the nozzle orifice and onto the substrate.
18 . The method of claim 17 wherein the flux agent has an average particle size distribution Dv90 of less than or equal to about 30 microns, as determined by laser diffraction, and a viscosity of 1000 to about 4000 mPas, measured at a sheer rate of about 23.5 s −1 and a temperature of about 21° C.
19 . The method of claim 17 further comprising the step of brazing on the substrate to create a joint.
20 . The method of claim 19 wherein the joint is free of visible carbon black residue after the step of brazing.