BRANCHED, TERMINATED POLYAMIDE COMPOSITIONS
The present disclosure provides a method of producing partially terminated polyamide compositions with branched chains from polyamide precursors. The partially terminated, branched polyamide compositions have increased melt strength properties and melt stability.
1 . A polyamide composition having the following formula:
wherein:
a=6 to 10;
b=6 to 10;
c=6 to 10;
d=6 to 10;
x=80 to 400;
m=1 to 400;
said polyamide includes dimer acids wherein carbon chains of the dimer acids both have more than 8 carbons;
the polyamide composition has a dimer diamine or dimer acid composition between 1 wt. % and 40 wt. % based on the total weight of the polyamide composition;
the polyamide composition is terminated with an amine endgroup and a carboxyl endgroup; and
the polyamide composition has a relative viscosity between 3.0 and 7.0 RV as determined by GB/T 12006.1-2009/ISO 307:2007.
2 . The polyamide composition of claim 1 , wherein the amine endgroup concentration is between 15 mmol/kg to 40 mmol/kg, and the carboxyl endgroup concentration is between 15 mmol/kg to 40 mmol/kg.
3 . The polyamide composition of claim 1 , wherein the polyamide composition has a relative viscosity of 4.0 RV to 7.0 RV as determined by GB/T 12006.1-2009/ISO 307:2007.
4 . The polyamide composition of claim 1 , wherein the polyamide composition has a formic acid viscosity of 230 FAV to 950 FAV, as determined by ASTM D789.
5 . The polyamide composition of claim 1 , wherein the polyamide composition has a formic acid viscosity of 230 FAV to 260 FAV, as determined by ASTM D789.
6 . A polyamide composition that is dual-terminated with an amine end group and a carboxyl end group, the polyamide composition has a relative viscosity of 4.0 RV to 7.0 RV and a formic acid viscosity of 230 FAV to 970 FAV, as determined by ASTM D789.
7 . The polyamide composition of claim 6 , wherein the amine endgroup concentration is between 15 mmol/kg to 40 mmol/kg, and the carboxyl endgroup concentration is between 15 mmol/kg to 40 mmol/kg.