IP Library Granted Patent US 6,911,484
Granted Patent B1
US 6,911,484 · App. 09/624,708 · Granted Jun 28, 2005

Expanding medium, system and method for decorating surfaces

Assignee: Earlychildhood.com LLC
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Quick Facts
Patent No.
US 6,911,484
App. No.
09/624,708
Granted
Jun 28, 2005
Kind
B1
Abstract

The invention is a decorating medium, system and method for producing relief art on substrate surfaces. The decorating medium is an acrylic emulsion based medium containing an expandable polymer which expands the medium upon heating. The acrylic emulsion is produced with a mixture of an acrylic binder and an acrylic thickener or a cellulosic thickener combined in the appropriate range to obtain a medium rheology suitable for controlled application of the medium to the substrate surfaces. The decorating medium is applied to a substrate surface in a desired pattern either directly from a storage bottle or tube equipped with a nozzle or with an applicator such as a brush, a sponge, a knife or spatula. The desired pattern is achieved by free hand or by using a stencil or mask. After the decorating medium is applied to the surface of the substrate in the desired pattern, the medium is cured and heated. The heat causes the medium to expand and creates the relief art on the surface of the substrate. The relief art is flexible after curing and may be painted or decorated according the needs and taste of the artist. In an alternative embodiment of the invention, the decorating medium is mixed with decorating additives of choice such as pigments, colorants or glitters, prior to curing and heating the medium. The medium, the system and the method of the current invention are particularly useful for creating relief art on cloth or fabric substrates, but are also suitable for creating relief art on other substrate surfaces including metal, plastic, paper, cardboard and glass surfaces.

Claims (27)

1. A decorating medium for creating relief art on a substrate surface, the medium comprising:

a. a water-based emulsion body;

b. an expandable polymer with a blowing agent encapsulated therein, wherein the medium is cured and expanded when heated after application to the substrate surface; and

c. a preservative selected from the group consisting of Hydroxyalkl-1-aza-3,7- dioxabicyclo(3.3.0)octane, Tetrachlorisophthalonitrile 1,2-Benzisothiazolin-3-one, and Phenoxyethanol.

2. The decorating medium of claim 1 , wherein the water-based emulsion body comprises an acrylic binder and an acrylic thickener.

3. The decorating medium of claim 2 , wherein the acrylic binder is selected from the group consisting of Vinyl Acetate-Ethylene Polymer, Vinyl Acetate-Vinyl Chloride-Ethylene Terpolymer and a Vinyl-Acrylic Polymer.

4. The decorating medium of claim 2 , wherein the acrylic binder is in the range of 25 to 95 percent of the total weight of the decorating medium.

5. The decorating medium of claim 2 , wherein the decorating medium has a viscosity in a range of 3,000 to 25,000 centipoise in a range of 7.0 to 9.0.

6. The decorating medium of claim 2 , wherein the acrylic thickener is in a range of 0.5 to 10% percent of the weight of the decorating medium.

7. The decorating medium of claim 1 , wherein the preservative is in the range of 0.005 to 0.50 percent of total weight of the medium.

8. The decorating medium of claim 1 , wherein the expandable polymer is a Polyvinylidene Chloride polymer encapsulating an alkane blowing agent.

9. The decorating medium of claim 8 , wherein the blowing agent is Isobutane.

10. A system for decorating surfaces, the system comprising:

a. a water based heat curable and expandable medium;

b. a water compatible decorating additive for mixing with the heat curable and expandable medium; and

c. a preservative selected from the group consisting of Hydroxyalkl-1-aza-3,7-dioxabicyclo(3.3.0)ocatane, Tetrachlorisophthalonitrile 1,2-Benzisothiazolin-3-one, Phenoxyethanol.

11. The system of claim 10 , wherein the decorating additive is a coloring agent selected from the group consisting of ink, dye, food coloring, acrylic paint, finger paint and tempera paint.

12. The system of claim 10 , wherein the water based heat curable and expandable medium comprises:

a. an emulsion body comprising an acrylic binder and an acrylic thickener or a cellulosic thickener; and

b. an expandable polymer with a blowing agent encapsulated therein, wherein the medium is cured and expanded when heated to temperatures below 140 Celsius.

13. The system of claim 12 , wherein the acrylic binder is selected from the group consisting of Vinyl Acetate-Ethylene Polymer, Vinyl Acetate-Vinyl Chloride-Ethylene Terpolymer and Vinyl-Acrylic Polymer.

14. The system of claim 12 , wherein the acrylic binder is in a range of 25 to 95 percent of a total weight of the medium.

15. The system of claim 12 , wherein the decorating medium has a viscosity in a range of 3,000 to 25,000 centipoise in a pH range of 7.0 to 9.0.

16. The system of claim 13 , wherein the acrylic thickener is in a range of 0.5 to 10 percent of a weight of the medium.

17. The system of claim 10 , wherein the preservative is in a range of 0.005 to 0.50 percent of a total weight of the medium.

18. The system of claim 12 , wherein the expandable polymer is a Polyvinylidene Chloride polymer emasculating an alkane blowing agent.

19. The system of claim 18 , wherein the alkane blowing agent is Isobutane.

Assignments (18)
RELEASE OF SECURITY INTEREST Recorded Jan 19, 2024
From: ARES CAPITAL CORPORATION
To: EXCELLIGENCE LEARNING CORPORATION; ANGELES CORPORATION; CHILDCARE EDUCATION INSTITUTE, LLC; CHILDREN'S FACTORY, LLC; EARLYCHILDHOOD LLC; REALLY GOOD STUFF, LLC; FROG STREET PRESS, LLC
Reel/Frame 066185/0261 →
RELEASE OF SECURITY INTEREST Recorded Apr 19, 2017
From: GENERAL ELECTRIC COMPANY, AS ADMINISTRATIVE AGENT (AS SUCCESSOR IN INTEREST BY MERGER TO GENERAL ELECTRIC CAPITAL CORPORATION, AS ADMINISTRATIVE AGENT)
To: EXCELLIGENCE LEARNING CORPORATION; ANGELES CORPORATION; EARLYCHILDHOOD LLC; EDUCATIONAL PRODUCTS, INC.
Reel/Frame 042066/0010 →
SECURITY INTEREST Recorded Apr 18, 2017
From: EXCELLIGENCE LEARNING CORPORATION; ANGELES CORPORATION; CHILDCARE EDUCATION INSTITUTE, LLC; CHILDREN'S FACTORY, LLC; EARLYCHILDHOOD LLC; REALLY GOOD STUFF, LLC; FROG STREET PRESS, LLC
To: ARES CAPITAL CORPORATION
Reel/Frame 042045/0473 →
RELEASE OF SECURITY INTEREST Recorded Dec 30, 2014
From: GENERAL ELECTRIC CAPITAL CORPORATION
To: EXCELLIGENCE LEARNING CORPORATION
Reel/Frame 034601/0051 →
SECURITY INTEREST Recorded Dec 30, 2014
From: EXCELLIGENCE LEARNING CORPORATION; ANGELES CORPORATION; EARLYCHILDHOOD LLC; EDUCATIONAL PRODUCTS, INC.
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS ADMINISTRATIVE AGENT
Reel/Frame 034601/0383 →
RELEASE OF SECURITY INTEREST Recorded Dec 23, 2011
From: ALLY COMMERCIAL FINANCE LLC (AS SUCCESSOR BY MERGER TO GMAC BUSINESS CREDIT, LLC)
To: EXCELLIGENCE LEARNING CORPORATION (FORMERLY KNOWN AS LEARNINGSTAR CORP.); EARLYCHILDHOOD LLC; SMARTERKIDS.COM, INC.; EDUCATIONAL PRODUCTS INC.
Reel/Frame 027439/0542 →
RELEASE OF SECURITY INTEREST Recorded Oct 11, 2011
From: BANK OF AMERICA, N.A.
To: EARLYCHILDHOOD LLC
Reel/Frame 027041/0424 →
SECURITY AGREEMENT Recorded Sep 6, 2011
From: EXCELLIGENCE LEARNING CORPORATION; EXCELLIGENCE HOLDINGS CORP.; ACHIEVEMENT PRODUCTS, INC.; ANGELES CORPORATION; COLORATIONS, INC.; EARLYCHILDHOOD LLC; EDUCATIONAL PRODUCTS, INC.; MARKETING LOGISTICS, INC.; SMARTERKIDS.COM, INC.
To: GENERAL ELECTRIC CAPITAL CORPORATION
Reel/Frame 026862/0303 →
RELEASE OF SECURITY INTEREST Recorded Sep 6, 2011
From: ARES CAPITAL CORPORATION, AS AGENT
To: ELC ACQUISITION CORP.; ELC HOLDINGS CORPORATION; EXCELLIGENCE LEARNING CORPORATION; EXCELLIGENCE HOLDINGS CORP.; ACHIEVEMENT PRODUCTS, INC.; ANGELES CORPORATION; COLORATIONS, INC.; EARLYCHILDHOOD LLC; EDUCATIONAL PRODUCTS, INC.; MARKETING LOGISTICS, INC.; SMARTERKIDS.COM, INC.; STEFFY WOOD PRODUCTS, INC.
Reel/Frame 026861/0826 →
SECURITY AGREEMENT Recorded Aug 1, 2011
From: ELC ACQUISITION CORP.; ELC HOLDINGS CORPORATION; EXCELLIGENCE LEARNING CORPORATION; EXCELLIGENCE HOLDINGS CORP.; ACHIEVEMENT PRODUCTS, INC.; ANGELES CORPORATION; COLORATIONS, INC.; EARLYCHILDHOOD LLC; EDUCATIONAL PRODUCTS, INC.; MARKETING LOGISTICS, INC.; SMARTERKIDS.COM, INC.; STEFFY WOOD PRODUCTS, INC.
To: ARES CAPITAL CORPORATION, AS AGENT
Reel/Frame 026682/0695 →
RELEASE OF SECURITY INTEREST Recorded Aug 1, 2011
From: BANK OF MONTREAL, AS AGENT
To: EARLYCHILDHOOD LLC
Reel/Frame 026682/0528 →
RELEASE OF SECURITY INTEREST Recorded Aug 1, 2011
From: BANK OF MONTREAL, AS AGENT
To: EARLYCHILDHOOD LLC
Reel/Frame 026682/0518 →
SECOND LIEN PATENT COLLATERAL AGREEMENT Recorded Dec 5, 2006
From: EARLYCHILDHOOD LLC
To: BANK OF MONTREAL, AS AGENT
Reel/Frame 018584/0185 →
SECURITY AGREEMENT Recorded Nov 30, 2006
From: EARLYCHILDHOOD LLC
To: BANK OF MONTREAL, AS AGENT
Reel/Frame 018563/0628 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2003
From: EARLYCHILDHOOD LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 014601/0102 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 24, 2001
From: EARLYCHILDHOOD.COM
To: EARLYCHILDHOOD LLC
Reel/Frame 012008/0848 →
SECURITY INTEREST Recorded May 15, 2001
From: LEARNINGSTAR CORP.; EARLYCHILDHOOD LLC; SMARTERKIDS.COM, INC.; EDUCATIONAL PRODUCTS, INC.
To: GMAC BUSINESS CREDIT, LLC, AS AGENT
Reel/Frame 011874/0318 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2000
From: GOOBICH, JOEL
To: EARLYCHILDHOOD. COM LLC
Reel/Frame 010961/0381 →