Method for producing heterogeneous catalysts containing metal nanoparticles
A method for producing highly dispersed catalysts is disclosed. The method includes contacting a support material with a solvent for a period of time, adding a metal salt to the solvent and support mixture, and then adding a reducing agent to the solution to reduce the metal salt to nanometer sized metal particles on the surface of the support. Excess solvent is used in the process, the volume of solvent being greater than two times the pore volume of the support.
1. A method for producing a supported platinum catalyst comprising:
contacting a quantity of alumina support material with a volume of water for a first time period to form a liquid mixture, wherein said volume of water is greater than two times a pore volume of said quantity of alumina support material;
adding a platinum salt solution having a molar concentration of 0.0001 to 0.1 to said liquid mixture following said first time period and stirring said liquid mixture for a second time period; and
adding a reducing agent to said liquid mixture following said second time period and stirring said liquid mixture for a third time period, wherein said platinum salt is reduced to platinum particles within pores of said quantity of alumina support material within said liquid mixture during said third time period,
wherein the average platinum particle diameter is greater than 3.0 nm and less than 5.0 nm.
2. The method as recited in claim 1 , wherein said platinum salt solution added to said liquid mixture comprises dissolved platinum ions.
3. The method as recited in claim 2 , wherein pH of said liquid mixture is not adjusted after the platinum salt solution is added to said liquid mixture.
4. The method as recited in claim 3 , wherein said reducing agent is chosen from the group consisting of N 2 H 4 , NH 2 OH, sodium citrate, potassium citrate, ammonium citrate, alkali metal borohydrides, alcohols and glycols.
5. The method as recited in claim 4 , wherein said reducing agent comprises N 2 H 4 .
6. The method as recited in claim 1 , wherein the step of adding the reducing agent comprises purging said liquid mixture with argon and then purging said liquid mixture with hydrogen.
7. The method as recited in claim 1 , wherein the platinum weight loading of the supported platinum catalyst is less than 1%.
8. The method as recited in claim 1 , wherein the range of platinum particle diameters is about 1 nm to 15 nm.
9. The method as recited in claim 1 , wherein the platinum salt solution comprises a Pt(NO 3 ) 2 salt solution.
10. A method for producing a supported platinum catalyst comprising:
contacting a quantity of alumina support material with a volume of water for a first time period to form a liquid mixture, wherein said volume of water is greater than two times a pore volume of said quantity of alumina support material;
obtaining a platinum salt solution having a molar concentration of 0.0001 to 0.1;
adding the platinum salt solution to said liquid mixture following said first time period and stirring said liquid mixture for a second time period;
adding a reducing agent to said liquid mixture following said second time period and stirring said liquid mixture for a third time period;
filtering the liquid mixture to separate out said quantity of alumina support material with platinum particles supported thereon; and
drying said quantity of alumina support material with platinum particles supported thereon,
wherein said platinum salt is reduced to platinum particles within pores of said quantity of alumina support material within said liquid mixture during said third time period prior to said filtering and said drying, and
wherein the average platinum particle diameter is greater than 3.0 nm and less than 5.0 nm.
11. The method as recited in claim 10 , wherein pH of said liquid mixture is not adjusted after the platinum salt solution is added to said liquid mixture.
12. The method as recited in claim 11 , wherein said reducing agent is chosen from the group consisting of N 2 H 4 , NH 2 OH, sodium citrate, potassium citrate, ammonium citrate, alkali metal borohydrides, alcohols and glycols.
13. The method as recited in claim 12 , wherein said reducing agent comprises N 2 H 4 .
14. The method as recited in claim 12 , wherein the step of adding the reducing agent comprises purging said liquid mixture with argon and then purging said liquid mixture with hydrogen.
15. The method as recited in claim 10 , wherein the platinum weight loading of the supported platinum catalyst is less than 1%.
16. The method as recited in claim 10 , wherein the range of platinum particle diameters is about 1 nm to 15 nm.
17. The method as recited in claim 10 , wherein the platinum salt solution comprises a Pt(NO 3 ) 2 salt solution.
18. The method as recited in claim 10 , wherein the third time period is about 1 to 2 hours.