Adhesion of polyethylene on polypropylene
View Patent ↗This invention provides a multi-layer film or sheet prepared by coextruding or laminating polypropylene with one or more polyethylene(s), characterised in that the adhesion between a polypropylene layer and a polyethylene layer is provided by a metallocene-produced polyethylene.
1. A multilayer film comprising a film layer formed of polypropylene and an adhesive layer formed of a metallocene-produced polyethylene in an adhesive relationship with said polypropylene layer and having a density of from 0.925 to 0.96 g/cm 3 and a melt flow index MI 2 within the range of 0.05 to 50 g/10 min. wherein the metallocene-produced polyethylene has an amount of crystallization larger than 4% for chains having less than 10 short chain branches per 1000 carbon atoms, and wherein the metallocene is ethylene bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride.
2. The multilayer film of claim 1 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 5/MI 2 .
3. The multilayer film of claim 1 where said film is formed by co-extruding said polypropylene and said metallocene-produced polyethylene.
4. The multilayer film of claim 1 wherein said metallocene-produced polyethylene and said polypropylene are co-extruded through a flat die.
5. The multilayer film of claim 1 wherein said metallocene-produced polyethylene and said polypropylene are co-extruded through an annular die.
6. The multilayer film of claim 1 consisting of one film layer formed of polypropylene and said metallocene-produced polyethylene adhesive layer.
7. The multilayer film of claim 1 wherein the polypropylene film layer represents from 0.5 to 99.99% of the total film or sheet thickness.
8. The multilayer film of claim 1 wherein said layer of metallocene-produced polyethylene is interspersed between said polypropylene film layer and a polyethylene film layer to provide a tie layer between said polypropylene film layer and said polyethylene film layer.
9. The multilayer film of claim 8 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 5/MI 2 .
10. A multilayer film comprising first and second external film layers, each formed of a metallocene-produced polyethylene having a density within the range of 0.925 to 0.96 g/cm 3 and a melt flow index within the range of 0.05 to 50 g/10 min. and an internal layer formed of polypropylene interposed between said external layers and in an adhesive relationship with said external layers wherein the metallocene-produced polyethylene has an amount of crystallization larger than 4% for chains having less than 10 short chain branches per 1000 carbon atoms, and wherein the metallocene is ethylene bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride.
11. The multilayer film of claim 10 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 5/MI 2 .
12. A multilayer film comprising a first film layer formed of polyproyplene and a second film layer formed of polyethylene and further comprising a tic layer formed of metallocene-prodcued polyethylene having a density within the range of 0.91 to 0.96 g/cm 3 and a melt flow index MI 2 within the range of 0.05 to 50 g/10 min. interposed between said first polyproyplene film layer and said second polyethylene film layer in an adhesive relationship therewith, wherein the metallocene-produced polyethylene has an amount of crystallization larger than 4% for chains having less than 10 short chain branches per 1000 carbon atoms, and wherein the metallocene is ethylene bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride.
13. The multilayer film of claim 12 wherein said metallocene-produced polyethylene tile layer has a density within the range of 0.917 to 0.96 g/cm 3 .
14. The multilayer film of claim 12 wherein said metallocene-produced polyethylene tie layer has a density within the range of 0.925 to 0.96 g/cm 3 .
15. The multilayer film of claim 12 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 5/MI 2 .
16. The multilayer film of claim 15 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 10/MI 2 .
17. The multilayer film of claim 16 wherein the metallocene-produced polyethylene has a Dow rheological index larger than 20/MI 2 .
18. A multilayer film comprising:
a film layer formed of polypropylene; and
an adhesive layer formed of a metallocene-produced polyethylene in an adhesive relationship with the film layer, wherein the metallocene-produced polyethylene comprises a density of from 0.925 g/cm 3 to 0.96 g/cm 3 , a melt flow index MI 2 of from 0.05 g/10 min. to 50 g/10 min. and an amount of crystallization of greater 4% for chains having less than 10 short chain branches per 1000 carbon atoms and wherein the multilayer film is absent tying additives.
19. A multilayer him comprising:
a film layer formed of polypropylene; and
an adhesive layer consisting essentially of a metallocene-produced polyethylene in an adhesive relationship with the film layer, wherein the metallocene-produced polyethylene comprises a density of from 0.925 g/cm 3 to 0.96 g/cm 3 , a melt flow index MI 2 of from 0.05 g/10 min. to 50 g/10 min. and an amount of crystallization of greater 4% for chains having less than 10 short chain branches per 1000 carbon atoms and wherein the metallocene is ethylene bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride.