Method for producing toner
View Patent ↗A toner which can efficiently induce high-frequency magnetic induction heating by Neel relaxation and/or Brown relaxation is provided. A toner including a core particle containing a thermoplastic polymer material and superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm which adhere to the surfaces of the core particle is manufactured by directly forming the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm on the surfaces of the core particle so that the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm are not in contact with each other. As a result, the toner is prevented from being scattered due to the influence of a magnetic field, so that a high quality image is formed.
1. A method for manufacturing a toner to be fixed by high-frequency magnetic induction heating which comprise at least
a core particle comprising a thermoplastic polymer material; and
superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm which adhere to the surfaces of the core particle,
the method comprising:
preparing a core particle dispersion in which a core particle comprising a thermoplastic polymer material is dispersed in a dispersion medium;
introducing divalent iron ions (Fe 2+ ) to the core particle dispersion;
introducing an oxidizing agent to the core particle dispersion in the presence of water; and
stopping the growth of ferrite on the surface of the core particle after a predetermined time has elapsed from the introduction of the oxidizing agent;
wherein the superparamagnetic ferrite fine particles are not in contact with each other.
2. The method for manufacturing a toner according to claim 1 , wherein the particle diameter of the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm is 30 nm or less.
3. The method for manufacturing a toner according to claim 1 , wherein the particle diameter of the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm is in the range of from 18 to 23 nm.
4. A toner to be fixed by high-frequency magnetic induction heating comprising:
a core particle comprising a thermoplastic polymer material; and
superparamagnetic fine particles having a particle diameter of less than 100 nm which adhere to the surface of the core particle,
wherein the superparamagnetic fine particles are not in contact with each other.
5. The toner according to claim 4 , wherein the particle diameter of the superparamagnetic fine particles having a particle diameter of less than 100 nm is 30 nm or less.
6. The toner according to claim 4 , wherein the particle diameter of the superparamagnetic fine particles is in the range of 18 to 23 nm.
7. The toner according to claim 4 , wherein the thermoplastic polymer material comprises polyacrylate, polystyrene, styrene copolymer, or polyester.
8. The toner according to claim 7 , wherein the styrene copolymer is styrene-butadiene copolymer or styrene-(meth)acrylic acid ester copolymer.
9. The toner according to claim 4 , wherein the core particle comprises wax or an antistatic agent.
10. The toner according to claim 4 , wherein the core particle comprises an organic coloring agent or an inorganic coloring agent.
11. The toner according to claim 4 , wherein the superparamagnetic fine particles comprise magnetite, maghemite, Co ferrite, or hexagonal barium ferrite.
12. A toner to be fixed by high-frequency magnetic induction heating comprising:
a core particle comprising a thermoplastic polymer material; and
superparamagnetic fine particles having a from 18 to 23 nm which adhere to the surface of the core particle.
13. A method for forming an image comprising:
forming an unfixed toner image on a recording medium; and
fixing the unfixed toner image on the recording medium by using a high-frequency magnetic field,
wherein, the toner comprises:
a core particle comprising a thermoplastic polymer material; and
superparamagnetic fine particles having a particle diameter of less than 100 nm which adhere to the surface of the core particle,
wherein the superparamagnetic fine particles are not in contact with each other.
14. The method for forming an image according to claim 13 , wherein the frequency of the high-frequency magnetic field is in the range of from 100 kHz to 5 MHz.
15. The method for forming an image according to claim 13 , wherein the frequency of the high-frequency magnetic field is in the range of from 300 kHz to 1 MHz.
16. A method for forming an image comprising:
forming an unfixed toner image on a recording medium; and
fixing the unfixed toner image on the recording medium by using a high-frequency magnetic field,
wherein the toner comprises:
a core particle comprising a thermoplastic polymer material; and
superparamagnetic fine particles having a particle diameter from 18 to 23 nm, and which adhere to the surface of the core particle.
17. The method for forming an image according to claim 16 , wherein the frequency of the high-frequency magnetic field is in the range of from 100 kHz to 5 MHz.
18. The method for forming an image according to claim 16 , wherein the frequency of the high-frequency magnetic field is in the range of from 300 kHz to 1 MHz.
19. A method for manufacturing a toner to be fixed by high-frequency magnetic induction heating which comprise at least
a core particle comprising a thermoplastic polymer material; and
superparamagnetic ferrite fine particles having a particle diameter of from 18 to 23 nm which adhere to the surfaces of the core particle,
the method comprising:
preparing a core particle dispersion in which a core particle comprising a thermoplastic polymer material is dispersed in a dispersion medium;
introducing divalent iron ions (Fe 2+ ) to the core particle dispersion;
introducing an oxidizing agent to the core particle dispersion in the presence of water; and
stopping the growth of ferrite on the surface of the core particle after a predetermined time has elapsed from the introduction of the oxidizing agent.