Process for the production of HFO trans-1234ze from HFC-245fa

1. A continuous integrated manufacturing process for the production of trans-1,3,3,3-tetrafluoropropene which consists of the steps:

(a) dehydrofluorinating 1,1,1,3,3-pentafluoropropane in a vapor phase reaction, in the absence of an oxygen-containing gas, to produce a product stream comprising cis-1,3,3,3-tetrafluoropropene, trans-1,3,3,3-tetrafluoropropene and hydrogen fluoride;

(b) removing the hydrogen fluoride from the product stream of step (a); and

(c) recovering trans-1,3,3,3-tetrafluoropropene from the product stream of step (a) or step (b) by distilling the product stream of step (a) or step (b) to isolate and recover the trans-1,3,3,3-tetrafluoropropene therefrom.

2. The process of claim 1 , further comprising the steps;

(d) recovering a residue from step (c) comprising one or more of hydrogen fluoride, cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane;

(e) individually isolating and recovering the hydrogen fluoride, cis-1,3,3,3-tetrafluoro-propene and 1,1,1,3,3-pentafluoropropane from the residue in step (d); and

(f) isolating and recovering at least one of the cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane from the residue in step (e) and recycling the recovered material back to step (a).

3. The process of claim 2 , further comprising the step of recovering cis-1,3,3,3-tetrafluoropropene or a mixture of cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane from the residue and converting cis-1,3,3,3-tetrafluoropropene to 1,1,1,3,3-pentafluoropropane by fluorination.

4. The process of claim 3 , wherein the fluorination reaction is a liquid phase reaction.

5. The process of claim 3 , wherein the fluorination reaction is a vapor phase reaction.

6. The process of claim 3 , wherein the resulting 1,1,1,3,3-pentafluoropropane is recycled back to step (a).

7. The process of claim 1 , wherein the dehydrofluorinating is conducted with a catalyst comprising one or more of fluorinated Cr 2 O 3 , AlF 3 , FeF 3 , 10% MgF 2 -90% AlF 3 , Fe on activated carbon, Ni on activated carbon, and Co on activated carbon.

8. The process of claim 7 , wherein the dehydrofluorinating is conducted in a vapor phase at a temperature of from about 100° C. to about 600° C.; at a contact time of the 1,1,1,3,3-pentafluoropropane with the catalyst of from about 0.5 seconds to about 120 seconds.

9. The process of claim 1 , wherein step (b) further comprises the recovering of the hydrogen fluoride by passing the product stream of step (a) through a sulfuric acid extractor, desorbing the extracted hydrogen fluoride from the sulfuric acid, and then distilling the desorbed hydrogen fluoride.