IP Library Granted Patent US 8,076,165
Granted Patent B2
US 8,076,165 · App. 11/887,153 · Granted Dec 13, 2011

Method of manufacturing p-type nitride semiconductor and semiconductor device fabricated by the method

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Quick Facts
Patent No.
US 8,076,165
App. No.
11/887,153
Granted
Dec 13, 2011
Kind
B2
Abstract

The present invention includes a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen carrier gas and a hydrogen carrier gas of a flow quantity larger than that of the nitrogen carrier gas to thereby supply a raw material containing Mg and a Group V raw material containing N, and a second step of lowering a temperature by using a second carrier gas to which a material containing N is added, and hence solves the problems.

Claims (21)

1. A method of manufacturing a p-type nitride semiconductor comprising:

a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen gas and a hydrogen gas of a flow quantity larger than a flow quantity of said nitrogen gas to thereby supply a raw material containing magnesium and a Group V raw material containing nitrogen (N); and

a second step of lowering a temperature by using a second carrier gas to which a material containing nitrogen (N) is added of a concentration of at least 0.01% and less than 20%,

Wherein ammonia is used at a concentration of at least 0.01% and at most 5% as said material containing nitrogen (N).

2. A method of manufacturing a p-type nitride semiconductor, comprising:

a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen gas and a hydrogen gas of a flow quantity larger than a flow quantity of said nitrogen gas to thereby supply a raw material containing magnesium and a Group V raw material containing nitrogen (N); and

a second step of lowering a temperature by using a second carrier gas to which a material containing nitrogen (N) is added at a concentration of at least 0.01% and less than 20%, wherein a flow quantity of the second carrier gas is larger than the flow quantity of the nitrogen gas in the first carrier gas.

3. A method of manufacturing a p-type nitride semiconductor, comprising:

a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen gas and a hydrogen gas of a flow quantity larger than a flow quantity of said nitrogen gas to thereby supply a raw material containing magnesium and a Group V raw material containing nitrogen (N); and

a second step of lowering a temperature by using a second carrier gas to which a material containing nitrogen (N) is added at a concentration of at least 0.01% and less than 20%, wherein said second step is a step of lowering the temperature to 400° C. or lower, and time required for reaching 400° C. is at most 25 minutes.

4. A method of manufacturing a p-type nitride semiconductor, comprising:

a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen gas and a hydrogen gas of a flow quantity larger than a flow quantity of said nitrogen gas to thereby supply a raw material containing magnesium and a Group V raw material containing nitrogen (N); and

a second step of lowering a temperature by using a second carrier gas to which a material containing nitrogen (N) is added at a concentration of at least 0.01% and less than 20%,

Wherein dimethyl hydrazine is used at concentration at least 0.01% and at most 2% as said material containing nitrogen (N).

5. A method of manufacturing a p-type nitride semiconductor, comprising:

a first step of forming a nitride semiconductor layer by metal organic chemical vapor deposition by using a first carrier gas containing a nitrogen gas and a hydrogen gas of a flow quantity larger than a flow quantity of said nitrogen gas to thereby supply a raw material containing magnesium and a Group V raw material containing nitrogen (N);

a second step of lowering a temperature by using a second carrier gas to which a material containing nitrogen (N) is added at a concentration of at least 0.01% and less than 20%, and

a third step of subjecting the nitride semiconductor layer to an annealing treatment after said step in an inert gas for at least one minute and at most 15 minutes.

6. The method of manufacturing the p-type nitride semiconductor according to claim 5 , wherein the annealing treatment in the third step is performed at at least 700° C. and at most 900° C.

7. The method of manufacturing the p-type nitride semiconductor according to claim 5 , wherein in said third step, ammonia is further added at a concentration of at least 0.01% and at most 5% in addition to said inert gas.

8. The method of manufacturing the p-type nitride semiconductor according to claim 5 , wherein in said third step, hydrogen is further added at a concentration of at least 10 ppm and at most 500 ppm in addition to said inert gas.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 10, 2022
From: SHARP KABUSHIKI KAISHA
To: SHARP FUKUYAMA LASER CO., LTD.
Reel/Frame 059039/0927 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2007
From: TSUDA, YUHZOH; ITO, SHIGETOSHI; TANEYA, MOTOTAKA; UETA, YOSHIHIRO; TAKAKURA, TERUYOSHI
To: SHARP KABUSHIKI KAISHA
Reel/Frame 019944/0149 →