Curable composition
View Patent ↗The present invention has its object to provide a curable composition comprising a reactive silyl group-containing organic polymer component which allows slight bleedout of a liquid compound to occur to the cured product surface and shows good adhesiveness and water-resistant adhesiveness using an amine compound as a non-organotin catalyst. The present invention relates to a curable composition which comprises: (A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation, (B) a silanol condensation catalyst, and (C) an adhesion promoter, and that the silanol condensation catalyst (B) is an amine compound (B-1) having a melting point lower than 23° C., and that the adhesion promoter (C) comprises an amino group-containing silane coupling agent (C-1) and an epoxy group-containing silane coupling agent (C-2) in a specific proportion.
1. A curable composition which comprises:
(A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation,
0.5 to 5 parts by weight of (B) a silanol condensation catalyst containing an amine compound (B-1) having a melting point lower than 23° C. and optionally, a carboxylic acid metal salt (B-3), per 100 parts by weight of the (A) component and
1 to 10 parts by weight of (C) an adhesion promoter containing an amino group-containing silane coupling agent (C-1) and an epoxy group-containing silane coupling agent (C-2) per 100 parts by weight of the (A) component
wherein
the (A) component organic polymer is at least one polymer selected from the group consisting of polyoxyalkylene polymers and (meth)acrylate ester polymers
wherein the component (B-1) is an amidine compound represented by the general formula (1):
R 1 N═CR 2 —NR 3 2 (1)
wherein R 1 , R 2 and the two R 3 moieties each independently is a hydrogen atom or a monovalent organic group and any two or more of R 1 , R 2 and the two R 3 moieties may be bound together to form a ring structure and having a melting point of lower than 23° C.
the ratio between the number (b3) of moles of the carboxylic acid metal salt (B-3) and the number (b1) of moles of the amine compound (B-1), namely the ratio (b3)/(b1), is 0 to not higher than 0.01 and
the ratio between the total number (c1) of moles of the nitrogen atom in the amino group-containing silane coupling agent (C-1) and the total number (c2) of moles of the epoxy group in the epoxy group-containing silane coupling agent (C-2), namely the ratio (c1)/(c2), is not higher than 5.
2. The curable composition according to claim 1 wherein the component (B-1) is an amidine compound of the general formula (1), wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon group whose α-carbon to the nitrogen atom has single bonds alone or a hydrogen atom.
3. The curable composition according to claim 1 wherein the component (B-1) is an amidine compound of the general formula (1), wherein any two or more of R 1 , R 2 and the two R 3 moieties are bound together to form a ring structure.
4. The curable composition according to claim 1 wherein the amidine compound represented by the general formula (1) as the component (B-1) is a cyclic amidine compound represented by the general formula (2):
wherein R 4 is a divalent organic group and R 5 and R 6 each independently is a hydrogen atom or a monovalent organic group and R 5 and R 6 may be bound together to form a ring structure.
5. The curable composition according to claim 1 wherein the polyoxyalkylene polymer is a polyoxypropylene polymer.
6. The curable composition according to claim 1 wherein the main chain skeleton of the polyoxyalkylene polymer is composed of hydrogen atoms, carbon atoms and oxygen atoms alone.
7. A sealing composition which comprises the curable composition according to claim 1 .
8. An adhesive composition which comprises the curable composition according to claim 1 .