Method of using ionic liquids to inhibit or prevent the swelling of clay
View Patent ↗An ionic liquid may be used to inhibit the swelling and/or disintegration of clay in a subterranean formation. A subterranean clay-containing formation may be treated with the ionic liquid by contacting the formation with a well treatment composition containing the ionic liquid dispersed or dissolved in a carrier fluid. Damage to the formation caused by contact with the well treating composition is reduced or substantially eliminated.
1. A method of inhibiting the swelling of clay particulates in a subterranean formation comprising:
(a) introducing into the subterranean formation a well treatment composition comprising an ionic liquid entrained in an aqueous fluid, wherein the ionic liquid comprises a cation and an anion, the cation being an imidazolium of formula (I):
wherein R 1 and R 2 are independently a C 1 -C 6 alkyl group or a C 1 -C 6 alkoxyalkyl group; R 3 , R 4 and R 5 are independently —H, a C 1 -C 6 alkyl, a C 1 -C 6 alkoxyalkyl group or a C 1 -C 6 alkoxy group; and the anion is selected from the group consisting of X, perchlorate, thiocyanate, cyanate, a C 1 -C 6 carboxylate, an alkyl sulfate, methanesulfonate, BX 4 − , PF 6 − , AsF 6 − , SbF 6 − , NO 2 − , NO 3 − and SO 4 − ; wherein X is a halide; and
(b) delivering the aqueous fluid with entrained ionic liquid into the subterranean formation
wherein (i) the amount of ionic liquid in the well treatment composition is between from about 0.03 to 0.6 percent by volume; (ii) the ionic liquid is in contact with the formation for a time sufficient to inhibit swelling of clay particulates in the formation; and (iii) the affinity of clay particulates in the formation for the ionic liquid is maintained after treatment of the subterranean formation with the well treatment composition.
2. The method of claim 1 , wherein R 3 , R 4 and R 5 are —H.
3. The method of claim 2 , wherein R 1 and R 2 are methyl or ethyl.
4. The method of claim 3 , wherein the anion is a halide.
5. The method of claim 4 , wherein the ionic liquid is 1-ethyl-3-methylimidazolium chloride.
6. The method of claim 1 , wherein the aqueous fluid is selected from the group consisting of a drilling fluid, drill-in fluid, stimulation fluid and gravel pack fluid.
7. The method of claim 6 , wherein the aqueous fluid is selected from the group consisting of a fracturing fluid and acidizing fluid.
8. The method of claim 1 , wherein the amount of ionic liquid in the well treatment composition is between from about 0.1 to 0.6 percent by volume.
9. The method of claim 1 , wherein the cation is 1-ethyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazolium methanesulfonate, 1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium methanesulfonate, 1-ethyl-2,3-di-methylimidazolium ethylsulfate, and 1,2,3-trimethyl-imidazolium methylsulfate.
10. The method of claim 1 , wherein the amount of ionic liquid in the well treatment composition is between from about 0.03 to about 0.06 percent by volume.
11. The method of claim 6 , wherein the aqueous fluid is a gravel pack fluid.
12. The method of claim 1 , wherein the clay is selected from the group consisting of montmorillonite, saponite, nontronite, hectorite, sauconite; kaolinite, nacrite, dickite, halloysite, hydrobiotite, glauconite, illite, bramallite, chlorite, chamosite, vermiculite, attapulgite and sepiolite.
13. A method of treating a subterranean formation to substantially prevent swelling of the clay in the formation which comprises introducing into the formation a well treatment composition comprising an ionic liquid dispersed, dissolved or entrained in an aqueous fluid, wherein the amount of ionic liquid in the well treatment composition is between from about 0.03 to 0.6 percent by volume and wherein the ionic liquid is selected from the group consisting of 1-ethyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazolium methanesulfonate, 1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium methanesulfonate, methyl-tri-n-butylammonium methylsulfate, 1-ethyl-2,3-di-methylimidazolium ethylsulfate, 1,2,3-trimethyl-imidazolium methylsulfate and tris-(2-hydroxyethyl)-methylammonium methylsulfate.
14. The method of claim 13 , wherein the ionic liquid is 1-ethyl-3-methylimidazolium chloride.
15. The method of claim 13 , wherein the aqueous fluid is selected from the group consisting of a fracturing fluid and acidizing fluid.
16. The method of claim 13 , wherein the aqueous fluid is selected from the group consisting of a drilling fluid, drill-in fluid, stimulation fluid and gravel pack fluid.
17. The method of claim 13 , wherein the amount of ionic liquid in the well treatment composition is between from about 0.1 to about 0.6 percent by volume.
18. A method of reducing or substantially eliminating permeability damage caused by swellable clay in a subterranean formation comprising:
(a) introducing into the subterranean formation an aqueous well treatment fluid comprising an ionic liquid entrained within an aqueous fluid, wherein the ionic liquid is present in the aqueous well treatment fluid in an amount between from about 0.03 to 0.6 percent by volume and wherein the ionic liquid comprises a cation and an anion, the cation being an imidazolium of formula (I):
wherein R 1 and R 2 are independently a C 1 -C 6 alkyl group or a C 1 -C 6 alkoxyalkyl group; R 3 , R 4 and R 5 are independently —H, a C 1 -C 6 alkyl, a C 1 -C 6 alkoxyalkyl group or a C 1 -C 6 alkoxy group; and the anion is selected from the group consisting of X, perchlorate, thiocyanate, cyanate, a C 1 -C 6 carboxylate, an alkyl sulfate, methanesulfonate, BX 4 − , PF 6 − , AsF 6 − , SbF 6 − , NO 2 − , NO 3 − and SO 4 − ; wherein X is a halide; and
(b) preventing the swelling and migration of the swellable clay in the formation upon exposure of the swellable clay to water, the affinity of the swellable clay with the ionic liquid preventing the swelling of the swellable clay.
19. The method of claim 18 , wherein the ionic liquid is selected from the group consisting of 1-ethyl-3-methylimidazolium chloride,1-ethyl-3-methylimidazolium methanesulfonate, 1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium methanesulfonate, 1-ethyl-2,3-di-methylimidazolium ethylsulfate, and 1,2,3-trimethyl-imidazolium methylsulfate.
20. The method of claim 18 , wherein R 3 , R 4 and R 5 are —H.
21. The method of claim 20 , wherein R 1 and R 2 are methyl or ethyl.
22. The method of claim 21 , wherein the anion is a halide.
23. The method of claim 18 , wherein the anion is a halide.
24. The method of claim 18 , wherein the aqueous fluid is selected from the group consisting of a fracturing fluid, acidizing fluid, drilling fluid, drill-in fluid, stimulation fluid and gravel pack fluid.
25. The method of claim 18 , wherein R 1 and R 2 are methyl or ethyl and R 3 , R 4 and R 5 are —H.