Ethylene-tetrafluoroethylene copolymer
View Patent ↗The present invention provides an ETFE-type copolymer having a high melt tension and excellent blow moldability. An ethylene-tetrafluoroethylene copolymer which comprises ethylene units, tetrafluoroethylene units and units of a monomer (A) having at least two copolymerizable double bonds and which has a ratio (X/W) of its melt tension (XmN) to a load (Wkg) applied for the measurement of the melt tension being at least 0.8.
1. An ethylene-tetrafluoroethylene copolymer which consists essentially of ethylene units, tetrafluoroethylene units, units of a monomer (A) having at least two copolymerizable double bonds, and optionally units of a monomer (B) having one copolymerizable double bond,
wherein
monomer (A) is a monomer represented by the following formula:
Y—R f —Z
wherein R f is a polyfluoroalkylene group, and each of Y and Z which are independent of each other, is a vinyl group, a trifluorovinyl group or a trifluorovinyloxy group,
monomer (B) is CH 2 ═CH—C n F 2n+1 wherein n is an integer of from 4 to 8,
the proportion of the tetrafluoroethylene units is from 30 to 70 mol % and the proportion of the ethylene units is from 70 to 30 mol %, based on the total of the tetrafluoroethylene units and the ethylene units,
the proportion of units of the monomer (A) is 0.01 to 0.2 mol % based on the total of the tetrafluoroethylene units and the ethylene units to be charged for polymerization,
the proportion of units of the monomer (B), when present, is from more than 0 mol % to 10 mol %, based on the total of the tetrafluoroethylene units and the ethylene units,
and wherein the copolymer has a ratio (X/W) of its melt tension (XmN) to a load (Wkg) applied for the measurement of the melt tension being at least 0.8.
2. The ethylene-tetrafluoroethylene copolymer according to claim 1 , wherein the proportion of the tetrafluoroethylene units is from 40 to 60 mol % and the proportion of the ethylene units is from 60 to 40 mol %, based on the total of the tetrafluoroethylene units and the ethylene units.
3. The ethylene-tetrafluoroethylene copolymer according to claim 1 , where monomer (B) is present.
4. The ethylene-tetrafluoroethylene copolymer according to claim 3 , wherein n is 4.
5. The ethylene-tetrafluoroethylene copolymer according to claim 3 , wherein the proportion of units of the monomer (B) is 0.1 to 5 mol %, based on the total of the tetrafluoroethylene units and the ethylene units.
6. The ethylene-tetrafluoroethylene copolymer according to claim 1 , wherein the monomer (A) is a monomer represented by the following formula:
CH 2 ═CH—(CF 2 ) n —CH═CH 2
wherein n is an integer of from 4 to 8.
7. The ethylene-tetrafluoroethylene copolymer according to claim 6 , which consists of said ethylene units, said tetrafluoroethylene units, and said units of monomer (A).
8. The ethylene-tetrafluoroethylene copolymer according to claim 7 , wherein the proportion of units of the monomer (A) is 0.03 to 0.1 mol % based on the total of the tetrafluoroethylene units and the ethylene units to be charged for polymerization.
9. The ethylene-tetrafluoroethylene copolymer according to claim 6 , which consists of said ethylene units, said tetrafluoroethylene units, said units of monomer (A), and said units of monomer (B).
10. The ethylene-tetrafluoroethylene copolymer according to claim 9 , wherein the proportion of units of the monomer (A) is 0.03 to 0.1 mol % based on the total of the tetrafluoroethylene units and the ethylene units to be charged for polymerization.
11. The ethylene-tetrafluoroethylene copolymer according to claim 6 , wherein the proportion of units of the monomer (A) is 0.03 to 0.1 mol % based on the total of the tetrafluoroethylene units and the ethylene units to be charged for polymerization.
12. The ethylene-tetrafluoroethylene copolymer according to claim 1 , wherein the ratio (X/W) is from 0.8 to 5.
13. The ethylene-tetrafluoroethylene copolymer according to claim 1 , wherein Y and Z are the same.
14. The ethylene-tetrafluoroethylene copolymer according to claim 13 , wherein Y and Z are both vinyl groups or trifluorovinyl groups.
15. The ethylene-tetrafluoroethylene copolymer according to claim 1 , wherein the proportion of units of the monomer (A) is 0.03 to 0.1 mol % based on the total of the tetrafluoroethylene units and the ethylene units to be charged for polymerization.
16. The ethylene-tetrafluoroethylene copolymer according to claim 1 , where monomer (B) is not present.
17. The ethylene-tetrafluoroethylene copolymer according to claim 1 , which consists of said ethylene units, said tetrafluoroethylene units, and said units of monomer (A).
18. The ethylene-tetrafluoroethylene copolymer according to claim 1 , which consists of said ethylene units, said tetrafluoroethylene units, said units of monomer (A), and said units of monomer (B).