Coated article with low-E coating having zinc stannate based layer between IR reflecting layers for reduced mottling and corresponding methods
View Patent ↗A coated article is provided which may be heat treated (e.g., thermally tempered) and/or heat bent in certain example instances. In certain example embodiments, a zinc stannate based layer is provided between a tin oxide based layer and a silicon nitride based layer, and this has been found to significantly reduce undesirable mottling damage upon heat treatment/bending. This results in significantly improved bendability of the coated article in applications such as vehicle windshields and the like.
1. A bent vehicle windshield comprising first and second bent glass substrates, the first bent substrate supporting a coating thereon, the coating comprising:
a first dielectric layer supported by the first bent glass substrate;
a first infrared (IR) reflecting layer supported by the first bent glass substrate and located over at least the first dielectric layer;
a first layer comprising tin oxide located over at least the first IR reflecting layer and the first dielectric layer;
a first layer comprising zinc stannate located over and contacting the first layer comprising tin oxide;
a layer comprising silicon nitride located over at least the first layer comprising zinc stannate;
a second IR reflecting layer located over at least the layer comprising silicon nitride; and
at least another dielectric layer located over at least the second IR reflecting layer.
2. The windshield of claim 1 , further comprising a layer comprising zinc oxide located under and contacting the second IR reflecting layer, and wherein the layer comprising zinc oxide is over and contacting the layer comprising silicon nitride.
3. The windshield of claim 1 , further comprising an overcoat layer of zirconium oxide.
4. The windshield of claim 1 , wherein the layer comprising silicon nitride directly contacts the layer comprising zinc stannate.
5. The windshield of claim 1 , wherein the windshield is bent to a degree sufficient so as to have a centerline convex value “x” of at least about 26 mm, and is substantially free of mottling.
6. The windshield of claim 1 , wherein the windshield is bent to a degree sufficient so as to have a centerline convex value “x” of at least about 28 mm, and is substantially free of mottling.
7. The windshield of claim 1 , wherein the windshield is bent to a degree sufficient so as to have a centerline convex value “x” of at least about 30 mm, and is substantially free of mottling.
8. A coated article comprising a coating supported by a glass substrate, the coating comprising from the glass substrate, the coating comprising from the glass substrate outwardly:
a layer comprising silicon nitride;
a first layer comprising zinc oxide located over and contacting the layer comprising silicon nitride;
a first infrared (IR) reflecting layer located over and contacting the layer comprising zinc oxide;
a layer comprising tin oxide located over the first IR reflecting layer;
a layer comprising zinc stannate located over the layer comprising tin oxide;
a layer comprising silicon nitride located over the layer comprising zinc stannate;
a second IR reflecting layer located over the layer comprising silicon nitride; and
at least another dielectric layer located over the second IR reflecting layer.
9. The coated article of claim 8 , wherein the coated article is heat treated and is bent to a degree sufficient so as to have a centerline convex value “x” of at least about 26 mm.
10. The coated article of claim 8 , wherein the coated article is heat treated and is bent to a degree sufficient so as to have a centerline convex value “x” of at least about 28 mm and is substantially free of mottling.