Process for the production of propylene random copolymers for injection moulding applications
View Patent ↗Process for the production of polypropylene random copolymers containing 2.5 to 5.0 wt % of ethylene as comonomer and having an MFR 2 in accordance with ISO 1 133 (230° C., 2.16 kg load) of ≧25 g/10 min to 100 g/10 min and a hexane-solubles content, determined according to FDA CFR 21 §177.1520 below 5 wt %, said process comprising the step of polymerizing propylene and ethylene in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester as internal donor and (ii) an organometallic cocatalyst and (iii) an external donor represented by formula (I) or (II) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) (I) or Si(OCH 3 ) 2 (CH 3 (cyclohexyl) (II) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms, the polypropylene random copolymers with a low level of odor and taste themselves and their use for injection molding applications, preferably for thin-wall packaging for food packaging in non-cooking applications and for medical packaging.
1. Process for the production of polypropylene random copolymers with a low level of odour and taste containing 2.5 to 5.0 wt % of ethylene as comonomer and having an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ≧25 g/10 min to 100 g/10 min and a hexane-solubles content, determined according to FDA CFR 21 §177.1520 below 5 wt %, said process comprising the step of polymerizing propylene and ethylene in the presence of a catalyst system comprising
(i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester as internal donor and
(ii) an organometallic cocatalyst and
(iii) an external donor represented by formula (I)
Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) (I)
wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms,
wherein the polypropylene random copolymer has a xylene soluble fraction of less than 8 wt %.
2. Process according to claim 1 wherein the procatalyst (i) used has been prepared by
a) reacting a spray crystallized or emulsion solidified adduct of MgCl 2 and a C 1 -C 2 -alcohol with TiCl 4
b) reacting the product of stage a) with a dialkylphthalate of formula (III)
wherein R 1 ′ and R 2 ′ are independently at least a C 5 -alkyl
under conditions where a transesterification between said C 1 -C 2 -alcohol and said dialkylphthalate of formula (III) takes place to form the internal donor
c) washing the product of stage b) and
d) optionally reacting the product of step c) with TiCl 4 .
3. Process according to claim 2 , wherein the dialkylphthalate of formula (III) is dioctylphthalate and that the C 1 -C 2 -alcohol is ethanol.
4. Process according to claim 1 , wherein the Ziegler-Natta procatalyst (i) is used in the presence of an organometallic cocatalyst (ii) selected from the group consisting of trialkylaluminium, dialkyl aluminium chloride and alkyl aluminium sesquichloride.
5. Process according to claim 4 , wherein the cocatalyst is triethylaluminium.
6. Process according to claim 1 , wherein the polypropylene random copolymer is produced in one or two slurry reactors or in a combination of one or two slurry reactor(s) and one or two gas phase reactor(s).