Organic electroluminescent device having triptycene derivative material
View Patent ↗Disclosed is a useful organic EL device which comprises a phosphorescent light-emitting layer and is endowed with improved luminous efficiency and high driving stability. Also disclosed is a hole-transporting material suitable for use in the phosphorescent light-emitting device. The hole-transporting material is a triptycene derivative which has substituents at the 9- and 10-positions and is substituted with an aromatic group containing at least one diarylamino group (—ArNAr 2 ). The organic EL device contains the triptycene derivative in at least one organic layer selected from the group of a phosphorescent light-emitting layer, a hole-transporting layer, an electron-blocking layer, and an exciton-blocking layer. The diarylamino group (—NAr 2 ) may be fused to form an aromatic heterocyclic group such as a carbazolyl group.
1. An organic electroluminescent device comprising an anode, organic layers containing a phosphorescent light-emitting layer, and a cathode piled one upon another on a substrate wherein the organic layer of the phosphorescent light-emitting layer comprises a triptycene derivative represented by general formula (1):
wherein in general formula (1), A 1 to A 5 each is independently a substituent represented by formula (2);
a, b, and c each is an integer of 0-2 and 0≦a+b+c≦3; and
R 1 and R 2 each is independently hydrogen, an alkyl group of 1-10 carbon atoms, an alkoxyl group of 1-6 carbon atoms, or an acyl group of 2-6 carbon atoms;
wherein in formula (2), n is an integer of 0-1 and the sum of n's in general formula (1) is an integer of 1;
L is a group derived from benzene, pyridine, or pyrimidine; and
Ar 1 and Ar 2 each is independently an aromatic hydrocarbon group of 6-18 carbon atoms or an aromatic heterocyclic group of 3-17 carbon atoms, and Ar 1 , Ar 2 and the nitrogen atom together optionally form a nitrogen-containing heterocycle.
2. The organic electroluminescent device as described in claim 1 , wherein the substituent represented by formula (2) is a substituent represented by formula (3):
wherein L and n respectively have the same meaning as in formula (2);
X is independently a methine group or nitrogen;
the two aromatic rings bonded to the nitrogen atom are optionally fused to form three rings with a ring containing the said nitrogen atom being located at the center ring.
3. The organic electroluminescent device as described in claim 1 , wherein the triptycene derivative represented by general formula (1) is a triptycene derivative represented by general formula (4):
wherein A 1 , A 2 , R 1 , and R 2 respectively have the same meaning as in general formula (1); however, the sum of the integers designated as n in formula (2) is 1 in general formula (4);
B 1 to B 3 each is independently the substituent represented by formula (2), but all the integers designated as n are 0; and
d, e, and f each is an integer of 0-2 and 0≦d+e+f≦3.