Blended polyolefin dispersions
View Patent ↗Blended polyolefin dispersions, including: (A) a liquid; (B) an olefin-based polymer dispersed in the liquid, the dispersed olefin-based polymer having an average particle size ranging from 0.1 to 5 microns; and (C) an alpha-beta unsaturated carboxylic acid-based polymer dispersed in the liquid, the dispersed alpha-beta unsaturated carboxylic acid-based polymer having an average particle size ranging from 0.02 microns to 1 micron. Coatings, froths, foams, toners, and other various uses for the blended dispersions are also disclosed.
1. A blended polyolefin dispersion comprising:
a blend dispersion formed from
(A) a first dispersion comprising (i) an ethylene/α-olefin multi-block copolymer having hard segments and soft segments and (ii) a surfactant, the dispersed ethylene/α-olefin multi-block copolymer having an average particle size ranging from 0.1 to 5 microns; and
(B) a second dispersion having a pKa greater than or equal to 10 and comprising an alpha-beta unsaturated carboxylic acid-based polymer, the dispersed alpha-beta unsaturated carboxylic acid-based polymer having an average particle size ranging from 0.02 microns to 1 micron,
wherein the average particle size of (A) is larger than the average particle size of (B).
2. The blended polyolefin dispersion of claim 1 , wherein the first or second dispersion further comprises at least one of water, a liquid hydrocarbon, and a water-compatible organic compound.
3. The blended polyolefin dispersion of claim 1 , wherein the average particle size of (A) is at least twice the average particle size of (B) by at least 50%.
4. The blended polyolefin dispersion of claim 1 , wherein the particles size of (A) is at least ten times larger than the particle size of (B).
5. The blended polyolefin dispersion of claim 1 , wherein the number average molecular weight of (A) is larger than the number average molecular weight of (B), as measured by gel permeation chromatography.
6. The blended polyolefin dispersion of claim 1 , wherein the number average molecular weight of (A) is at least twice the number average molecular weight of (B), as measured by gel permeation chromatography.
7. The blended polyolefin dispersion of claim 1 , wherein the alpha-beta unsaturated carboxylic acid-based polymer comprises at least one of an ethylene-acrylic acid copolymer and an ethylene-methacrylic acid copolymer.
8. The blended polyolefin dispersion of claim 1 , wherein the alpha-beta unsaturated carboxylic acid-based polymer is at least partially neutralized.
9. A froth produced from the dispersion of claim 1 .
10. A foam produced from the dispersion of claim 1 .
11. The blended polyolefin dispersion of claim 1 comprising from 80 wt % to 95 wt % of the first dispersion (A) and from 20 wt % to 5 wt % of the second dispersion (B).
12. The blended polyolefin dispersion of claim 1 , wherein the blend dispersion has a pH greater than 7.0.
13. The blended polyolefin dispersion of claim 1 , wherein the blend dispersion has a pH greater than 9.0.
14. The blended polyolefin dispersion of claim 1 , wherein the dispersed ethylene/α-olefin multi-block copolymer has an average particle size from 0.5 microns to 2.7 microns and the dispersed alpha-beta unsaturated carboxylic acid-based polymer has an average particle size from 0.06 to 1.0 microns.