Heat transfer methods, systems and compositions
View Patent ↗The present invention relates to a refrigerant composition, including difluoromethane (HFC-32), pentafluoroethane (HFC-125), and trifluoroiodomethane (CF 3 I) for use in a heat exchange system, including air conditioning and refrigeration applications and in particular aspects to the use of such compositions as a replacement of the refrigerant R-410A for heating and cooling applications and to retrofitting heat exchange systems, including systems designed for use with R-410A.
1. A refrigerant blend consisting of:
about 50% by weight difluoromethane (HFC-32),
about 11.5% by weight pentafluoroethane (HFC-125), and
about 38.5% by weight trifluoroiodomethane (CF 3 I),
wherein the percentages are based on the total weight of the three compounds in the blend.
2. A heat transfer composition comprising a refrigerant according to claim 1 .
3. The heat transfer composition as claimed in claim 2 , wherein the refrigerant comprises greater than 70% by weight of the heat transfer composition.
4. The heat transfer composition of claim 3 further comprising a stabilizer selected from a diene based compound, or a diene based compound and a phosphorous compound, and/or a nitrogen compound and/or a phenol compound.
5. The heat transfer composition of claim 4 wherein the diene based compound is a terpene selected from the group consisting of terebene, retinal, geraniol, terpinene, delta-3 carene, terpinolene, phellandrene, fenchene, myrcene, farnesene, pinene, nerol, citral, camphor, menthol, limonene, nerolidol, phytol, carnosic acid and vitamin A 1 , and combinations of two or more of these.
6. The heat transfer composition of claim 4 wherein the stabilizer composition comprises a diene based compound and a phosphorous compound, wherein said phosphorous compound is a phosphite compound selected from diaryl phosphite, dialkyl phosphite, triaryl phosphite and/or trialkyl phosphite and/or a phosphate compound selected from triaryl phosphate, trialkyl phosphate, alkyl mono acid phosphate, aryl diacid phosphate, amine phosphate and combinations of two or more of these.
7. The heat transfer composition of claim 6 wherein the phosphorous compound is a phosphite compound selected from the group consisting of hindered phosphites, tris-(di-tert-butylphenyl)phosphite, di-n-octyl phophite, iso-decyl diphenyl phosphite and diphenyl phosphite.
8. The heat transfer composition of claim 7 wherein the stabilizer composition comprises farnesene and diphenyl phosphite.
9. The heat transfer composition of claim 7 further comprising a nitrogen compound selected from dinitrobenzene, nitrobenzene, nitromethane, nitrosobenzene, and TEMPO [(2,2,6,6-tetramethylpiperidin-1-yl)oxyl], and combinations of two or more of these.
10. The heat transfer composition of claim 4 wherein the stabilizer composition comprises BHT in an amount of from about 0.001% by weight to about 5% by weight of the heat transfer composition.
11. The heat transfer composition of claim 10 wherein the stabilizer composition comprises farnesene, diphenyl phosphite and BHT.
12. The heat transfer composition of claim 2 further comprising a polyol ester (POE) lubricant.
13. The heat transfer composition of claim 2 wherein said refrigerant has a Global Warming Potential (GWP) of not greater than 750.
14. A method of cooling in a heat transfer system comprising an evaporator, a condenser and a compressor, the method comprising i) condensing a refrigerant blend according to claim 1 , and ii) evaporating the blend in the vicinity of a body or article to be cooled;
wherein the evaporator temperature of the heat transfer system is in the range of from about −40° C. to about −10° C.
15. The method of claim 14 wherein the heat transfer system is an air conditioning system.
16. A method of replacing an existing refrigerant contained in a heat transfer system comprising removing at least a portion of said existing refrigerant from said system, said existing refrigerant being R-410A and replacing at least a portion of said existing refrigerant by introducing into said system a refrigerant according to claim 1 .
17. The method of claim 16 wherein the heat transfer system is an air conditioning system.