Method for the production of glycols from sorbitol
View Patent ↗Implementations of the disclosed subject matter provide a process for producing ethylene glycol and propylene glycol from a sorbitol feed which may include contacting the sorbitol feed with hydrogen in a reactor in the presence of a solvent and a bi-functional catalyst system. The bi-functional catalyst system may include a first catalyst comprising a copper compound, a zinc compound, and an additional metal compound and a second catalyst comprising sodium carbonate.
1. A process for producing ethylene glycol and propylene glycol from a sorbitol feed comprising:
contacting the sorbitol feed with hydrogen in a reactor in the presence of a solvent and a bi-functional catalyst system comprising:
1) a first catalyst comprising a copper compound, a zinc compound, and an additional metal compound, and
2) a second catalyst comprising sodium carbonate.
2. The process of claim 1 , wherein the additional metal compound comprises at least one selected from the group consisting of: zirconium, aluminum, magnesium, praseodymium, neodymium, promethium, gadolinium, yttrium, lanthanum, samarium, thorium, cerium, europium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, titanium, scandium, and mixtures thereof.
3. The process of claim 1 , wherein the additional metal compound comprises lanthanum.
4. The process of claim 3 , wherein the first catalyst further comprises at least one metal selected from the group consisting of: zirconium, aluminum, magnesium, praseodymium, neodymium, promethium, gadolinium, yttrium, samarium, thorium, cerium, europium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, titanium, scandium, and mixtures thereof.
5. The process of claim 1 , wherein the concentration of sorbitol in the sorbitol feed is between about 1 wt % to 75 wt % sorbitol.
6. The process of claim 5 , wherein the ratio of the amount of the first catalyst to the second catalyst is between about 0.3 to 1.
7. The process of claim 6 , wherein the total amount of the first and second catalysts is 0.3-0.5 wt % on the basis of the total reactants and solvent entering the reactor.
8. The process of claim 1 , wherein the sorbitol feed is the product of a hydrogenation process of a C6 monomer containing carbohydrate feed.
9. The process of claim 1 , further comprising obtaining a product stream from the reactor comprising a yield of at least 10 wt % EG.
10. The process of claim 1 , further comprising obtaining a product stream from the reactor comprising a yield of at least 15 wt % PG.