PDC cutter with chemical addition for enhanced abrasion resistance
View Patent ↗A superabrasive cutter and a method of making the superabrasive cutter are disclosed. The superabrasive cutter may comprise a plurality of polycrystalline superabrasive particles and about 0.01% to about 4% by weight of the superabrasive particles of a dopant as evaluated prior to a high pressure/high temperature process. The dopant may be immiscible with a catalyst for forming the polycrystalline superabrasive particles.
1. A superabrasive cutter, comprising:
a substrate; and
a polycrystalline superabrasive composite bonded to the substrate, the polycrystalline superabrasive composite comprising:
a plurality of superabrasive particles that are sintered to form the polycrystalline superabrasive composite in a high pressure/high temperature process;
a catalyst that promotes sintering between the superabrasive particles; and
about 0.01% to about 4% by weight of the superabrasive particles of a dopant evaluated prior to and before the high pressure/high temperature process is performed,
wherein when the dopant and the catalyst are both are held above their respective melting points, the dopant is substantially immiscible with the catalyst and is a semiconductor comprising at least one of bismuth telluride or germanium, and
wherein the dopant has a solubility of less than about 1.0% with the catalyst.
2. The superabrasive cutter of claim 1 , wherein the superabrasive particles are selected from a group of cubic boron nitride, diamond, and diamond composite materials.
3. The superabrasive cutter of claim 1 , wherein the dopant optionally further includes a metalloid comprising at least one of antimony or tellurium.
4. The superabrasive cutter of claim 1 , wherein the dopant has a lower melting temperature than the catalyst.
5. The superabrasive cutter of claim 1 , wherein the dopant is present in an amount by weight of the superabrasive particles of less than about 1.0% evaluated prior to the high pressure/high temperature process.
6. The superabrasive cutter of claim 1 , wherein the dopant is present in an amount by weight of the superabrasive particles in a range from about 1.0% to about 2.0% evaluated prior to the high pressure/high temperature process.
7. The superabrasive cutter of claim 6 , wherein the dopant is present in an amount by weight of the superabrasive particles of less than about 1.5% evaluated prior to the high pressure/high temperature process.
8. The superabrasive cutter of claim 1 , wherein the dopant is distributed throughout the polycrystalline superabrasive particles.
9. The superabrasive cutter of claim 1 , wherein the polycrystalline superabrasive composite comprises a first polycrystalline superabrasive zone that is absent of any catalyst material beyond unavoidable remnants of the catalyst and that is positioned distally from the substrate and a second polycrystalline superabrasive zone that contains the catalyst material beyond unavoidable remnants and that is positioned proximally to the substrate.
10. The superabrasive cutter of claim 1 , wherein the dopant is present in the polycrystalline superabrasive composite following the high pressure/high temperature process.