Method and system for water based phenolic binders for silicon-dominant anodes
Systems and methods for water based phenolic binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a pyrolyzed water-based phenolic binder. The water-based phenolic binder may include phenolic/resol type polymers crosslinked with poly(methyl vinyl ether-alt-maleic anhydride), poly(methyl vinyl ether-alt-maleic acid), and/or Poly(acrylamide-co-diallyldimethylammonium chloride) (PDADAM). The electrode coating layer may further include conductive additives. The current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer may include more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte, where the electrolyte includes a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.
1. A battery electrode, the electrode comprising:
an electrode coating layer on a current collector, the electrode coating layer formed from silicon and a pyrolyzed water-based phenolic binder, wherein the water-based phenolic binder comprises one or more of:
(a) a phenolic/resol type polymer crosslinked with poly(methyl vinyl ether-alt-maleic anhydride);
(b) a phenolic/resol type polymer crosslinked with poly(methyl vinyl ether-alt-maleic acid);
(c) a phenolic/resol type polymer crosslinked with poly(acrylamide-co-diallyldimethylammonium chloride) (PDADAM);
(d) a phenol-crotonaldehyde-resorcinol derivative; and
(e) a phenolic/resol type polymer derivatized by one or more functional groups selected from the group consisting of ethers, polyethoxylates, esters, glycolipids, phosphates, oxiranes, and/or carbamates.
2. The electrode according to claim 1 , wherein the electrode coating layer further comprises conductive additives.
3. The electrode according to claim 1 , wherein the current collector comprises one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer.
4. The electrode according to claim 1 , wherein the electrode coating layer comprises more than 70% silicon.
5. A battery, the battery comprising:
a cathode, a separator, an electrolyte, and an anode, the anode comprising an electrode coating layer on a current collector, the electrode coating layer formed from silicon and a pyrolyzed water-based phenolic binder, wherein the water-based phenolic binder comprises one or more of:
(a) a phenolic/resol type polymer crosslinked with poly(methyl vinyl ether-alt-maleic anhydride);
(b) a phenolic/resol type polymer crosslinked with poly(methyl vinyl ether-alt-maleic acid);
(c) a phenolic/resol type polymer crosslinked with poly(acrylamide-co-diallyldimethylammonium chloride) (PDADAM);
(d) a phenol-crotonaldehyde-resorcinol derivative; and
(e) a phenolic/resol type polymer derivatized by one or more functional groups selected from the group consisting of ethers, polyethoxylates, esters, glycolipids, phosphates, oxiranes, and/or carbamates.