Catalyst component for the preparation of nucleated polyolefins

1. Process for the production of a nucleated polypropylene composition, comprising:

A) obtaining a catalyst composition containing a catalyst component through the steps of:

a1) providing a solution of at least a Group 2 metal alkoxy compound (Ax) being the reaction product of a Group 2 metal compound (MC) and a monohydric alcohol (A) comprising in addition to the hydroxyl moiety at least one ether moiety optionally in an organic liquid reaction medium; or

a2) providing a solution of at least a Group 2 metal alkoxy compound (Ax′) being the reaction product of a Group 2 metal compound (MC) and an alcohol mixture of the monohydric alcohol (A) and a monohydric alcohol (B) of formula ROH, optionally in an organic liquid reaction medium; or

a3) providing a solution of a mixture of the Group 2 metal alkoxy compound (Ax) and a Group 2 metal alkoxy compound (Bx) being the reaction product of a Group 2 metal compound (MC) and the monohydric alcohol (B), optionally in an organic liquid reaction medium; or

a4) providing a solution of Group 2 metal alkoxy compound of formula M(OR1) n (OR2) m X 2−n−m or mixture of Group 2 alkoxides M(OR1) n′ X 2−n′ and M(OR2) m′ X 2−m′ , where M is Group 2 metal, X is halogen, R1 and R2 are different alkyl groups of C2 to C16 carbon atoms, and 0<n<2, 0<m<2 and n+m+(2−n−m)=2, provided that both n and m≠0, 0<n′<2 and 0<m′<2; and

b) adding said solution from step a1, a2, a3, or a4 to at least one compound (TC) of a transition metal of Group 4 to 6, and

c) obtaining the solid catalyst component particles,

d) washing said solidified particles,

e) recovering the solidified particles of the olefin polymerisation catalyst component,

wherein an electron donor is added at any step prior to step c) and is a non-phthalic internal electron donor,

wherein the catalyst component is washed in step d) at least three times with at least one toluene and at least one TiCl 4 washing step and 1 to 3 further washing steps with an aromatic and/or aliphatic hydrocarbon selected from toluene heptane, or pentane;

wherein internal donor is added to either the toluene washing step and/or the TiCl 4 washing step in an amount of 10 to 60 wt % of the total amount of donor used in catalyst preparation steps a) to d);

wherein the catalyst component is further modified by a polymeric nucleating agent comprising vinyl compound units, and wherein the catalyst modification is performed until the concentration of unreacted vinyl compound is less than 0.1 wt %; and

B) polymerizing propylene, optionally with co-monomers selected from C2 or C4 to C12 monomers in the presence of the catalyst composition obtained from step A), wherein the nucleated polypropylene composition comprises a polymeric nucleating agent in an amount in the range from 15 to 500 ppm.

2. The process according to claim 1 , wherein the polymeric nucleating agent is selected from the group of vinyl alkanes or vinyl cycloalkanes, 3-methyl-1-butene, 3-ethyl-1-hexene, 3-methyl-1-pentene, 4-methyl-1-pentene or mixtures thereof.

3. The process according to claim 1 , wherein the internal donor (ID) used in the preparation of the catalyst component is selected from (di)esters of non-phthalic carboxylic (di)acids, 1,3-diethers, derivatives and mixtures thereof.

4. The process according to claim 3 , wherein the electron donor for the catalyst component is selected from diesters of mono-unsaturated dicarboxylic acids, belonging to the group comprising malonates, maleates, succinates, citraconates, glutarates, cyclohexene-1,2-dicarboxylates and benzoates, and any derivatives and/or mixtures thereof.

5. The process according to claim 1 , wherein the catalyst composition comprises the modified catalyst component together with a co-catalyst and an external donor for the polymerization of propylene, optionally with co-monomers selected from C2 or C4 to C12 monomers.