Haze-free base oils with high paraffinic content
The present invention relates to a method for reducing the cloud point of a base oil with high saturates/paraffinic content to below 0° C., wherein the method comprises subjecting said base oils to a cloud point reduction step comprising adding said base oil to a solvent mixture, wherein the solvent mixture comprises a paraffin naphtha fraction and a co-solvent to obtain a solvent treatment mixture; and subjecting the solvent treatment mixture to a solvent de-waxing step.
1. A method for reducing the cloud point of a base oil comprising a high saturates and paraffinic content to below 0° C., the method comprising:
(a) combining the base oil with a solvent and a co-solvent to form a treatment mixture,
wherein the solvent comprises a paraffinic naphtha fraction, and
wherein the co-solvent comprises one or more of methyl isobutyl ketone, methyl butyl ketone, methyl propyl ketone, and methyl isopropyl ketone; and
(b) cooling the treatment mixture to a temperature of less than −20° C. to form a wax crystal and a de-waxed mixture comprising a portion of the solvent and a de-waxed oil;
(c) separating the wax crystal from the de-waxed mixture to form a separated de-waxed mixture comprising the portion of the solvent and the de-waxed oil;
(d) distilling the separated de-waxed mixture to form a distilled solvent and a de-waxed oil, wherein the de-waxed oil comprises a cloud point below 0° C.
2. The method according to claim 1 , wherein the paraffinic naphtha fraction comprises paraffinic molecules comprising carbon chain lengths in the range of from 5 to 11.
3. The method according to claim 1 , wherein the paraffinic naphtha fraction comprises paraffinic molecules of at least one of carbon chain length 6, 7 and 8.
4. The method according to claim 1 , wherein the paraffinic naphtha fraction comprises paraffinic molecules of carbon chain length comprising one or more of 5, 6, 7, 8, 9, 10, and 11.
5. The method according to claim 1 , wherein the co-solvent further comprises methyl ethyl ketone.
6. The method according to claim 1 , wherein the weight ratio of the naphtha fraction to the co-solvent is from 70:30 to 30:70.
7. The method according to claim 1 ,
wherein the combining the base oil with the solvent is done at a ratio of base oil to solvent of from 1:3 to 1:6, and
wherein the combining the base oil with the solvent is done at a temperature from 20° C. to 150° C.