Metal-semiconductor contact structure based on two-dimensional semimetal electrodes
Disclosed is a metal-semiconductor contact structure based on two-dimensional (2D) semimetal electrodes, including a semiconductor module and a metal electrode module, where the semiconductor module is a 2D semiconductor material, and the metal electrode module is a 2D semimetal material with no dangling bonds on its surface; the 2D semiconductor material and the 2D semimetal material are interfaced with a Van der Waals interface with a surface roughness of 0.01-1 nanometer (nm) and no dangling bonds on the surface, the 2D semiconductor material and the 2D semimetal material are spaced less than 1 nm apart.
1. A metal-semiconductor contact structure based on two-dimensional (2D) semimetal electrodes, comprising a semiconductor module and a metal electrode module; wherein the semiconductor module is a 2D semiconductor material, and the metal electrode module is a 2D semimetal material with no dangling bonds on a surface; the 2D semiconductor material and the 2D semimetal material are interfaced with a Van der Waals interface with a surface roughness of 0.01-1 nanometer (nm) and no dangling bonds on the surface, the 2D semiconductor material and the 2D semimetal material are spaced less than 1 nm apart; the 2D semiconductor material is a 2D material, and the 2D semimetal material is an MX 2 2D layered semimetal material; the 2D semiconductor material has a thickness of 0.1-20 nm and the 2D semimetal material has a thickness of 1-100 nm; the 2D semimetal material has a work function in a range of 4.0-6.0 electron volts (eV), and the 2D semimetal material creates, with electrodes, a hole Schottky potential barrier with a height of 0-30 million electron volts (meV); the electrodes of 2D semimetal material create Schottky potential barrier comprising electron and hole types; and the 2D semiconductor material and the 2D semimetal material are prepared in a method selected from a combination of chemical vapor deposition, physical vapor deposition, chemical vapor transport, mechanical stripping and organic assisted methods;
the 2D semiconductor material is one selected form a group of boron phosphide (BP), molybdenum ditelluride (MoTe 2 ), molybdenum disulfide (MoS 2 ), tungsten diselenide (WSe 2 ), molybdenum diselenide (MoSe 2 ) and tungsten disulphide (WS 2 );
in the MX 2 2D layered semimetal material, M represents a transition metal and X refers to any chalcogen;
the 2D layered semimetal material is one selected from a group of 1T′-MoTe 2 , 2H-niobium disulfide (2H-NbS 2 ), 1T′-tungsten ditelluride (1T′-WTe 2 ), 1T′-tantalum disulfide (1T′-TeSe 2 ), 1T′-titanium disulfide (1T′-TiS 2 ), 1T-hafnium ditelluride (1T-HfTe 2 ), 1T-titanium ditelluride (1T-TiTe 2 ), 1T′-WS 2 , platina ditelluride (PtTe 2 ) and vanadium diselenide (VSe 2 ); and
the 2D semiconductor material is a doped 2D material, and the doped 2D material comprises metal doping elements of molybdenum (Mo), tungsten (W), niobium (Nb), copper (Cu), aluminum (Al), gold (Au) and iron (Fe), and sulfur doping elements of oxygen (O), sulphur (S), selenium (Se), tellurium (Te), nitrogen (N) and phosphorus (P).