IP Library Granted Patent US 11,661,339
Granted Patent B1
US 11,661,339 · App. 17/135,787 · Granted May 30, 2023

High pressure gas generation system for hydrogen production and other applications

Inventors: Scott Mahar (Poway, CA); Matthew Fish (Vista, CA); Nelson Craig Stephens (San Diego, CA); Dylan Schaubel (Encinitas, CA); Bunsen Wong (La Jolla, CA); Nathaniel LeCompte (Spring Valley, CA)
Assignee: General Atomics
C01B3/08B01J3/02B01J3/03C01B3/061H01M8/04201H01M8/065
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Quick Facts
Patent No.
US 11,661,339
App. No.
17/135,787
Granted
May 30, 2023
Kind
B1
Abstract

Disclosed are apparatuses, systems, methods, and devices for generating high-pressure gas such as hydrogen and oxygen. In one aspect, an apparatus is disclosed. The apparatus includes a reactor which includes a pressure vessel containing a metal compound configured to react with a liquid to generate the high-pressure gas when the liquid is available in the vessel. The reactor includes an outlet configured to pass the generated high-pressure gas out of the vessel. The apparatus also includes a receiver configured to store the generated high-pressure gas generated in the vessel and passed to a receiver via the outlet or passed directly to fuel cell or vehicle tank.

Claims (33)

1. An apparatus for generating a pressurized gas, comprising:

a reactor comprising:

a pressure vessel containing a metal compound configured to react with a liquid via contact between the metal compound and the liquid without applying external heat or power to generate a pressurized gas at a pressure greater than or equal to 2000 pounds per square inch, when the liquid is available in the pressure vessel to be in contact with the metal compound to cause a reaction between the metal compound and the liquid;

an inlet configured to pass the liquid from outside the pressure vessel to inside the pressure vessel; and

an outlet configured to pass the generated pressurized gas out of the pressure vessel while regulating a liquid level in the pressure vessel via the pressure of the generated pressurized gas inside the pressure vessel to control the reaction between the metal compound and the liquid; and

a receiver coupled to the outlet to receive the generated pressurized gas from the pressure vessel and configured to store the generated pressurized gas.

2. The apparatus of claim 1 , wherein the metal compound comprises an alkali metal.

3. The apparatus of claim 1 , wherein the metal compound comprises an aluminum alloy.

4. The apparatus of claim 1 , wherein the liquid includes one or more of fresh water, ocean water, tap water, or other water-based liquid including urine.

5. The apparatus of claim 3 , wherein the aluminum alloy reacts with water according to one or more chemical reactions including:

2Al+6H 2 O→2AlO(OH) 3 +3H 2 ,

2Al+4H 2 O→2AlO(OH)+3H 2 ,

2Al+3H 2 O→Al 2 O 3 +3H 2 ,

and wherein the generated pressurized gas comprises hydrogen.

6. The apparatus of claim 1 , wherein the generated pressurized gas comprises hydrogen and is stored in the receiver at a pressure of 3000 pounds per square inch (psi) or more.

7. The apparatus of claim 1 , wherein the receiver is selected to have a maximum storage capacity for storing hydrogen as the generated pressured gas, and wherein the maximum storage capacity is selected to be a mass of hydrogen between 50 grams and 25 kilograms.

8. The apparatus of claim 1 , wherein the metal compound comprises a potassium superoxide that reacts with water according to 4 KO 2 +2 H 2 O→4 KOH+3 O 2 , and wherein the generated pressurized gas comprises oxygen.

9. The apparatus of claim 1 , wherein the metal compound is further configured to include a coating comprising plastic or salt to delay the reaction after exposure to the liquid.

10. A method of generating a pressurized gas, comprising:

placing a metal compound to be in contact with a liquid in a reactor vessel to cause, without applying external heat or power, a reaction between the metal compound and the liquid to generate a gas; and

pressurizing the gas to a pressure greater than or equal to 2000 pounds per square inch, via the reaction without using a power source, to regulate a level of contact between the metal compound and the liquid to control the reaction between metal compound and the liquid.

11. The method of claim 10 , wherein the metal compound comprises an alkali metal.

12. The method of claim 10 , wherein the metal compound comprises an aluminum alloy.

13. The method of claim 10 , wherein the liquid is one or more of fresh water, ocean water, tap water, or other water-based liquid including urine.

14. The method of claim 12 , wherein the aluminum alloy reacts with water according to one or more chemical reactions including:

2Al+6H 2 O→2AlO(OH) 3 +3H 2 ,

2Al+4H 2 O→2AlO(OH)+3H 2 ,

2Al+3H 2 O→Al 2 O 3 +3H 2 ,

and wherein the generated pressurized gas comprises hydrogen.

15. The method of claim 14 , comprising storing the pressurized hydrogen in a receiver tank at a pressure of 2,000 pounds per square inch (psi) or more.

16. The method of claim 10 , wherein the metal compound includes potassium superoxide and the liquid includes one or more of fresh water, ocean water, tap water, or other water-based liquid including urine.

17. The method of claim 10 , wherein the metal compound comprises a potassium superoxide that reacts with water according to 4 KO 2 +2 H 2 O→4 KOH+3 O 2 , and the pressurized gas comprises oxygen.

18. The method of claim 10 , wherein the metal compound is configured to include a coating comprising plastic or salt to delay the reaction after exposure to the liquid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2020
From: MAHAR, SCOTT; FISH, MATTHEW; STEPHENS, NELSON CRAIG; SCHAUBEL, DYLAN; WONG, BUNSEN; LECOMPTE, NATHANIEL
To: GENERAL ATOMICS
Reel/Frame 054859/0641 →
Cited By (10)
US 12,187,405 US 12,269,571 US 12,275,516 US 12,296,940 US 12,428,124 US 12,429,311 US 12,582,958 US 12,589,853 US 12,698,545 US 12,702,962