Preparation method for ultra-high compacted lithium iron phosphate cathode material and lithium battery
The present application belongs to the field of lithium battery technology, particularly relating to a preparation method for ultra-high compacted lithium iron phosphate cathode material and lithium battery. The method comprises: obtaining an iron-containing precursor based on iron phosphate and dispersant; Mixing the iron-containing precursor, lithium source, phosphorus source, and first carbon source for first sintering to obtain the first precursor mixture and grinding to the first preset particle size to obtain the first precursor; Mixing the iron-containing precursor, lithium source, phosphorus source, and second carbon source for second sintering to obtain the second precursor mixture and grinding to the second preset particle size to obtain the second precursor; Mixing the first precursor, second precursor, and third carbon source and performing a third sintering to obtain the lithium iron phosphate cathode material, improving the coating integrity of the first carbon coating.
1. A preparation method for ultra-high compacted lithium iron phosphate cathode material, comprising: S1. conducting a chemical reaction based on iron phosphate and dispersant to obtain an iron-containing precursor; S2. obtaining an iron-containing precursor mixture by mixing the iron-containing precursor, a borane, a lithium source, a phosphorus source, and a first carbon source; using ultraviolet light to irradiate the iron-containing precursor mixture; performing a first sintering to the irradiated iron-containing precursor mixture and crushing to obtain a first precursor mixture, grinding the first precursor mixture to a first preset particle size to obtain a first precursor, wherein the borane is a borane nanosheet or a borane nanomembrane; S3. mixing and grinding the iron-containing precursor, the lithium source, the phosphorus source, and a second carbon source, performing a second sintering to obtain a second precursor mixture, and grinding the second precursor mixture to a second preset particle size to obtain a second precursor, where the second carbon source is an amino acid chelated titanium; S4. mixing the first precursor, the second precursor, and a third carbon source, then drying and performing a third sintering in an inert gas atmosphere to obtain the lithium iron phosphate cathode material.
2. The preparation method according to claim 1 , wherein the first preset particle size is greater than the second preset particle size.
3. The preparation method according to claim 1 , wherein the mass ratio of borane to the iron-containing precursor mixture is 1: (10,000˜100,000).
4. A lithium battery, comprising a cathode sheet, wherein the cathode sheet is made of the lithium iron phosphate cathode material according to claim 1 .